Synthesis and Characterization of Rare Earth/Polyurethane Composite Material

The organic ligand sulfosalicylic acid (SSA) which was selected as molecular bridge for sensitization of terbium ions was modified by thionyl chloride (SOCl2) and 3-ammonium propyl triethoxy silane (APTES) to obtain the hybrid precursor SSA-Si. Then the solution of Tb (NO3)3was added in the presence of tetraethylorthosilicate (TEOS). The binary lanthanide organic/inorganic hybrid material was obtained. The ternary hybrid material was obtained by adding the solution of Tb (NO3)3and polyurethane. We investigated the thermal stability and luminescence properties of hybrids and found that the ternary hybrid materials exhibit better thermal stability and stronger emission intensity. Furthermore, compared with the binary mesoporous material Tb-(SSA-Si)3, the ternary mesoporous material Tb-(SSA-Si)3-PU exhibits the characteristic emission of the Tb3+ion with a higher luminescence intensity, suggesting that the introduction of polymer polyurethane into the mesoporous matrix is of benefit for the sensitization of Tb3+luminescence, by replacing H2O groups that can quench the luminescence of Tb3+ion.

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Encapsulation of Lanthanide β-diketone Hybrids in Organic Oligomer Poly(ethylene glycol) 400

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.1102.125 ◽

2015 ◽

Vol 1102 ◽

pp. 125-128

Author(s):

Hua Ti Li ◽

Dong Liu ◽

Ying Li ◽

Jie Lin Wang ◽

Xia Wang

Keyword(s):

Thermal Stability ◽

Ethylene Glycol ◽

Hybrid Materials ◽

Mesoporous Material ◽

Organic Ligand ◽

Poly Ethylene Glycol ◽

Characteristic Emission ◽

Hybrid Precursor ◽

Poly Ethylene ◽

The Eu

The organic ligand 2-Thenoyltrifluoroacetone (TTA) which was selected as molecular bridge for sensitization of europium and terbium ions were modified by 3-(triethoxysilyl)-propylisocyanate (TEPIC) to obtain the hybrid precursor TTA-Si. Then the solution of Eu(NO3)3 and Tb(NO3)3 were added in the presence of tetraethylorthosilicate (TEOS). The binary lanthanide organic/inorganic hybrid material were obtained. The ternary hybrid materials were obtained by adding the solution of Eu(NO3)3 and Tb(NO3)3 and Poly (ethylene glycol) (PEG400). We investigated the thermal stability and luminescence properties of hybrids and found that the ternary hybrid materials exhibit better thermal stability and stronger emission intensity. Furthermore, compared with the binary mesoporous material Eu-(TTA-Si)3 and Tb-(TTA-Si)3, the ternary mesoporous material Eu-(TTA-Si)3-PEG and Tb-(TTA-Si)3-PEG exhibits the characteristic emission of the Eu3+ and Tb3+ ion with a higher luminescence intensity, suggesting that the introduction of PEG is of benefit for the sensitization of Eu3+ and Tb3+ luminescence, by replacing H2O groups that can quench the luminescence of Eu3+ and Tb3+ ions.

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Synthesis and Characterization of Luminescence Eu3+/Polyurethane Composite Material

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.884-885.247 ◽

2014 ◽

Vol 884-885 ◽

pp. 247-250 ◽

Cited By ~ 1

Author(s):

Kai Sheng ◽

Jie Lin Wang ◽

Ying Li ◽

Yi Han Wang ◽

Meng Xue Xu ◽

...

Keyword(s):

Thermal Stability ◽

Composite Material ◽

Rare Earth ◽

Hybrid Materials ◽

Chain Extender ◽

Synthesis And Characterization ◽

Rare Earth Ion ◽

Polyurethane Composite ◽

Small Molecule Ligands

Selecting lactam 2,6-pyridinedicarboxamide (PDCA) as the ligand and 1,4-butanediol as chain extender, we prepare polyurea polyurethane PDCA-PU; then, introduction of rare earth ion Eu3+ and small molecule ligands 1,10-phenanthroline (phen), synthesized binary and ternary polyurethane composite containing Eu3+, and comparing the fluorescence properties of the material. We investigated the thermal stability and luminescence properties of hybrids and found that the ternary hybrid materials exhibit better thermal stability and stronger emission intensity.

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