Optical Investigations in Er3+/Yb3+ Co-Doped Nanostructured Phosphate Glass Ceramics

2013 ◽  
Vol 798-799 ◽  
pp. 67-70 ◽  
Author(s):  
Xiao Chen Yu ◽  
Ai Bin Hao ◽  
Shao Wei Liang ◽  
Zhong Wang Sun

Er3+/Yb3+co-doped transparent phosphate glass ceramics were fabricated and characterized optically. The formation of nanocrystals is confirmed by x-ray diffraction. Stark split near infrared emission peaks of Er3+have been observed in the glass ceramics, and the effective bandwidth increases with increasing annealing temperature. Upconversion emissions of Er3+in the glass ceramics under 975nm wavelength excitation, especially in the green wavelength region, are enhanced. The results can be attributed to the enhancement of ligand field due to incorporation of Er3+ions into the crystal lattices.

2009 ◽  
Vol 24 (2) ◽  
pp. 310-315 ◽  
Author(s):  
Jin Luo ◽  
Shifeng Zhou ◽  
Botao Wu ◽  
Hucheng Yang ◽  
Song Ye ◽  
...  

Cr3+/Ni2+ co-doped optically transparent magnesium aluminosilicate glass-ceramics containing MgAl2O4 nanocrystals have been prepared by heat-treatment. Greatly enhanced broadband near-infrared emission centered at 1216 nm in Cr3+/Ni2+ co-doped glass ceramics is observed when compared with the Ni2+ single-doped glass ceramics under 532 nm excitation. The observed enhancement of infrared emission is attributed to the energy transfer from Cr3+ to Ni2+ ions in the nanocrystalline phase, which leads to the emission due to 3T2(3F) → 3A2(3F) transition of octahedral Ni2+ ions.


2019 ◽  
Vol 234 ◽  
pp. 142-147 ◽  
Author(s):  
Ho Kim Dan ◽  
Jianbei Qiu ◽  
Dacheng Zhou ◽  
Qing Jiao ◽  
Rongfei Wang ◽  
...  

2007 ◽  
Vol 101 (11) ◽  
pp. 113511 ◽  
Author(s):  
Daqin Chen ◽  
Yuansheng Wang ◽  
Feng Bao ◽  
Yunlong Yu

2010 ◽  
Vol 43 (9) ◽  
pp. 095401 ◽  
Author(s):  
Yixi Zhuang ◽  
Miaojia Guan ◽  
Junhua Xie ◽  
Yu Teng ◽  
Jiajia Zhou ◽  
...  

2019 ◽  
Vol 45 (15) ◽  
pp. 18831-18837 ◽  
Author(s):  
Mingming Li ◽  
Jiapan Luan ◽  
Yin Zhang ◽  
Feng Jiang ◽  
Xiang Zhou ◽  
...  

2012 ◽  
Vol 1471 ◽  
Author(s):  
Z. Pan ◽  
G. Sekar ◽  
R. Akrobetu ◽  
R. Mu ◽  
S. H. Morgan

ABSTRACTTb and Yb co-doped oxyfluoride glasses were fabricated in a lithium-lanthanum-aluminosilicate matrix by a melt-quench technique. Glass-ceramics were obtained by appropriate heat treatment of the as-prepared glasses. Visible to near-infrared down-conversion quantum cutting was studied for samples with different thermal annealing temperatures and time. Laser light at 488 nm was used to excite Tb3+ ions while Yb3+ ions were excited by energy transfer from the excited Tb3+ ions. Near-infrared emission at 940 – 1020 nm was observed. It has been found that the emission at 940 – 1020 nm increased significantly from the glass-ceramic compared to that of the as-prepared glass. This result suggests that the energy-transfer efficiency increases in glass-ceramics compared to that in glass. A significant portion of rare-earth ions may be incorporated inside LaF3 nanoparticles (NPs) in the glass-ceramic. Because the Yb3+ emission at 940 – 1020 nm is matched well with the band gap of crystalline Si, the quantum cutting effect may have its potential application in silicon-based solar cells.


2021 ◽  
Vol 866 ◽  
pp. 158568
Author(s):  
Jiaming Liu ◽  
Xin Huang ◽  
Heng Pan ◽  
Xu Zhang ◽  
Xiujie Fang ◽  
...  

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