Synthesis, Crystal Structures and Properties of Two Transition Metal Complexes Based on 4, 4'-{[2, 2'-(ethane-1, 2-bicarboxymethyl)] amino-bis(acetyl)} Dibenzoic Acid

Two isostructural transition metal complexes based on the 4,4'-{[2,2'-(ethane-1,2-bicarboxymethyl)] amino-bis (acetyl)} dibenzoic acid (H4L) were synthesized under hydrothermal conditions, namely, [M(H2L)(H2O)]·3H2O (M=Ni, 1 ; Co, 2). The two compounds were structurally characterized by infrared spectra, thermogravimetric analysis and single crystal X-ray diffractions. Compounds 1-2 are mononuclear units and further extended to generate the two dimensional structures by hydrogen-bonds and π-π interactions. Compounds 1 exhibit the high thermal stability.

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Transition-metal complexes with sulfur ligands. 57. Stabilization of high-valent iron(IV) centers and vacant coordination sites by sulfur .pi.-donation: syntheses, x-ray structures, and properties of [Fe("S2")2(PMe3)n] (n = 1, 2) and (NMe4)[Fe("S2")2(PMe3)2].cntdot.CH3OH ("S2"2- = 1,2-benzenedithiolate(2-))

Journal of the American Chemical Society ◽

10.1021/ja00010a026 ◽

1991 ◽

Vol 113 (10) ◽

pp. 3819-3828 ◽

Cited By ~ 77

Author(s):

Dieter Sellmann ◽

Michael Geck ◽

Falk Knoch ◽

Gerhard Ritter ◽

Joachim Dengler

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

X Ray ◽

Coordination Sites ◽

Structures And Properties ◽

High Valent

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Transition-Metal Complexes with the Novel Poly (1,2,4-triazolyl)borate Ligands [HnB(C2H2N3)4 −n]− (n = 1 and 2): Synthesis and Characterization of Metal Complexes of Dihydrobis(1,2,4-triazolyl)borate as One- or Two-Dimensional Coordination Polymers with Six-Membered Ring Water Substructures and the Structure of Two-Dimensional Liquid and Solid Water As Organized in the Intercalate [Ni{HB(C2H2N3)3}2] · 6 H2O (X-ray Studies at 293 and 160 K)

Chemische Berichte ◽

10.1002/cber.19951280306 ◽

1995 ◽

Vol 128 (3) ◽

pp. 235-244 ◽

Cited By ~ 57

Author(s):

Christoph Janiak ◽

Tobias G. Scharmann ◽

Holger Hemling ◽

Dieter Lentz ◽

Joachim Pickardt

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Coordination Polymers ◽

Membered Ring ◽

Synthesis And Characterization ◽

The Novel ◽

Two Dimensional ◽

X Ray

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An Efficient Catalytic Method for the C-N Acylation of Heterocycles by Schiff Base Co(II), Ni(II), Cu(II) and Zn(II) Transition Metal Complexes..

Letters in Organic Chemistry ◽

10.2174/1570178617999200922150741 ◽

2020 ◽

Vol 17 ◽

Author(s):

Sujit Hegade ◽

Gautam Gaikwad ◽

Yuvraj Jadhav ◽

Sanjay Chavan ◽

Ganpatrao Mulik

Keyword(s):

Schiff Base ◽

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Acetyl Chloride ◽

Structural Type ◽

High Thermal Stability ◽

Schiff Base Complexes ◽

Catalytic Method ◽

X Ray

: The catalytic activity of Schiff base Co(II), Ni(II), Cu(II) and Zn(II) transition metal complexes were tested for N-Acylation of heterocycles with acetyl chloride. It is observed that all the complexes worked as the efficient catalysts. The Structural type of the complexes were studied by X-ray powder diffractogram (XRD). The mixed ligand complexes with PPh3 ligand show greater activity as compared to Phen complexes and Schiff base complexes. Especially complex [Ni(L)(PPh3)2Cl2] efficiently worked as catalyst because of high thermal stability (TGA-DSC) and large catalytic surface area (BET).

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Volatility and High Thermal Stability in Mid-to-Late First-Row Transition-Metal Complexes Containing 1,2,5-Triazapentadienyl Ligands

Inorganic Chemistry ◽

10.1021/ic302787z ◽

2013 ◽

Vol 52 (3) ◽

pp. 1182-1184 ◽

Cited By ~ 5

Author(s):

Lakmal C. Kalutarage ◽

Mary Jane Heeg ◽

Philip D. Martin ◽

Mark J. Saly ◽

David S. Kuiper ◽

...

Keyword(s):

Thermal Stability ◽

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

High Thermal Stability

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Transition-metal complexes with sulfur ligands. 57. Stabilization of high-valent iron(IV) centers and vacant coordination sites by sulfur .pi.-donation: syntheses, x-ray structures, and properties of [Fe("S2")2(PMe3)n] (n = 1, 2) and (NMe4)[Fe("S2")2-(PMe3)2].cntdot.CH3OH ("S2"2- = 1,2-benzenedithiolate (2-)). [Erratum to document cited in CA114(22):220083s]

Journal of the American Chemical Society ◽

10.1021/ja00033a091 ◽

1992 ◽

Vol 114 (7) ◽

pp. 2769-2769

Author(s):

Dieter Sellmann ◽

Michael Geck ◽

Falk Knoch ◽

Gerhard Ritter ◽

Joachim Dengler

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

X Ray ◽

Coordination Sites ◽

Structures And Properties ◽

High Valent

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Preparation, properties and structure of some intermediate nido- and arachno-monocarbaboranes

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19812345 ◽

1981 ◽

Vol 46 (10) ◽

pp. 2345-2353 ◽

Cited By ~ 33

Author(s):

Karel Baše ◽

Bohumil Štíbr ◽

Jiří Dolanský ◽

Josef Duben

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Nmr Spectra ◽

Liquid Ammonia ◽

X Ray Diffraction ◽

X Ray ◽

H Nmr ◽

Starting Compound

The 6-N(CH3)3-6-CB9H11 carbaborane reacts with sodium in liquid ammonia with the formation of 6-CB9H12- which was used as a starting compound for preparing the 4-CB8H14, 9-L-6-CB9H13 (L = (CH3)2S, CH3CN and P(C6H5)3), 1-(η5-C5H5)-1,2-FeCB9H10-, and 2,3-(η5-C5H5)2-2,31-Co2CB9H10- carboranes. The 4-CB8H14 compound was dehydrogenated at 623 K to give 4-(7)-CB8H12 carborane. Base degradation of 6-N(CH3)3-6-CB9H11 in methanol resulted in the formation of 3,4-μ-N(CH3)3CH-B5H10. The structure of all compounds was proposed on the basis of their 11B and 1H NMR spectra and X-ray diffraction was used in the case of the transition metal complexes.

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