Co-Precipitation Synthesis and Photoluminescence Properties of K2SiF6:Mn4+ Red Phosphor for White Light Emitting Diodes

2019 ◽  
Vol 807 ◽  
pp. 101-109
Author(s):  
Di Wu ◽  
Xin Yu Ye ◽  
Lin Sheng Wang ◽  
Qing Hua Zeng

A novel red-emitting K2SiF6:Mn4+ phosphors with different Mn4+ doping mole fraction were synthesized by co-precipitation method. X-ray diffraction (XRD), scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FT-IR) and fluorescence spectrometer were used to characterize the properties of K2SiF6:Mn4+ phosphors. As-prepared K2SiF6:Mn4+ phosphors have cubic crystal structure. Under excitation at 450 nm, an intense red emission peak around 632 nm corresponding to the 2Eg-4A2 transition of Mn4+ was observed for 8.37 mol% K2SiF6:Mn4+ phosphors and was used as the optimum doping concentration. The excellent luminescent properties make the phosphor K2SiF6:Mn4+ a candidate for applications in InGaN-YAG:Ce3+ type LEDs for high color rendering. “A warm” white light LED with an efficiency of 147 lm/w and a color rendering index of 87.4 at a color temperature of 2864K has been obtained by fabricating YAG:Ce3+ with K2SiF6:Mn4+ on an InGaN chip.

RSC Advances ◽  
2015 ◽  
Vol 5 (72) ◽  
pp. 58136-58140 ◽  
Author(s):  
Zhengliang Wang ◽  
Yong Liu ◽  
Yayun Zhou ◽  
Qiang Zhou ◽  
Huiying Tan ◽  
...  

Red hexafluoride phosphors were synthesized by a simple co-precipitation method. WLEDs fabricated with as-prepared phosphors emit intense warm white-light under 20 mA current excitation. Therefore, they may find application in warm WLEDs.


2017 ◽  
Vol 29 (37) ◽  
pp. 1702910 ◽  
Author(s):  
Zifei Wang ◽  
Fanglong Yuan ◽  
Xiaohong Li ◽  
Yunchao Li ◽  
Haizheng Zhong ◽  
...  

2015 ◽  
Vol 36 (12) ◽  
pp. 1402-1408 ◽  
Author(s):  
罗 洋 LUO Yang ◽  
江建青 JIANG Jian-qing ◽  
侯得健 HOU De-jian ◽  
游维雄 YOU Wei-xiong ◽  
叶信宇 YE Xin-yu

Nanophotonics ◽  
2016 ◽  
Vol 5 (4) ◽  
pp. 565-572 ◽  
Author(s):  
Wei Chen ◽  
Kai Wang ◽  
Junjie Hao ◽  
Dan Wu ◽  
Jing Qin ◽  
...  

AbstractIn this research, we have developed an approach by incorporating quantum dots (QDs) with red emission into mesoporous silica microspheres through a non-chemical process and obtained luminescent microspheres (LMS). Owing to the lattice structure of LMS, QDs were effectively protected from intrinsic aggregation in matrix and surface deterioration by encapsulant, oxygen and moisture. The LMS composite has therefore maintained large extent luminescent properties of QDs, espe-cially for the high quantum efficiency. Moreover, the fabricated white light emitting diode (WLED) utilizing LMS and YAG:Ce yellow phosphor has demonstrated excellent light performance with color coordinates around (x = 0.33, y = 0.33), correlated color temperature between 5100 and 5500 K and color rendering index of Ra = 90, R9 = 95. The luminous efficiency of the WLED has reached up to a new record of 142.5 lm/W at 20 mA. LMS provide a promising way to practically apply QDs in lightings and displays with high efficiency as well as high stability.


2018 ◽  
Vol 58 (1) ◽  
pp. 456-461 ◽  
Author(s):  
Zhengliang Wang ◽  
Zhiyu Yang ◽  
Zhaofeng Yang ◽  
Qianwen Wei ◽  
Qiang Zhou ◽  
...  

2020 ◽  
Vol 8 (3) ◽  
pp. 1095-1103 ◽  
Author(s):  
Liangling Sun ◽  
Balaji Devakumar ◽  
Jia Liang ◽  
Shaoying Wang ◽  
Qi Sun ◽  
...  

Broadband cyan-emitting Ca2LuZr2(AlO4)3:Ce3+ garnet phosphors enabled to fill the cyan gap in the emission spectra of near-ultraviolet-pumped warm-white LEDs, thus resulting in improved color rendering index.


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