Effect of Phosphorus or Boron Addition on Water-Resistance of Water-Glass Adhesives

2003 ◽  
Vol 439 ◽  
pp. 215-220
Author(s):  
Hyung Mi Lim ◽  
Bong Young Kim ◽  
Seung Ho Lee
2020 ◽  
Vol 58 (5) ◽  
pp. 319-325
Author(s):  
Min A Bae ◽  
Man Sig Lee ◽  
Jae Ho Baek

In recent years, the metal casting industry has sought to meet ever more stringent environmental standards. Inorganic binders based on silicate chemistry have many advantages with respect to environmental issues, but often suffer from reduced strength, burn-on and poor water-resistance. In particular, when sand is mixed with a water glass based inorganic binder, it adversely affects fluidity. In this study, a Powder flow test (PFT) analysis was conducted to confirm the effect of the surface tension of water glass on mixed sand. Certain additives were selected as surfactants to lower the surface tension of the water glass. The characteristics of the samples were measured using the PFT. A correlation between the surface tension of the water glass and the fluidity of the mixed sand was established. We then evaluated the effect of the inorganic binder on core strength. Using the surfactants, the fluidity of the mixed sand increased by 66%. However, strength and water resistance were reduced by approximately 45%. As a result, it was found that when 1.5% of surfactant was added, the resulting fluidity and humidity strength characteristics produced a mixed sand with good properties. Water glass with improved fluidity can produce a high quality core and mold. Finally, we used a practical application prove that an inorganic binder can replace organic binders in foundry cores.


2013 ◽  
Vol 746 ◽  
pp. 289-292 ◽  
Author(s):  
Evgeniy Valerjevich Korolev ◽  
Anna Nikolaevna Grishina

The water glass can be used as a binder for the design of water-resistant radiation-protective building materials. In the present work the possibility of hardening of such materials by barium chloride is investigated. The chemical reactions which can take place during the structure forming and lead to the formation of barium hydrosilicates are presented. It is shown by means of X-ray phase analysis that formation of such hydrosilicates of composition BaO·SiO2·6Н2О, BaO·2SiO2·4Н2О, Ba2[SiO2(OH)2]2and BaO·SiO2·Н2О actually occurs. The influence of the quantity of hardener to the chemical composition of the reaction products is examined. The effect of the reaction products to the water resistance of composite is studied. It is shown that water resistance can be increased in case of stochiometric quantity of barium chloride; in such case the primary product of reaction is BaO·2SiO2·4Н2О.


2012 ◽  
Vol 12 (3) ◽  
pp. 53-58 ◽  
Author(s):  
J. Kamińska ◽  
J. Dańko

Abstract The results of investigations of the granulation process of foundry dusts generated in the dry mechanical reclamation process of used sands, where furan resins were binders are presented in the paper. Investigations concerned producing of granules of the determined dimensions and strength parameters. Granules were formed from the dusts mixture consisting in 50 mass% of dusts obtained after the reclamation of the furane sands and in 50 mass % of dusts from sands with bentonite. Dusts from the bentonite sands with water were used as a binder allowing the granulation of after reclamation dusts from the furane sands. The following parameters of the ready final product were determined: moisture content (W), shatter test of granules (Wz) performed directly after the granulation process and after 1, 3, 5, 10 days and nights of seasoning, water-resistance of granules after 24 hours of being immersed in water, surface porosity ep and volumetric porosity ev. In addition the shatter test and water-resistance of granulate dried at a temperature of 105°C were determined. Investigations were performed at the bowl angle of inclination 45°, for three rotational speeds of the bowl being: 10, 15, 20 rpm. For the speed of 10 rpm the granulation tests of dusts mixture after the preliminary mixing in the roller mixer and with the addition of water-glass in the amount of 2% in relation to the amount of dust were carried out. The obtained results indicate that the granulator allows to obtain granules from dusts originated from the reclamations of moulding sands with the furane resin with an addition of dusts from the bentonite sands processing plants.


1908 ◽  
Vol 66 (1719supp) ◽  
pp. 373-373
Author(s):  
Karl Wallin
Keyword(s):  

2007 ◽  
Vol 61 (4) ◽  
pp. 455-459
Author(s):  
Yoko Saito ◽  
Liu Xiang ◽  
Hideki Touda ◽  
Junji Kasai

2020 ◽  
Vol 57 (10) ◽  
pp. 714-742
Author(s):  
V. G. Efremenko ◽  
K. M. Wu ◽  
K. Shimizu ◽  
I. Petryshynets ◽  
B. V. Efremenko ◽  
...  

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