Variation Law of Temperature Field and Pressure Field in Synthesis of SiC by Carbothermal Reduction Method

2014 ◽  
Vol 809-810 ◽  
pp. 258-263
Author(s):  
Yang Li ◽  
Jie Chen

Through numerical simulation of temperature field and pressure field in synthesis of SiC by carbothermal reduction method, the variation law of temperature and pressure with time in furnace was studied. Research results show that the high temperature isothernal face expands outside gradually with the prolong of the synthesis time, so the temperature field area compatible to the production of SiC increase gradually, but too long synthesis time not only increase energy consumption, but also generate SiC product yield decreased. Compared with single heat furnace, the pressure is comparatively more uniformity in three-heat-source and the pressure is 140~200kPa, which is useful for synthesis of SiC and can prevent furnace spewing. At the bottom of single heat furnace should pay attention to charge ration when charging, adding a little sawdust can increase the porosity and release pressure.

2018 ◽  
pp. 101-107
Author(s):  
Bingying Xie ◽  
Jincheng Yu ◽  
Yujun Zhang ◽  
Hongyu Gong ◽  
Xiao Lin ◽  
...  

Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 1811 ◽  
Author(s):  
Yuan Zeng ◽  
Feng Liang ◽  
Jianghao Liu ◽  
Jun Zhang ◽  
Haijun Zhang ◽  
...  

To address the various shortcomings of a high material cost, energy-intensive temperature conditions and ultra-low efficiency of the conventional boro/carbothermal reduction method for the industrial preparation of ZrB2-SiC powders, a novel molten-salt and microwave-modified boro/carbothermal reduction method (MSM-BCTR) was developed to synthesize ZrB2-SiC powders. As a result, phase pure ZrB2-SiC powders can be obtained by firing low-cost zircon (ZrSiO4), amorphous carbon (C), and boron carbide (B4C) at a reduced temperature of 1200 °C for only 20 min. Such processing conditions are remarkably milder than not only that required for conventional boro/carbothermal reduction method to prepare phase pure ZrB2 or ZrB2-SiC powders (firing temperature of above 1500 °C and dwelling time of at least several hours), but also that even with costly active metals (e.g., Mg and Al). More importantly, the as-obtained ZrB2 particles had a single crystalline nature and well-defined plate-like morphology, which is believed to be favorable for enhancing the mechanical properties, especially toughness of their bulk counterpart. The achievement of a highly-efficient preparation of such high-quality ZrB2-SiC powders at a reduced temperature should be mainly attributed to the specific molten-salt and microwave-modified boro/carbothermal reduction method.


2007 ◽  
Vol 12 (7-8) ◽  
pp. 1011-1015 ◽  
Author(s):  
H. Liu ◽  
P. Zhang ◽  
G. C. Li ◽  
Q. Wu ◽  
Y. P. Wu

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