Evolutions of Microstructure and Phase Transformation in Cu-Al-Fe-Nb/Ta High-Temperature Shape Memory Alloys

2015 ◽  
Vol 833 ◽  
pp. 67-70
Author(s):  
Shui Yuan Yang ◽  
Cui Ping Wang ◽  
Yu Su ◽  
Xing Jun Liu

The evolutions of microstructure and phase transformation behavior of Cu-Al-Fe-Nb/Ta high-temperature shape memory alloys under the quenched and aged states were investigated in this study, including Cu-10wt.% Al-6wt.% Fe, Cu-10wt.% Al-4wt.% Fe-2wt.% Nb and Cu-10wt.% Al-4wt.% Fe-2wt.% Ta three types alloys. The obtained results show that after quenching, Cu-10wt.% Al-6wt.% Fe alloy exhibits two-phase microstructure of β′1 martensite + Fe (Al,Cu) phase; Cu-10wt.% Al-4wt.% Fe-2wt.% Nb alloy also has two-phase microstructure of (β′1 + γ′1 martensites) + Nb (Fe,Al,Cu)2 phase; Cu-10wt.% Al-4wt.% Fe-2wt.% Ta alloy is consisted of three-phase of (β′1 + γ′1 martensites) + Fe (Al,Cu,Ta) + Ta2(Al,Cu,Fe)3 phases. However, α (Cu) phase precipitates after aging for three alloys; and Fe (Al,Cu,Nb) phase is also present in Cu-10wt.% Al-4wt.% Fe-2wt.% Nb alloy. All the studied alloys exhibit complicated martensitic transformation behaviors resulted from the existence of two types martensites (β′1 and γ′1).

2015 ◽  
Vol 833 ◽  
pp. 63-66
Author(s):  
Cui Ping Wang ◽  
Yu Ding Liu ◽  
Shui Yuan Yang ◽  
Xing Jun Liu

The microstructure and phase transformation behavior of Ni-Mn-Fe high-temperature shape memory alloys including Ni40+xFe10Mn50-x (x = 0, 10) were investigated. The results show that both two alloys exhibit single fcc γ phase annealed at 900°C for 1 day. When these quenched alloys are again annealed at 500°C for 20 days, they almost exhibit main tetragonal θ martensite. The microstructural evolutions are consistent with the results of phase transformation measurements. It is clearly found that there is an irreversible phase transformation around 480°C ~ 570°C, which is associated with the formation of tetragonal θ martensite from γ phase. Afterwards, the reversible martensitic transformation occurs during heating and cooling with very high transformation temperature.


Crystals ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 345 ◽  
Author(s):  
Weiya Li ◽  
Chunwang Zhao

The microstructure and martensitic transformation behavior of Ni50−xTi50Lax (x = 0.1, 0.3, 0.5, 0.7) shape memory alloys were investigated experimentally. Results show that the microstructure of Ni50−xTi50Lax alloys consists of a near-equiatomic TiNi matrix, LaNi precipitates, and Ti2Ni precipitates. With increasing La content, the amounts of LaNi and Ti2Ni precipitates demonstrate an increasing tendency. The martensitic transformation start temperature increases gradually with increasing La content. The Ni content is mainly responsible for the change in martensite transformation behavior in Ni50−xTi50Lax alloys.


2007 ◽  
Vol 546-549 ◽  
pp. 2241-2244 ◽  
Author(s):  
Yun Qing Ma ◽  
Cheng Bao Jiang ◽  
Yan Li ◽  
Cui Ping Wang ◽  
Xing Jun Liu

A strong need exists to develop new kinds of high-temperature shape-memory alloys. In this study, two series of CoNiGa alloys with different compositions have been studied to investigate their potentials as high-temperature shape-memory alloys, with regard to their microstructure, crystal structure, and martensitic transformation behavior. Optical observations and X-ray diffractions confirmed that single martensite phase was present for low cobalt samples, and dual phases containing martensite and γ phase were present for high cobalt samples. It was also found that CoNiGa alloys in this study exhibit austenitic transformation temperatures higher than 340°C, showing their great potentials for developing as high-temperature shape-memory alloys.


2006 ◽  
Vol 503-504 ◽  
pp. 1013-0 ◽  
Author(s):  
Chao Ying Xie ◽  
Z.G. Fan ◽  
Z.H. Li ◽  
G.Q. Xiang ◽  
X.H. Cheng

Microstructures and transformation behavior of TiNi shape memory alloy after high temperature ECAE process have been investigated. It is found that the initial coarse grains were refined after high temperature ECAE processes and short annealing at 750°C. Transformation temperatures of TiNi alloy sharply decreased after two ECAE processes, rose obviously when annealed at 750°C for 5min, and quickly rose back after annealing at 500°C for 2 hours. Reasons for phase transformation behavior changes have been discussed.


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