scholarly journals Microstructure and Phase Transformation Analysis of Ni50−xTi50Lax Shape Memory Alloys

Crystals ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 345 ◽  
Author(s):  
Weiya Li ◽  
Chunwang Zhao
Keyword(s):  
Phase Transformation ◽  
Martensitic Transformation ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Martensite Transformation ◽  
Transformation Behavior ◽  
Ni Content ◽  
Start Temperature

The microstructure and martensitic transformation behavior of Ni50−xTi50Lax (x = 0.1, 0.3, 0.5, 0.7) shape memory alloys were investigated experimentally. Results show that the microstructure of Ni50−xTi50Lax alloys consists of a near-equiatomic TiNi matrix, LaNi precipitates, and Ti2Ni precipitates. With increasing La content, the amounts of LaNi and Ti2Ni precipitates demonstrate an increasing tendency. The martensitic transformation start temperature increases gradually with increasing La content. The Ni content is mainly responsible for the change in martensite transformation behavior in Ni50−xTi50Lax alloys.

Evolutions of Microstructure and Phase Transformation in Cu-Al-Fe-Nb/Ta High-Temperature Shape Memory Alloys

2015 ◽  
Vol 833 ◽  
pp. 67-70
Author(s):  
Shui Yuan Yang ◽  
Cui Ping Wang ◽  
Yu Su ◽  
Xing Jun Liu
Keyword(s):  
Phase Transformation ◽  
High Temperature ◽  
Martensitic Transformation ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Transformation Behavior ◽  
Two Phase ◽  
Phase Transformation Behavior ◽  
Three Phase

The evolutions of microstructure and phase transformation behavior of Cu-Al-Fe-Nb/Ta high-temperature shape memory alloys under the quenched and aged states were investigated in this study, including Cu-10wt.% Al-6wt.% Fe, Cu-10wt.% Al-4wt.% Fe-2wt.% Nb and Cu-10wt.% Al-4wt.% Fe-2wt.% Ta three types alloys. The obtained results show that after quenching, Cu-10wt.% Al-6wt.% Fe alloy exhibits two-phase microstructure of β′1 martensite + Fe (Al,Cu) phase; Cu-10wt.% Al-4wt.% Fe-2wt.% Nb alloy also has two-phase microstructure of (β′1 + γ′1 martensites) + Nb (Fe,Al,Cu)2 phase; Cu-10wt.% Al-4wt.% Fe-2wt.% Ta alloy is consisted of three-phase of (β′1 + γ′1 martensites) + Fe (Al,Cu,Ta) + Ta2(Al,Cu,Fe)3 phases. However, α (Cu) phase precipitates after aging for three alloys; and Fe (Al,Cu,Nb) phase is also present in Cu-10wt.% Al-4wt.% Fe-2wt.% Nb alloy. All the studied alloys exhibit complicated martensitic transformation behaviors resulted from the existence of two types martensites (β′1 and γ′1).

Evolution of hysteresis characteristic of shape memory alloys at incomplete phase transformation cyclic loading

2021 ◽  
Author(s):  
Yajun You ◽  
Xin Guo
Keyword(s):  
Phase Transformation ◽  
Martensitic Transformation ◽  
Cyclic Loading ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Martensite Transformation ◽  
Cyclic Load ◽  
Hysteretic Behavior ◽  
Transformation Stage ◽  
Cyclic Loading Tests

Abstract The phase transformation ratchetting of Shape Memory Alloys (SMAs) at incomplete phase transformation cyclic loading is experimentally and theoretically investigated. To this end, two different kinds of incomplete phase transformation cyclic loading tests on NiTi wires are performed, i.e. incomplete transformation cyclic loads are respectively applied at the stages of forward martensite transformation and reverse martensite transformation. When the cyclic load of incomplete transformation is applied in the positive martensitic transformation stage, a novel phenomenon is discovered: although there is no greater stress to drive the anstenite turn to martensite, the SMAs can still gradually undergo martensite transformation and accumulation until martensite reaches saturation. The hysteretic behavior finally reaches a shakedown state where the strain-stress curve no longer changes with the number of cycles. When the cyclic load of incomplete transformation is applied in the reverse martensitic transformation stage, a similar phenomenon is obtatined. According to the analysis of the temperature evolution during the deformation process of the SMAs, combined with the relationship between the phase transformation yield stress and the temperature of SMAs, the experimental results are reasonably explained. This research is of great significance for a more comprehensive grasp of the mechanical behavior of SMAs.

scholarly journals Effect of Nd Addition on the Microstructure and Martensitic Transformation of Ni-Ti Shape Memory Alloys

2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
M. Dovchinvanchig ◽  
C. W. Zhao ◽  
S. L. Zhao ◽  
X. K. Meng ◽  
Y. J. Jin ◽  
...  
Keyword(s):  
Rare Earth ◽  
Martensitic Transformation ◽  
Shape Memory Alloy ◽  
Shape Memory ◽  
Earth Element ◽  
Transformation Behavior ◽  
Nd Addition ◽  
One Step ◽  
Niti Matrix ◽  
Start Temperature

The effect of rare earth element Nd addition on the microstructure and martensitic transformation behavior of Ni50Ti50−xNdx(x=0, 1, 3, 7, 20) shape memory alloy was investigated experimentally. The results showed that the microstructure of Ni-Ti-Nd ternary alloy consists of the NiNd phase and the NiTi matrix. One-step martensitic transformation was observed in all alloys. The martensitic transformation start temperatureMsincreased gradually with increasing Nd content for Ni-Ti-Nd alloys.

In situ TEM study of irradiation-induced transformation in TiNi shape memory alloys

2003 ◽  
Vol 792 ◽  
Author(s):  
X. T. Zu ◽  
F.R. Wan ◽  
S. Zhu ◽  
L. M. Wang
Keyword(s):  
Phase Transformation ◽  
Martensitic Transformation ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Electron Irradiation ◽  
Room Temperature ◽  
Critical Voltage ◽  
In Situ Tem ◽  
In Situ Observation

ABSTRACTTiNi shape memory alloy (SMA) has potential applications for nuclear reactors and its phase stability under irradiation is becoming an important topic. Some irradiation-induced diffusion-dependent phase transformations, such as amorphization, have been reported before. In the present work, the behavior of diffusion-independent phase transformation in TiNi SMA was studied by electron irradiation at room temperature. The effect of irradiation on the martensitic transformation of TiNi shape memory alloys was studied by Transmission Electron Microscopy (TEM) with in-situ observation and differential scanning calorimeter (DSC). The results of TEM and DSC measurements show that the microstructure of samples is R phase at room temperature. Electron irradiations were carried out using several different TEM with accelerating voltage of 200 kV, 300 kV, 400 kV and 1000 kV. Also the accelerating voltage in the same TEM was changed to investigate the critical voltage for the effect of irradiation on phase transformation. It was found that a phase transformation occurred under electron irradiation above 320 kV, but never appeared at 300 kV or lower accelerating voltage. Such phase transformation took place in a few seconds of irradiation and was independent of atom diffusion. The mechanism of Electron-irradiation-induced the martensitic transformation due to displacements of atoms from their lattice sites produced by the accelerated electrons.

Experimental and FEM Analysis of the Fracture Behavior in NiTi Shape Memory Alloys

2006 ◽  
Vol 324-325 ◽  
pp. 919-922 ◽  
Author(s):  
Xin Mei Wang ◽  
Zhu Feng Yue
Keyword(s):  
Fracture Toughness ◽  
Phase Transformation ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Fracture Behavior ◽  
Micromechanical Model ◽  
Crack Tip ◽  
Fem Analysis ◽  
Transformation Behavior ◽  
Niti Shape Memory Alloys

In the present work, the fracture toughness of a NiTi pseudoelastic alloy has been obtained by experiments on CT specimens, which is KIC =39.38MPa·m1/2. Then the stress induced phase transformation behavior in front of the crack tip of the CT specimen is simulated by a micromechanical model considering the different elastic properties between martensite and austenite. The results show that the pre-crack promotes phase transformation at the crack tip. And the phase transformation is localised near the crack tip. It is also shown that phase transformation reduces the Mises stress around the crack tip.

Heusler Type CoNiGa Alloys with High Martensitic Transformation Temperature

2007 ◽  
Vol 546-549 ◽  
pp. 2241-2244 ◽  
Author(s):  
Yun Qing Ma ◽  
Cheng Bao Jiang ◽  
Yan Li ◽  
Cui Ping Wang ◽  
Xing Jun Liu
Keyword(s):  
High Temperature ◽  
Martensitic Transformation ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Martensite Phase ◽  
Optical Observations ◽  
Martensitic Transformation Temperature ◽  
Transformation Behavior ◽  
X Ray ◽  
Austenitic Transformation

A strong need exists to develop new kinds of high-temperature shape-memory alloys. In this study, two series of CoNiGa alloys with different compositions have been studied to investigate their potentials as high-temperature shape-memory alloys, with regard to their microstructure, crystal structure, and martensitic transformation behavior. Optical observations and X-ray diffractions confirmed that single martensite phase was present for low cobalt samples, and dual phases containing martensite and γ phase were present for high cobalt samples. It was also found that CoNiGa alloys in this study exhibit austenitic transformation temperatures higher than 340°C, showing their great potentials for developing as high-temperature shape-memory alloys.

Effects of High Temperature ECAE Process on Microstructures and Martensitic Transformation of TiNi Shape Memory Alloy

2006 ◽  
Vol 503-504 ◽  
pp. 1013-0 ◽  
Author(s):  
Chao Ying Xie ◽  
Z.G. Fan ◽  
Z.H. Li ◽  
G.Q. Xiang ◽  
X.H. Cheng
Keyword(s):  
Phase Transformation ◽  
High Temperature ◽  
Martensitic Transformation ◽  
Shape Memory Alloy ◽  
Shape Memory ◽  
Tini Alloy ◽  
Behavior Changes ◽  
Transformation Behavior ◽  
Coarse Grains ◽  
Short Annealing

Microstructures and transformation behavior of TiNi shape memory alloy after high temperature ECAE process have been investigated. It is found that the initial coarse grains were refined after high temperature ECAE processes and short annealing at 750°C. Transformation temperatures of TiNi alloy sharply decreased after two ECAE processes, rose obviously when annealed at 750°C for 5min, and quickly rose back after annealing at 500°C for 2 hours. Reasons for phase transformation behavior changes have been discussed.

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