REGULAR ARTICLE: Theoretical Treatment of Ultrafast Decay of Excited Vibronic States in the Improved Adiabatic Approximation

2017 ◽  
Vol 5 (4) ◽  
pp. 110-120
Author(s):  
Jian Lei and Rongxing He
Keyword(s):  
Adiabatic Approximation ◽  
Theoretical Treatment ◽  
Vibronic States

Study of the vibronic coupling in the ground state of Methylthio radical

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Ground State ◽  
Adiabatic Approximation ◽  
Vibronic Coupling ◽  
Energy Gaps ◽  
Jahn Teller ◽  
Coupling Parameters ◽  
Vibronic States

Using a methodology based on the crude adiabatic approximation, we study the complete linear and quadratic vibronic coupling in the ground state of SCH3 radical. In order to build the representation of the hamiltonian, we evaluated 30 integrals intervening in the formulation of the vibronic coupling. Diagonalization of this representation gives the vibronic levels. For the lowest vibronic states, the implied modes are Q1 (symmetric C-S stretching) and Q4 (CH3 rocking). Energy gaps A1-A2 and A2-ε resulting from the splitting due to the Jahn-Teller coupling E e = A1 + A2+ ε are evaluated to 250 and 169 cm-1, respectively. Essential coupling parameters are surrounded to simplify the study of highly vibronic states.

Contrasts of planar defects in reflection electron microscopy

1993 ◽  
Vol 51 ◽  
pp. 1004-1005
Author(s):  
Feng Tsai ◽  
J. M. Cowley
Keyword(s):  
Electron Microscopy ◽  
Surface Defects ◽  
Practical Importance ◽  
Theoretical Treatment ◽  
Crystal Surfaces ◽  
Planar Defects ◽  
Surface Steps ◽  
Surface Reconstructions ◽  
Domain Boundaries ◽  
Reflection Electron Microscopy

Reflection electron microscopy (REM) has been used to study surface defects such as surface steps, dislocations emerging on crystal surfaces, and surface reconstructions. However, only a few REM studies have been reported about the planar defects emerging on surfaces. The interaction of planar defects with surfaces may be of considerable practical importance but so far there seems to be only one relatively simple theoretical treatment of the REM contrast and very little experimental evidence to support its predications. Recently, intersections of both 90° and 180° ferroelectric domain boundaries with BaTiO3 crystal surfaces have been investigated by Tsai and Cowley with REM.The REM observations of several planar defects, such as stacking faults and domain boundaries have been continued by the present authors. All REM observations are performed on a JEM-2000FX transmission electron microscope. The sample preparations may be seen somewhere else. In REM, the incident electron beam strikes the surface of a crystal with a small glancing angle.

FURTHER CONSIDERATIONS ON THE CALCULATIONS OF SECRETION RATES. A CORRECTION

1961 ◽  
Vol 38 (3) ◽  
pp. 469-472 ◽  
Author(s):  
K. R. Laumas ◽  
J. F. Tait ◽  
S. A. S. Tait
Keyword(s):  
Steady State ◽  
Compartmental Model ◽  
Single Injection ◽  
Previous Treatment ◽  
Urinary Metabolite ◽  
Theoretical Treatment ◽  
Basic Equations ◽  
Special Circumstances ◽  
Secretion Rates

ABSTRACT Reconsideration of the question of the validity of the calculations of the secretion rates from the specificity activity of a urinary metabolite after the single injection of a radioactive hormone has led us to conclude that the basic equations used in a previous theoretical treatment are not generally applicable to the nonisotopic steady state if the radioactive steroid and hormone are introduced into the same compartment. If this is so, in a two compartmental model with metabolism occurring in both pools, it is now shown that the calculation (S = R — τ) is rigorously valid if certain precautions are taken. This is in contrast to the previous treatment which concluded (in certain special circumstances) that the calculation might not be correct. However, if the hormone is secreted in both compartments and the radioactive steroid is injected into only one, then the calculation (S = R — τ) may not be correct in certain circumstances as was previously concluded (Laumas et al. 1961).

The economics of escalation

2021 ◽  
Vol 33 (1) ◽  
pp. 106-140
Author(s):  
Fabio D’Orlando ◽  
Sharon Ricciotti
Keyword(s):  
Human Nature ◽  
Budget Constraint ◽  
Theoretical Treatment ◽  
Jel Codes ◽  
Innate Behavior ◽  
Hedonic Adaptation ◽  
The Past ◽  
Subjective Scale ◽  
The Subject ◽  
Positional Effects

Escalation is a key characteristic of many consumption behaviors that has not received theoretical attention. This paper aims to propose both a definition and a theoretical treatment of escalation in consumption. We define escalation as a subject’s attempt to obtain “more” or engage in consumption behaviors that are “more intense” on a measurable, quantitative or qualitative, objective or subjective, scale (more difficult ski slopes, stronger drugs, harder sex, better restaurants etc.), even if the subject preferred less intense consumption behaviors in the past. Further, this evolution in behavior also occurs if the budget constraint does not change. We will find endogenous and exogenous theoretical microfoundations for escalation in models of hedonic adaptation, desire for novelty, acquisition of consumption skills, rising aspirations, positional effects, and envy. However, we will also discuss the possibility that the tendency to escalate is a specific innate behavior inherent to human nature. Finally, we will propose a preliminary theoretical formalization of such behavior and indicate the possible implications of taking escalation into adequate consideration. JEL codes: B52, D11, D90, D91, I31

Efficient and Reliable Strategy for Identifying Muon Sites Based on the Double Adiabatic Approximation

2015 ◽  
Vol 119 (8) ◽  
pp. 4278-4285 ◽  
Author(s):  
P. Bonfà ◽  
F. Sartori ◽  
R. De Renzi
Keyword(s):  
Adiabatic Approximation

Photosensitive tunneling in superconductivity

1970 ◽  
Vol 48 (5) ◽  
pp. 630-631 ◽  
Author(s):  
V. Radhakrishnan
Keyword(s):  
Fermi Level ◽  
Density Of States ◽  
Tunneling Current ◽  
Theoretical Treatment ◽  
Photoconductive Property

Theoretical treatment of the model proposed by Giaever for his experiment on the photosensitive tunneling in superconductors is examined. New relations are derived which connect the photoconductive property of the barrier and the tunneling current. These relations are helpful to check the model and to determine the density of states for the trapped holes at the hole Fermi level.

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