scholarly journals One-Electron-Addition to Pentavalent Phosphorus with the Phosphorus-Chlorine Bond as Acceptor Introducing a Fundamental Distinction in Substitution Mechanism between S<sub>N</sub>2(P) and S<sub>N</sub>2(C)

2019 ◽  
Vol 09 (03) ◽  
pp. 182-191
Author(s):  
Henk M. Buck
Keyword(s):  
Pentavalent Phosphorus ◽  
Substitution Mechanism ◽  
Fundamental Distinction ◽  
Chlorine Bond

Study of Singlet Oxygen-Pentavalent Phosphorus Reactions.

1984 ◽  
Author(s):  
L. J. Marabella ◽  
J. Kuper ◽  
C. Lovejoy ◽  
J. Betts
Keyword(s):  
Singlet Oxygen ◽  
Pentavalent Phosphorus

Electrocatalytic cleavage of a carbon–chlorine bond by Re(IV)–chloro complex: a mechanistic insight from DFT

2021 ◽  
Author(s):  
Jamaladin Shakeri ◽  
Hassan Hadadzadeh ◽  
Hossein Farrokhpour ◽  
Matthias Weil ◽  
Mohammad Joshaghani
Keyword(s):  
Chloro Complex ◽  
Mechanistic Insight ◽  
Chlorine Bond

Chlorodifluoromethyl-substituted monosaccharide derivatives—radical activation of the carbon–chlorine-bond

2006 ◽  
Vol 341 (16) ◽  
pp. 2641-2652 ◽  
Author(s):  
Anita Wegert ◽  
Martin Hein ◽  
Helmut Reinke ◽  
Norbert Hoffmann ◽  
Ralf Miethchen
Keyword(s):  
Chlorine Bond

Mechanistic Analysis of Iridium Heteroatom C−H Activation:  Evidence for an Internal Electrophilic Substitution Mechanism

2007 ◽  
Vol 26 (7) ◽  
pp. 1565-1567 ◽  
Author(s):  
Jonas Oxgaard ◽  
William J. Tenn ◽  
Robert J. Nielsen ◽  
Roy A. Periana ◽  
William A. Goddard
Keyword(s):  
Electrophilic Substitution ◽  
Mechanistic Analysis ◽  
Substitution Mechanism

Catalytic deuterium exchange reactions with organics. XIII. Characteristic reactions of the Group VIII transition metals

1965 ◽  
Vol 18 (7) ◽  
pp. 1003 ◽  
Author(s):  
JL Garnett ◽  
WA Sollich
Keyword(s):  
Transition Metal ◽  
Hydrogen Exchange ◽  
Deuterium Oxide ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Group Viii ◽  
Exchange Reactions ◽  
Substitution Mechanism ◽  
Π Complex ◽  
Complex Adsorption

Activation procedures and hydrogen exchange reactions with six Group VIII transition metal catalysts (Pt, Pd, Ru, Rh, Ir, Ni) are reported for three characteristic reaction systems: (i) deuterium oxide/benzene, (ii) deuterium oxide/naphthalene, and (iii) deuterium oxide/n-octane. Results of these exchange reactions indicate that both π-complex adsorption and the dissociative π-complex substitution mechanism previously established for platinum are applicable to other Group VIII transition metal catalysts. For general catalytic labelling with isotopic hydrogen, platinum was found to be the most efficient of the catalysts investigated.

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