A New Route to Vinyl Phosphorus Derivatives by Formal Insertion of Phosphinidenes into the Carbon−Chlorine Bond of Chloroalkenes

2000 ◽  
Vol 65 (3) ◽  
pp. 652-654 ◽  
Author(s):  
Ngoc Hoa Tran Huy ◽  
François Mathey
Keyword(s):  
Chlorine Bond

Electrocatalytic cleavage of a carbon–chlorine bond by Re(IV)–chloro complex: a mechanistic insight from DFT

2021 ◽  
Author(s):  
Jamaladin Shakeri ◽  
Hassan Hadadzadeh ◽  
Hossein Farrokhpour ◽  
Matthias Weil ◽  
Mohammad Joshaghani
Keyword(s):  
Chloro Complex ◽  
Mechanistic Insight ◽  
Chlorine Bond

Chlorodifluoromethyl-substituted monosaccharide derivatives—radical activation of the carbon–chlorine-bond

2006 ◽  
Vol 341 (16) ◽  
pp. 2641-2652 ◽  
Author(s):  
Anita Wegert ◽  
Martin Hein ◽  
Helmut Reinke ◽  
Norbert Hoffmann ◽  
Ralf Miethchen
Keyword(s):  
Chlorine Bond

scholarly journals Transition-metal free umpolung carbon–nitrogen versus carbon–chlorine bond formation

2015 ◽  
Vol 56 (41) ◽  
pp. 5610-5612 ◽  
Author(s):  
John J. Sirois ◽  
Brenton DeBoef
Keyword(s):  
Transition Metal ◽  
Bond Formation ◽  
Metal Free ◽  
Chlorine Bond

scholarly journals Proteogenomics Reveals Novel Reductive Dehalogenases and Methyltransferases Expressed during Anaerobic Dichloromethane Metabolism

2019 ◽  
Vol 85 (6) ◽  
Author(s):  
Sara Kleindienst ◽  
Karuna Chourey ◽  
Gao Chen ◽  
Robert W. Murdoch ◽  
Steven A. Higgins ◽  
...  
Keyword(s):  
Amino Acid ◽  
Reductive Dechlorination ◽  
Bond Cleavage ◽  
Amino Acid Identity ◽  
Methyl Group ◽  
Acid Identity ◽  
Group Transfer ◽  
Degrading Bacterium ◽  
Chlorine Bond ◽  
Methyl Group Transfer

ABSTRACTDichloromethane (DCM) is susceptible to microbial degradation under anoxic conditions and is metabolized via the Wood-Ljungdahl pathway; however, mechanistic understanding of carbon-chlorine bond cleavage is lacking. The microbial consortium RM contains the DCM degrader “CandidatusDichloromethanomonas elyunquensis” strain RM, which strictly requires DCM as a growth substrate. Proteomic workflows applied to DCM-grown consortium RM biomass revealed a total of 1,705 nonredundant proteins, 521 of which could be assigned to strain RM. In the presence of DCM, strain RM expressed a complete set of Wood-Ljungdahl pathway enzymes, as well as proteins implicated in chemotaxis, motility, sporulation, and vitamin/cofactor synthesis. Four corrinoid-dependent methyltransferases were among the most abundant proteins. Notably, two of three putative reductive dehalogenases (RDases) encoded within strain RM’s genome were also detected in high abundance. Expressed RDase 1 and RDase 2 shared 30% amino acid identity, and RDase 1 was most similar to an RDase ofDehalococcoides mccartyistrain WBC-2 (AOV99960, 52% amino acid identity), while RDase 2 was most similar to an RDase ofDehalobactersp. strain UNSWDHB (EQB22800, 72% amino acid identity). Although the involvement of RDases in anaerobic DCM metabolism has yet to be experimentally verified, the proteome characterization results implicated the possible participation of one or more reductive dechlorination steps and methyl group transfer reactions, leading to a revised proposal for an anaerobic DCM degradation pathway.IMPORTANCENaturally produced and anthropogenically released DCM can reside in anoxic environments, yet little is known about the diversity of organisms, enzymes, and mechanisms involved in carbon-chlorine bond cleavage in the absence of oxygen. A proteogenomic approach identified two RDases and four corrinoid-dependent methyltransferases expressed by the DCM degrader “CandidatusDichloromethanomonas elyunquensis” strain RM, suggesting that reductive dechlorination and methyl group transfer play roles in anaerobic DCM degradation. These findings suggest that the characterized DCM-degrading bacteriumDehalobacterium formicoaceticumand “CandidatusDichloromethanomonas elyunquensis” strain RM utilize distinct strategies for carbon-chlorine bond cleavage, indicating that multiple pathways evolved for anaerobic DCM metabolism. The specific proteins (e.g., RDases and methyltransferases) identified in strain RM may have value as biomarkers for monitoring anaerobic DCM degradation in natural and contaminated environments.

Insertion of nitriles into the nitrogen-chlorine bond. Synthesis of polyfluoro- and (perfluoroalkyl)tetrazanes

1989 ◽  
Vol 28 (17) ◽  
pp. 3345-3349 ◽  
Author(s):  
Ghulam Sarwar ◽  
Robert L. Kirchmeier ◽  
Jean'ne M. Shreeve
Keyword(s):  
Chlorine Bond

Ab Initio Study of Carbon−Chlorine Bond Cleavage in Carbon Tetrachloride

2005 ◽  
Vol 39 (2) ◽  
pp. 612-617 ◽  
Author(s):  
Nianliu Zhang ◽  
Paul Blowers ◽  
James Farrell
Keyword(s):  
Carbon Tetrachloride ◽  
Ab Initio ◽  
Bond Cleavage ◽  
Ab Initio Study ◽  
Chlorine Bond

ChemInform Abstract: Tandem Carbon-Carbon and Carbon-Chlorine Bond Formation by Cu(II) Chloride-Promoted [3,3] Sigmatropic Rearrangement of N-Allylhydrazones.

ChemInform ◽  
2008 ◽  
Vol 39 (22) ◽  
Author(s):  
Devon A. Mundal ◽  
Jennifer J. Lee ◽  
Regan J. Thomson
Keyword(s):  
Bond Formation ◽  
Sigmatropic Rearrangement ◽  
Chlorine Bond

ChemInform Abstract: Transition-Metal Free Umpolung Carbon-Nitrogen versus Carbon-Chlorine Bond Formation.

ChemInform ◽  
2016 ◽  
Vol 47 (4) ◽  
pp. no-no
Author(s):  
John J. Sirois ◽  
Brenton DeBoef
Keyword(s):  
Transition Metal ◽  
Bond Formation ◽  
Metal Free ◽  
Chlorine Bond
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