Development of a Mineral Scale Inhibitor

CORROSION ◽  
1961 ◽  
Vol 17 (5) ◽  
pp. 232t-236t ◽  
Author(s):  
L. W. JONES

Abstract The expense attributable to scaling in oil producing operations totals many millions of dollars annually. Causes of precipitation and deposition are fairly well understood but better methods of control are needed. In order to evaluate chemical scale inhibitor components, a laboratory testing device was designed. Performance of sequestrants, surface active agents, colloids, and mixed compounds in the laboratory tester are discussed. Polyphosphates and sodium carboxymethyl cellulose proved effective for calcium carbonate scale and calcium sulfate scale, respectively. Results of tests made over a period of several years led to the development of an inhibitor composition that is capable of inhibiting both carbonate and sulfate scales. The inhibitor is now in field use. 5.8.2, 3.2.3, 8.4.3

RSC Advances ◽  
2016 ◽  
Vol 6 (46) ◽  
pp. 39883-39895 ◽  
Author(s):  
Ping Zhang ◽  
Dong Shen ◽  
Amy T. Kan ◽  
Mason B. Tomson

Developed calcium-phosphonate scale inhibitor reverse micelle nanomaterial for oilfield mineral scale control in low water cut or water sensitive wells.


Crystals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1494
Author(s):  
Yan Yan ◽  
Tao Yu ◽  
Huan Zhang ◽  
Jiayu Song ◽  
Chengtun Qu ◽  
...  

Co-precipitation of mineral-based salts during scaling remains poorly understood and thermodynamically undefined within the water industry. This study focuses on investigating calcium carbonate and calcium sulfate mixed precipitation in scaling. Scaling is often observed in the produced water supply as a result of treatment processes. Co-precipitation results were compared with experimental results of a single salt crystallization. Several parameters were carefully monitored, including the electrical conductivity, pH value, crystal morphology and crystal form. The existence of the calcium carbonate scale in the mixed system encourages the loose calcium sulfate scale to become more tightly packed. The mixed scale was firmly adhered to the beaker, and the adhesion of the co-deposition product was located between the pure calcium sulfate scale and the pure calcium carbonate scale. The crystalline form of calcium sulfate was gypsum in both pure material deposition and mixed deposition, while the calcium carbonate scale was stable in calcite form in the pure material deposition. In the co-deposition, apart from calcite form, some calcium carbonate scale crystals had metastable vaterite form. This indicated that the presence of SO42− ions reduced the energy barrier of the calcium carbonate scale and hindered its transformation from a vaterite form to a calcite one, and the increase in HCO3− content inhibited the formation of calcium sulfate scale.


2021 ◽  
Author(s):  
Jonathan J. Wylde ◽  
Alexander R. Thornton ◽  
Mark Gough ◽  
Rifky Akbar ◽  
William A. Bruckmann

Abstract A prolific Southeast Asia onshore oilfield has enjoyed scale free production for many years before recently experiencing a series of unexpected and harsh calcite scaling events. Well watercuts were barely measurable, yet mineral scale deposits accumulated quickly across topside wellhead chokes and within downstream flowlines. This paper describes the scale management experience, and the specific challenges presented by this extraordinarily low well water cut, low pH, calcium carbonate scaling environment. To the knowledge of the authors, no previous literature works have been published regarding such an unusual and aggressive mineral scale control scenario. A detailed analysis of the scaling experience is provided, including plant layout, scaling locations, scale surveillance and monitoring programs, laboratory testing, product selection and implementation, and scale inhibitor efficacy surveillance and monitoring programs. The surveillance and application techniques themselves are notable, and feature important lessons learned for addressing similar very low water cut and moderate pH calcium carbonate scaling scenarios. For example, under ultra-low watercut high temperature well production conditions, it was found that a heavily diluted scale inhibitor was necessary to achieve optimum scale control, and a detailed laboratory and field implementation process is described that led to this key learning lesson. The sudden and immediate nature of the occurrence demanded a fast-track laboratory testing approach to rapidly identify a suitable scale inhibitor for the high temperature topside calcium carbonate scaling scenario. The streamlined selection program is detailed, however what could not be readily tested for via conventional laboratory testing was the effect of <1% water cut, and how the product would perform in that environment. A risk-managed field surveillance program was initiated to determine field efficiency of the identified polymeric scale inhibitor and involved field-trialing on a single well using a temporary restriction orifice plate (ROP) to modify the residence time of the injected chemical. The technique proved very successful and identifed that product dispersibility was important, and that dilution of the active scale inhibitor had a positive effect on dispersibility for optimum inhibitor action. The lessons learned were rolled out to all at-risk field producers with positive results. The ongoing success of this program continues and will be detailed in the manuscript and presentation. This paper demonstrates a unique situation of calcium carbonate scale formation and control that utilized a previously unreported and analytical surveillance approach. The cumulative performance derived by improving not only chemical selection, but the way the wells were managed via surveillance and chemical management decision making processes is compelling and of value to other production chemists working in the scaling arena.


2013 ◽  
Vol 850-851 ◽  
pp. 1368-1371
Author(s):  
Bing Xin Du ◽  
Kun Huang

Introduce several examples of surface active agents used in wet-process phosphoric acid (WPPA) to show its effect on the quality of phosphogypsum. Summarized both domestic and foreign methods of comprehensive utilization of phosphogypsum, such as being made into calcium sulfate whisker, building materials, soil improvement agent, chemical raw materials and etc. Some problems of resources utilization of phosphogypsum in China are summarized, and reasonable suggestions are put forward.


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