Unusually Short Bond Length and Large Amplitude Intramolecular Motion in Crystals.

The observed direction of thermal motion of the oxygen atoms in calcite can be explained if the environment of the calcium atom is taken into consideration as well as the CO3 group. Rotation of Ca octahedra accompanied by an alternate steepening and flattening which retains the {\bar 3} point-symmetry and the Ca–O bond-length unchanged is associated with a screw-like movement of CO3 in which rotation in its own plane is geared to translation perpendicular to its plane. Concerted movements of all atoms in the structure satisfying these requirements can be described in terms of a single-oscillating parameter; they represent a single lattice mode. They are predictable using the assumption that small departures, in the `static' structure, of particular position parameters from ideal values indicate weaknesses of a kind that allow a large amplitude to vibrations in which the same parameters oscillate about their `static' value. Comparison of CaCo3 and the isomorphous NaNO3 with LaAlO3 and LiNbO3, which have very similar formal geometry but great differences in relative bond strength, helps to illustrate the principle involved.

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On nearly-commensurable periods in the restricted problem of three bodies, with calculations of the long-period variations in the interior 2:1 case

Symposium - International Astronomical Union ◽

10.1017/s0074180900105480 ◽

1966 ◽

Vol 25 ◽

pp. 197-222 ◽

Cited By ~ 4

Author(s):

P. J. Message

Keyword(s):

Periodic Solution ◽

Periodic Solutions ◽

Large Amplitude ◽

Restricted Problem ◽

Small Amplitude ◽

Minor Planets ◽

Long Period ◽

Numerical Integrations ◽

Period Variations ◽

The Mean

An analytical discussion of that case of motion in the restricted problem, in which the mean motions of the infinitesimal, and smaller-massed, bodies about the larger one are nearly in the ratio of two small integers displays the existence of a series of periodic solutions which, for commensurabilities of the typep+ 1:p, includes solutions of Poincaré'sdeuxième sortewhen the commensurability is very close, and of thepremière sortewhen it is less close. A linear treatment of the long-period variations of the elements, valid for motions in which the elements remain close to a particular periodic solution of this type, shows the continuity of near-commensurable motion with other motion, and some of the properties of long-period librations of small amplitude.To extend the investigation to other types of motion near commensurability, numerical integrations of the equations for the long-period variations of the elements were carried out for the 2:1 interior case (of which the planet 108 “Hecuba” is an example) to survey those motions in which the eccentricity takes values less than 0·1. An investigation of the effect of the large amplitude perturbations near commensurability on a distribution of minor planets, which is originally uniform over mean motion, shows a “draining off” effect from the vicinity of exact commensurability of a magnitude large enough to account for the observed gap in the distribution at the 2:1 commensurability.

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Information and estimation in image processing

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100125142 ◽

1987 ◽

Vol 45 ◽

pp. 14-17

Author(s):

B. Roy Frieden

Keyword(s):

Image Processing ◽

Optical System ◽

Large Amplitude ◽

Communication Theory ◽

Image Data ◽

Direct Approach ◽

Ill Posed

Despite the skill and determination of electro-optical system designers, the images acquired using their best designs often suffer from blur and noise. The aim of an “image enhancer” such as myself is to improve these poor images, usually by digital means, such that they better resemble the true, “optical object,” input to the system. This problem is notoriously “ill-posed,” i.e. any direct approach at inversion of the image data suffers strongly from the presence of even a small amount of noise in the data. In fact, the fluctuations engendered in neighboring output values tend to be strongly negative-correlated, so that the output spatially oscillates up and down, with large amplitude, about the true object. What can be done about this situation? As we shall see, various concepts taken from statistical communication theory have proven to be of real use in attacking this problem. We offer below a brief summary of these concepts.

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