Ionic Conductivity Enhancement Studies Of Composite Polymer Electrolyte Based On Poly (Vinyl Alcohol)-Lithium Perchlorate-Titanium Oxide

2017 ◽  
Vol 8 (4) ◽  
pp. 465-471 ◽  
Author(s):  
Chin-Shen. Lim
2017 ◽  
Vol 5 (25) ◽  
pp. 12934-12942 ◽  
Author(s):  
Ouwei Sheng ◽  
Chengbin Jin ◽  
Jianmin Luo ◽  
Huadong Yuan ◽  
Cong Fang ◽  
...  

The solid-state Li–S batteries using N-CNs/S cathode and composite polymer electrolyte added IL@ZrO2can work at the human body temperature of 37 °C.


2021 ◽  
Vol 8 ◽  
Author(s):  
Qiongyu Zhou ◽  
Songli Liu ◽  
Shiju Zhang ◽  
Yong Che ◽  
Li-Hua Gan

Compared with the fagile ceramic solid electrolyte, Li-ion conducting polymer electrolytes are flexible and have better contact with electrodes. However, the ionic conductivity of the polymer electrolytes is usually limited because of the slow segment motion of the polymer. In this work, we introduce porous Co3O4 cuboids to Poly (Ethylene Oxide)-based electrolyte (PEO) to investigate the influence of these cuboids on the ionic conductivity of the composite electrolyte and the performance of the all-solid-state batteries. The experiment results showed the porous cuboid Co3O4 fillers not only break the order motion of segments of the polymer to increase the amorphous phase amount, but also build Li+ continuous migration pathway along the Co3O4 surface by the Lewis acid-base interaction. The Li+ conductivity of the composite polymer electrolyte reaches 1.6 × 10−4 S cm−1 at 30°C. The good compatibility of the composite polymer electrolyte to Li metal anode and LiFePO4 cathode ensures good rate performance and long cycle life when applying in an all-solid-state LiFePO4 battery. This strategy points out the direction for developing the high-conducting composite polymer electrolytes for all-solid-state batteries.


2018 ◽  
Vol 49 (2) ◽  
pp. 360-367 ◽  
Author(s):  
Xun Wang ◽  
Jingjing Yang ◽  
Le Shao ◽  
Jiaojiao Li ◽  
Weifeng Zhao ◽  
...  

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