Field evidence for coal combustion links the 252 My-old Siberian Traps with global carbon disruption

Author(s):  
Linda Elkins-Tanton ◽  
Steven Grasby ◽  
Benjamin Black ◽  
Roman Veselovskiy ◽  
Omid Ardakani ◽  
...  

<p>The Permo-Triassic Extinction was the most severe in Earth history. The Siberian Traps eruptions are strongly implicated in the global atmospheric changes that likely drove the extinction. A sharp negative carbon isotope excursion coincides within geochronological uncertainty with the oldest dated rocks from the Norilsk section of the Siberian flood basalts. The source of this light carbon has been debated for decades.</p><p>We focused on the voluminous volcaniclastic rocks of the Siberian Traps, relatively unstudied as potential carriers of carbon-bearing gases. Over six field seasons we collected rocks from across the Siberian platform and show the first direct evidence that the earliest eruptions particularly in the southern part of the province burned large volumes of a combination of vegetation and coal. Samples from the Maymecha-Kotuy region, from the Nizhnyaya Tunguska, Podkamennaya Tunguska, and Angara Rivers all show evidence of high-temperature organic matter carbonization and combustion.</p><p>Field evidence indicates a process in which ascending magmas entrain xenoliths of coal and carbonaceous sediments that are carbonized in the subsurface and also combusted either through reduction of magmas or when exposed to the atmosphere. We demonstrate that the volume and composition of organic matter interactions with magmas may explain the global carbon isotope signal, and have significantly driven the extinction.</p>

Geology ◽  
2020 ◽  
Vol 48 (10) ◽  
pp. 986-991 ◽  
Author(s):  
L.T. Elkins-Tanton ◽  
S.E. Grasby ◽  
B.A. Black ◽  
R.V. Veselovskiy ◽  
O.H. Ardakani ◽  
...  

Abstract The Permian-Triassic extinction was the most severe in Earth history. The Siberian Traps eruptions are strongly implicated in the global atmospheric changes that likely drove the extinction. A sharp negative carbon isotope excursion coincides within geochronological uncertainty with the oldest dated rocks from the Norilsk section of the Siberian flood basalts. We focused on the voluminous volcaniclastic rocks of the Siberian Traps, relatively unstudied as potential carriers of carbon-bearing gases. Over six field seasons we collected rocks from across the Siberian platform, and we show here the first direct evidence that the earliest eruptions in the southern part of the province burned large volumes of a combination of vegetation and coal. We demonstrate that the volume and composition of organic matter interacting with magmas may explain the global carbon isotope signal and may have significantly driven the extinction.


2000 ◽  
Vol 162 (3-4) ◽  
pp. 211-223 ◽  
Author(s):  
Matthew R. Saltzman ◽  
Robert L. Ripperdan ◽  
M.D. Brasier ◽  
Kyger C. Lohmann ◽  
Richard A. Robison ◽  
...  

2016 ◽  
Vol 128 (9-10) ◽  
pp. 1352-1366 ◽  
Author(s):  
Allison A. Baczynski ◽  
Francesca A. McInerney ◽  
Scott L. Wing ◽  
Mary J. Kraus ◽  
Paul E. Morse ◽  
...  

2004 ◽  
Vol 1 (1) ◽  
pp. 393-412 ◽  
Author(s):  
F. Keppler ◽  
R. M. Kalin ◽  
D. B. Harper ◽  
W. C. McRoberts ◽  
J. T. G. Hamilton

Abstract. We report that the most abundant C1 units of terrestrial plants, the methoxyl groups of pectin and lignin, have a unique carbon isotope signature exceptionally depleted in 13C. Plant-derived C1 volatile organic compounds (VOCs) are also anomalously depleted in 13C compared with Cn+1 VOCs. The results confirm that the plant methoxyl pool is the predominant source of biospheric C1 compounds of plant origin such as methanol, chloromethane and bromomethane. Furthermore this pool, comprising ca. 2.5% of carbon in plant biomass, represents an important substrate for methanogenesis and could be a significant source of isotopically light methane entering the atmosphere. Our findings have significant implications for the use of carbon isotope ratios in elucidation of global carbon cycling. Moreover methoxyl groups could act as markers for biological activity in organic matter of terrestrial and extraterrestrial origin.


Geology ◽  
2021 ◽  
Vol 49 (3) ◽  
pp. e518-e518
Author(s):  
Linda T. Elkins-Tanton ◽  
S.E. Grasby ◽  
B.A. Black ◽  
R.V. Veselovskiy ◽  
O.H. Ardakani ◽  
...  

2004 ◽  
Vol 1 (2) ◽  
pp. 123-131 ◽  
Author(s):  
F. Keppler ◽  
R. M. Kalin ◽  
D. B. Harper ◽  
W. C. McRoberts ◽  
J. T. G. Hamilton

Abstract. We report that the most abundant C1 units of terrestrial plants, the methoxyl groups of pectin and lignin, have a unique carbon isotope signature exceptionally depleted in 13C. Plant-derived C1 volatile organic compounds (VOCs) are also anomalously depleted in 13C compared with Cn+1 VOCs. The results confirm that the plant methoxyl pool is the predominant source of biospheric C1 compounds of plant origin such as methanol, chloromethane and bromomethane. Furthermore this pool, comprising ca 2.5% of carbon in plant biomass, could be an important substrate for methanogenesis and thus be envisaged as a possible source of isotopically light methane entering the atmosphere. Our findings have significant implications for the use of carbon isotope ratios in elucidation of global carbon cycling. Moreover methoxyl groups could act as markers for biological activity in organic matter of terrestrial and extraterrestrial origin.


Geology ◽  
2021 ◽  
Vol 49 (3) ◽  
pp. e517-e517
Author(s):  
Vladimir I. Davydov ◽  
Eugeny V. Karasev ◽  
Veronika V. Zharinova

2011 ◽  
Vol 59 ◽  
pp. 100-115
Author(s):  
Christoph Korte ◽  
Heinz W. Kozur

Carbon isotope trends are useful for stratigraphic correlation, especially for time intervals when major perturbations of the global carbon cycle occurred. Such perturbations have been documented for the Triassic–Jurassic (T–J) boundary, and several successions from this time interval are characterized by (1) an initial negative excursion, followed by (2) a pronounced positive excursion and a subsequent (3) main negative carbon isotope excursion. These features, however, are not present in all T–J boundary sections, or the stratigraphic position of the positive or the main negative excursion has variable locations. In the present study, we analysed carbon isotopes in bulk carbonate from the pelagic Csővár quarry section in Hungary and from the intra-platform basin to shallow subtidal marine Kendlbachgraben section in Austria. Both T–J boundary successions are biostratigraphically well controlled enabling – with particular focus on the bio- and chemostratigraphy of other T–J boundary sections – correlation of the carbon isotope trends. This evaluation shows that the apex of the initial negative δ13C excursion occurred slightly, but distinctly, below the mass extinction event and represents an excellent stratigraphic correlation tool.


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