Portable optically stimulated luminescence age map of a paleoseismic exposure

The quality and quantity of geochronologic data used to constrain the history of major earthquakes in a region exerts a first-order control on the accuracy of seismic hazard assessments that affect millions of people. However, evaluations of geochronological data are limited by uncertainties related to inherently complex depositional processes that may vary spatially and temporally. To improve confidence in models of earthquake timing, we use a high-density suite of radiocarbon and optically stimulated luminescence (OSL) ages with a grid of 342 portable OSL samples to explore spatiotemporal trends in geochronological data across an exemplary normal fault colluvial wedge exposure. The data reveal a two-dimensional age map of the paleoseismic exposure and demonstrate how vertical and horizontal trends in age relate to dominant sedimentary facies and soil characteristics at the site. Portable OSL data provide critical context for the interpretation of 14C and OSL ages, show that geochronologic age boundaries between pre- and post-earthquake deposits do not match stratigraphic contacts, and provide the basis for selecting alternate Bayesian models of earthquake timing. Our results demonstrate the potential to use emergent, portable OSL methods to dramatically improve paleoseismic constraints on earthquake timing.

A red bole zircon record of cryptic silicic volcanism in the Deccan Traps, India

Silicic magmas within large igneous provinces (LIPs) are understudied relative to volumetrically dominant mafic magmas despite their prevalence and possible contribution to LIP-induced environmental degradation. In the 66 Ma Deccan LIP (India), evolved magmatism is documented, but its geographic distribution, duration, and significance remain poorly understood. Zircons deposited in weathered Deccan lava flow tops (“red boles”) offer a means of indirectly studying potentially widespread, silicic, explosive volcanism spanning the entire period of flood basalt eruptions. We explored this record through analysis of trace elements and Hf isotopes in zircon crystals previously dated by U–Pb geochronology. Our results show that zircon populations within individual red boles fingerprint distinct volcanic sources that likely developed in an intraplate setting on cratonic Indian lithosphere. However, our red bole zircon geochemical and isotopic characteristics do not match those from previously studied silicic magmatic centers, indicating that they must derive from yet undiscovered or understudied volcanic centers associated with the Deccan LIP.

Experimental evidence on the origin of Ca-rich carbonated melts formed by interaction between sedimentary limestones and mantle-derived ultrabasic magmas

In this experimental study, we documented the formation of strongly ultrabasic and ultracalcic melts through the interaction of melilititic and basanitic melts with calcite. Three strongly to moderately SiO2-undersaturated volcanic rocks from the Bohemian Massif (central Europe) were mixed with 10, 30, and 50 wt% CaCO3 and melted at 1100, 1200, and 1300 °C at 2 kbar to evaluate the maximum amount of carbonate that can be assimilated by natural ultrabasic melts at shallow depths. Experiments revealed a surprisingly complete dissolution of the CaCO3, only rarely reaching carbonate saturation, with typical liquidus phases represented by olivine, spinel, melilite, and clinopyroxene. Only in the runs with the most SiO2-undersaturated compositions did abundant monticellite form instead of clinopyroxene. For all starting mixtures, strongly ultrabasic (SiO2 down to 15.6 wt%), lime-rich (CaO up to 43.6 wt%), ultracalcic (CaO/Al2O3 up to ~27) melt compositions were produced at 1200 and 1300 °C, with up to ~25 wt% dissolved CO2. When present, quenched olivine showed much higher forsterite content (Fo95–97) than olivine in the natural samples (Fo79–85). The two major results of this study are (1) silicate-carbonatite melt compositions do not necessarily imply the existence of carbonatitic components in the mantle, because they are also produced during limestone assimilation, and (2) Fo-rich olivines cannot be used to infer any primitive character of the melt nor high potential temperature (Tp).

Are fluid inclusions in gypsum reliable paleoenvironmental indicators? An assessment of the evidence from the Messinian evaporites

The paleosalinity of water from which the gypsum precipitated during the Messinian salinity crisis is a controversial issue. Recent microthermometry studies on primary fluid inclusions in gypsum provided very low salinity values not compatible with precipitation from seawater, and suggested strong mixing between seawater and nonmarine waters enriched in calcium sulfate. We applied a new microthermometric protocol on gypsum crystals from nine Mediterranean sections that were experimentally stretched to measure a larger population of fluid inclusions. The results show salinities ranging from 9 to 238 wt‰ NaCl equivalent, largely falling within the evaporation path of normal seawater. The data from previous studies were obtained mostly from those fluid inclusions capable of nucleating a stable bubble after a weak stretching, which probably correspond to those having a lower salinity acquired through post-depositional crack-and-seal processes. Our data suggest instead that the primary gypsum precipitated from a marine brine, later modified by post-trapping processes during tectonics and exhumation.

Two-pronged kill mechanism at the end-Triassic mass extinction

High-resolution biomarker and compound-specific isotope distributions coupled with the degradation of calcareous fossil remnants reveal that intensive euxinia and decalcification (acidification) driven by Central Atlantic magmatic province (CAMP) activity formed a two-pronged kill mechanism at the end-Triassic mass extinction. In a newly proposed extinction interval for the basal Blue Lias Formation (Bristol Channel Basin, UK), biomarker distributions reveal an episode of persistent photic zone euxinia (PZE) that extended further upward into the surface waters. In the same interval, shelly taxa almost completely disappear. Beginning in the basal paper shales of the Blue Lias Formation, a Lilliput assemblage is preserved consisting of only rare calcitic oysters (Liostrea) and ghost fossils of decalcified aragonitic bivalves. The stressors of PZE and decalcification parsimoniously explain the extinction event and inform possible combined causes of other biotic crises linked to emplacement of large igneous provinces, notably the end-Permian mass extinction, when PZE occurred on a broad and perhaps global scale.

Magma recharge patterns control eruption styles and magnitudes at Popocatépetl volcano (Mexico)

Diffusion chronometry has produced petrological evidence that magma recharge in mafic to intermediate systems can trigger volcanic eruptions within weeks to months. However, less is known about longer-term recharge frequencies and durations priming magma reservoirs for eruptions. We use Fe-Mg diffusion modeling in orthopyroxene to show that the duration, frequency, and timing of pre-eruptive recharge at Popocatépetl volcano (Mexico) vary systematically with eruption style and magnitude. Effusive eruptions are preceded by 9–13 yr of increased recharge activity, compared to 15–100 yr for explosive eruptions. Explosive eruptions also record a higher number of individual recharge episodes priming the plumbing system. The largest explosive eruptions are further distinguished by an ~1 yr recharge hiatus directly prior to eruption. Our results offer valuable context for the interpretation of ongoing activity at Popocatépetl, and seeking similar correlations at other arc volcanoes may advance eruption forecasting by including constraints on potential eruption size and style.

Multi-proxy evidence of Caribbean-sourced marine incursions in the Neogene of Western Amazonia, Brazil

The timing of continental-scale marine flooding events in Western Amazonia during the Neogene is still an unsolved question. Despite broad proxy-based evidence of such events, the pathways and duration of late Miocene marine incursions remain controversial. We provide coupled calcareous and organic microfossil and geochemical data from six onshore cores from Neogene sequences of the Solimões Basin, Brazil. Our records support minor marine influence in the early Miocene (23.0, 21.1, 18.6, and 16.3 Ma), middle Miocene (14.9, 13.7, and 12.9 Ma) and early Pliocene (4.7, 4.2–4.1, and 3.8 Ma), and conspicuous marine incursions in the late Miocene (11.1–8.8 Ma) suggested by the consistent presence of salinity-indicative microfossils and geochemical data. Our findings challenge the view of major marine incursions in the early and middle Miocene in the studied area. We propose for the first time a new late Miocene incursion (LMI) event as the main marine flooding event in Western Amazonia during the Neogene. These onshore records are compared with three offshore cores from the Atlantic and Pacific Oceans. The similarity between microfossil assemblages of the Solimões Basin and the Caribbean Sea, and evidence of increased runoff from the Orinoco river drainage system, strongly suggest the Caribbean Sea as the primary source area of the marine incursions, supporting a Venezuelan seaway. We further show for the first time the potential linkage between Neogene marine incursions (mainly the LMI) into the Solimões Basin and major disturbances in the global carbon cycle.

Crustal thickness of the Grenville orogen: A Mesoproterozoic Tibet?

The Grenville Province on the eastern margin of Laurentia is a remnant of a Mesoproterozoic orogenic plateau that comprised the core of the ancient supercontinent Rodinia. As a protracted Himalayan-style orogen, its orogenic history is vital to understanding Mesoproterozoic tectonics and paleoenvironmental evolution. In this study, we compared two geochemical proxies for crustal thickness: whole-rock [La/Yb]N ratios of intermediate-to-felsic rocks and europium anomalies (Eu/Eu*) in detrital zircons. We compiled whole-rock geochemical data from 124 plutons in the Laurentian Grenville Province and collected trace-element and geochronological data from detrital zircons from the Ottawa and St. Lawrence River (Canada) watersheds. Both proxies showed several episodes of crustal thickening and thinning during Grenvillian orogenesis. The thickest crust developed in the Ottawan phase (~60 km at ca. 1080 Ma and ca. 1045 Ma), when the collision culminated, but it was still up to 20 km thinner than modern Tibet. We speculate that a hot crust and several episodes of crustal thinning prevented the Grenville hinterland from forming a high Tibet-like plateau, possibly due to enhanced asthenosphere-lithosphere interactions in response to a warm mantle beneath a long-lived supercontinent, Nuna-Rodinia.

When did the North Anatolian fault reach southern Marmara, Turkey?

We dated syntectonic calcites on fault planes from the southern branch of the western North Anatolian fault (NAF) in northern Turkey using U-Th geochronology. We selected strike-slip faults that are kinematically related to the current regional strain field. The isotopic ages cluster around different periods during the past ~700 k.y. The most prominent cluster peak of 510.5 ± 9.5 ka (1σ) is consistent with the maximum cumulative strike-slip offset data and tectonic plate motions measured by GPS data, highlighting the fact that the present configuration of the NAF in the southern Marmara region started at ca. 500 ka or earlier. These new isotopic ages, combined with previous considerations of regional tectonics, reveal that faulting along the western NAF initiated primarily in the southern Marmara region at least a few hundred thousand years earlier than the timing suggested for the northern branch of the western NAF. This study presents an innovative approach to constrain the timing of initiation of currently active fault segments along the NAF in southern Marmara. U-Th geochronology of fault-hosted calcite thus has a wide application in determining absolute ages of fault episodes in wider shear zones along plate boundaries.