scholarly journals Supplementary material to "Identifying global patterns of stochasticity and nonlinearity in the Earth System"

2016 ◽  
Author(s):  
Fernando Arizmendi ◽  
Marcelo Barreiro ◽  
Cristina Masoller
Keyword(s):  
Earth System ◽  
The Earth ◽  
Supplementary Material ◽  
Global Patterns

Iron and sulphur speciation and cycling in the sediments of marine systems located in the arid environment: Case of the northern Red Sea

2021 ◽  
pp. jgs2021-027
Author(s):  
Valeria Boyko ◽  
Jürgen Pätzold ◽  
Alexey Kamyshny
Keyword(s):  
Red Sea ◽  
Water Depth ◽  
Iron Content ◽  
Gulf Of Aqaba ◽  
Earth System ◽  
Content Type ◽  
Reactive Iron ◽  
The Earth ◽  
Sulphur Cycle ◽  
Supplementary Material

High fluxes of iron minerals associated with aeolian dry deposition may result in anomalously high reactive iron content and fast reoxidation of hydrogen sulphide in the sediments that prevents pyrite formation and results in “cryptic” sulphur cycle. In this work, we studied cycling of iron and sulphur in the deep-water (> 800 m water depth) sediments of the Red Sea and its northern extension, Gulf of Aqaba. We found that reactive iron content in the surface sediments of the Gulf of Aqaba and the Red Sea is high, while the content of sulphur-bound iron is very low and decreases with water depth. The presence of pyrite traces and zero-valent sulfur as well as isotopic compositions of sulphate and pyrite, which are consistent with sulphate reduction under substrate-limiting conditions, suggest that cryptic sulfur cycling is likely to be a result of fast reoxidation of hydrogen sulfide rather than microbial sulfate reduction suppression. In the sediments of Shaban Deep, which are overlain with hyper-saline hydrothermal brine, low reactive iron and high organic carbon contents result in a non-cryptic sulphur cycle characterized by preservation of pyrite in the sediments.Thematic collection: This article is part of the Sulfur in the Earth system collection available at: https://www.lyellcollection.org/cc/sulfur-in-the-earth-systemSupplementary material:https://doi.org/10.6084/m9.figshare.c.5508155

scholarly journals Identifying global patterns of stochasticity and nonlinearity in the Earth System

2016 ◽  
Author(s):  
Fernando Arizmendi ◽  
Marcelo Barreiro ◽  
Cristina Masoller
Keyword(s):  
Time Series ◽  
Extreme Values ◽  
Surface Air Temperature ◽  
Reanalysis Data ◽  
Earth System ◽  
Entropy Analysis ◽  
Solar Forcing ◽  
The Earth ◽  
Geographical Regions ◽  
Global Patterns

Abstract. By comparing time-series of surface air temperature (SAT, monthly reanalysis data from NCEP CDAS1 and ERA Interim) with respect to the top-of-atmosphere incoming solar radiation (the insolation), we perform a detailed analysis of the SAT response to solar forcing. By computing the entropy of SAT time-series, we also quantify the degree of stochasticity. We find spatial coherent structures which are characterized by high stochasticity and nearly linear response to solar forcing (the shape of SAT time-series closely follows that of the isolation), or vice versa. The entropy analysis also allows to identify geographical regions in which there are significant differences between the NCEP CDAS1 and ERA Interim datasets, which are due to the presence of extreme values in one dataset but not in the other. Therefore, entropy maps are a valuable tool for anomaly detection and model inter-comparisons.

Dynamic interplay of biogeochemical C, S, and Ba cycles in response to Shuram oxygenation event

2021 ◽  
pp. jgs2021-081
Author(s):  
Huan Cui ◽  
Alan J. Kaufman ◽  
Shuhai Xiao ◽  
Chuanming Zhou ◽  
Maoyan Zhu ◽  
...  
Keyword(s):  
Earth System ◽  
Content Type ◽  
Sulfate Minerals ◽  
Link Type ◽  
Carbonate Associated Sulfate ◽  
Microbial Sulfate Reduction ◽  
The Earth ◽  
Seawater Sulfate ◽  
Supplementary Material ◽  
Dynamic Interplay

Compared with Phanerozoic strata, sulfate minerals are relatively rare in the Precambrian record likely due to the lower concentrations of sulfate in dominantly anoxic oceans. Here, we present a compilation of sulfate minerals that are stratigraphically associated with the Ediacaran Shuram excursion (SE) — the largest negative δ13C excursion in Earth history. We evaluated 15 SE sections, all of which reveal the presence of sulfate minerals and/or concentration enrichment in carbonate-associated sulfate, suggesting a rise in sulfate reservoir. Notably, where data are available, the SE also reveals considerable enrichments in [Ba] relative to pre- and post-SE intervals. We propose that elevated seawater sulfate concentrations during the SE may have faciliated authigenesis of sulfate minerals. At the same time, the rise of Ba concentrations in shelf environments further facilitated barite deposition. A larger sulfate reservoir would stimulate microbial sulfate reduction and anaerobic oxidation of organic matter (including methane), contributing to the genesis of the SE. The existence of sulfate minerals throughout the SE suggests that oxidant pools were not depleted at that time, which challenges previous modelling results. Our study highlights the dynamic interplay of biogeochemical C, S, and Ba cycles in response to the Shuram oxygenation event.Thematic collection: This article is part of the Sulfur in the Earth system collection available at: https://www.lyellcollection.org/cc/sulfur-in-the-earth-systemSupplementary material:https://doi.org/10.6084/m9.figshare.c.5602560

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