scholarly journals Supplementary material to "Evidence for old carbon contamination in <sup>14</sup>C wiggle-match age series for the 946 CE eruption of Changbaishan volcano"

Author(s):  
Richard N. Holdaway ◽  
Ben Kennedy ◽  
Brendan M Duffy ◽  
Jiandong Xu ◽  
Clive Oppenheimer
2021 ◽  
Author(s):  
Richard N. Holdaway ◽  
Ben Kennedy ◽  
Brendan M Duffy ◽  
Jiandong Xu ◽  
Clive Oppenheimer

Abstract. Volcanic eruptions that are not historically attested are commonly radiocarbon dated by "wiggle matching" sequential 14C measurements of the rings of trees killed by the eruption against an accepted calibration curve. It is generally assumed that carbon laid down in the wood is uncontaminated by 14C-free ("old") carbon, although evidence for contamination is well documented. Often, ill-fitting ring ages are excluded from analysis. The ‘Millennium Eruption' of Changbaishan volcano on the China-DPR Korea border offers a valuable case study in wiggle match dating, since several independent groups reported age estimates before the determination and acceptance of a precise eruption year of 946 CE. Some of the discrepancies and incompatibilities between published dates were attributed to old carbon effects. Here, we apply a new methodology to correct for contamination levels of up to 4.5% old carbon to eight wiggle match date series for the Millennium Eruption. Without discarding ring ages, we find agreement indices as high as, or higher than, those for the published dates, and five of the eight date series yielded high-agreement-index eruption dates closer to 946 CE than the published dates. None of the five yield a best result at zero contamination. Differences between the eruption dates reveal a weak association with the direction of the sampled tree from the caldera, but no relationship with distance. Our results suggest that old carbon contamination is possible over a wide area, potentially leading to over-estimation of eruption ages by years, decades or more, cautioning against over-reliance on wiggle-match ages that are not corroborated by other lines of evidence. Our revised protocol that accounts for contamination offers a way forward in the application of wiggle match dating of eruptions and provides a platform for understanding discrepancies that exist when comparing wiggle match series.


Author(s):  
Indah Pratiwi ◽  
Yanti Sri Rezeki

This research aims to design workbook based on the scientific approach for teaching writing descriptive text. This research was conducted on the seventh-grade students of SMPN 24 Pontianak. The method of this research is ADDIE (Analysis, Design, Development, Implementation, and Evaluation) with the exclusion of Implementation and Evaluation phases. This material was designed as supplementary material to support the course book used especially in teaching writing of descriptive text. The respondents in this research were the seventh-grade students and an English teacher at SMPN 24 Pontianak. In this research, the researchers found that workbook based on scientific approach fulfilled the criteria of the good book to teach writing descriptive text. The researchers conducted an internal evaluation to see the usability and the feasibility of the workbook. The result of the evaluation is 89%. It showed that the workbook is feasible to be used by students as the supplementary material to support the main course book and help the students improve their writing ability in descriptive text.


2019 ◽  
Author(s):  
Oriol Planas ◽  
Feng Wang ◽  
Markus Leutzsch ◽  
Josep Cornella

The ability of bismuth to maneuver between different oxidation states in a catalytic redox cycle, mimicking the canonical organometallic steps associated to a transition metal, is an elusive and unprecedented approach in the field of homogeneous catalysis. Herein we present a catalytic protocol based on bismuth, a benign and sustainable main-group element, capable of performing every organometallic step in the context of oxidative fluorination of boron compounds; a territory reserved to transition metals. A rational ligand design featuring hypervalent coordination together with a mechanistic understanding of the fundamental steps, permitted a catalytic fluorination protocol based on a Bi(III)/Bi(V) redox couple, which represents a unique example where a main-group element is capable of outperforming its transition metal counterparts.<br>A main text and supplementary material have been attached as pdf files containing all the methodology, techniques and characterization of the compounds reported.<br>


2021 ◽  
Vol 295 ◽  
pp. 126433
Author(s):  
Qiang Wang ◽  
Jingjing Li ◽  
Jiakang Zhang ◽  
Peng Wu ◽  
Xianjun Lyu ◽  
...  

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