Resin Cement–Zirconia Bond Strengthening by Exposure to Low-Temperature Atmospheric Pressure Multi-Gas Plasma

The purpose of this study was to investigate the effect of gas species used for low-temperature atmospheric pressure plasma surface treatment, using various gas species and different treatment times, on zirconia surface state and the bond strength between zirconia and dental resin cement. Three groups of zirconia specimens with different surface treatments were prepared as follows: untreated group, alumina sandblasting treatment group, and plasma treatment group. Nitrogen (N2), carbon dioxide (CO2), oxygen (O2), argon (Ar), and air were employed for plasma irradiation. The bond strength between each zirconia specimen and resin cement was compared using a tension test. The effect of the gas species for plasma irradiation on the zirconia surface was investigated using a contact angle meter, an optical interferometer, an X-ray diffractometer, and X-ray photoelectric spectroscopy. Plasma irradiation increased the wettability and decreased the carbon contamination on the zirconia surface, whereas it did not affect the surface topography and crystalline phase. The bond strength varied depending on the gas species and irradiation time. Plasma treatment with N2 gas significantly increased bond strength compared to the untreated group and showed a high bond strength equivalent to that of the sandblasting treatment group. The removal of carbon contamination from the zirconia surface and an increase in the percentage of Zr-O2 on the zirconia surface by plasma irradiation might increase bond strength.

Evidence for old carbon contamination in ¹⁴C wiggle-match age series for the 946 CE eruption of Changbaishan volcano

Volcanic eruptions that are not historically attested are commonly radiocarbon dated by "wiggle matching" sequential 14C measurements of the rings of trees killed by the eruption against an accepted calibration curve. It is generally assumed that carbon laid down in the wood is uncontaminated by 14C-free ("old") carbon, although evidence for contamination is well documented. Often, ill-fitting ring ages are excluded from analysis. The ‘Millennium Eruption' of Changbaishan volcano on the China-DPR Korea border offers a valuable case study in wiggle match dating, since several independent groups reported age estimates before the determination and acceptance of a precise eruption year of 946 CE. Some of the discrepancies and incompatibilities between published dates were attributed to old carbon effects. Here, we apply a new methodology to correct for contamination levels of up to 4.5% old carbon to eight wiggle match date series for the Millennium Eruption. Without discarding ring ages, we find agreement indices as high as, or higher than, those for the published dates, and five of the eight date series yielded high-agreement-index eruption dates closer to 946 CE than the published dates. None of the five yield a best result at zero contamination. Differences between the eruption dates reveal a weak association with the direction of the sampled tree from the caldera, but no relationship with distance. Our results suggest that old carbon contamination is possible over a wide area, potentially leading to over-estimation of eruption ages by years, decades or more, cautioning against over-reliance on wiggle-match ages that are not corroborated by other lines of evidence. Our revised protocol that accounts for contamination offers a way forward in the application of wiggle match dating of eruptions and provides a platform for understanding discrepancies that exist when comparing wiggle match series.

Quantification of Carbonic Contamination of Fused Silica Surfaces at Different Stages of Classical Optics Manufacturing

The chemical composition of ground and polished fused silica glass surfaces plays a decisive role in different applications of optics. In particular, a high level of carbon impurities is often undesirable for further processing and especially for gluing or cementing where adhesion failure may be attributed to carbonic surface-adherent contaminants. In this study, the surface carbon content at different stages of classical optics manufacturing was thus investigated. Two different standard processes—grinding and lapping with two final polishing processes using both polyurethane and pitch pads—were considered. After each process step, the chemical composition and roughness of the surface were analysed using X-ray photoelectron spectroscopy and atomic force microscopy. An obvious correlation between surface roughness and effective surface area, respectively, and the proportion of carbon contamination was observed. The lowest carbon contamination was found in case of lapped and pitch polished surfaces.