International Rubber Science Hall of Fame Inductee

2008 ◽  
Vol 81 (2) ◽  
pp. 1-6
Author(s):  
Geoff Holden

Abstract Citation* - American scientist, chemist. Dr. Ralph Milkovich was a pioneer in anionic polymerization and heterophase polymer science. He demonstrated the concept of living anionic polymerization. He prepared the first poly(styrene-block-isoprene-block-styrene) thermoplastic elastomer, exhibiting the properties of a vulcanized rubber but processible as a thermoplastic. He also prepared a new class of polymeric materials, macromonomers, useful for the syntheses of well-defined, comb-type graft copolymers.

1991 ◽  
Vol 64 (3) ◽  
pp. 450-468 ◽  
Author(s):  
Roderic P. Quirk ◽  
Jungahn Kim

Abstract A variety of living polymerization systems are now available for the controlled synthesis of block copolymers. Although living anionic polymerization remains as the method of choice for the most precise structural control, living polymerizations proceeding via other mechanistic types provide extremely useful extensions of this methodology to a wider variety of monomers.


Polymer ◽  
1998 ◽  
Vol 39 (25) ◽  
pp. 6605-6610 ◽  
Author(s):  
A.C.M Rizmi ◽  
E Khosravi ◽  
W.J Feast ◽  
M.A Mohsin ◽  
A.F Johnson

2021 ◽  
Vol 54 (3) ◽  
pp. 1489-1498
Author(s):  
Raita Goseki ◽  
Taro Koizumi ◽  
Reina Kurakake ◽  
Satoshi Uchida ◽  
Takashi Ishizone

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