Recent Progress in the Application of Ionic Liquids in Electrochemical Oxidation and Reduction

2019 ◽  
Vol 41 (2) ◽  
pp. 264-264
Author(s):  
Nan Yao and Yu Lin Hu Nan Yao and Yu Lin Hu

Electrochemical oxidation and reduction, with clean power, are key to energy conversion and storage. For example, electrochemical oxidation is a determining step for fuel cells, combination of electrochemical oxidation and reduction can form a metal-air battery. Electrochemical oxidation and reduction make significant contributions to prepare valuable chemicals directly and improve yield efficiency and reduce the three wastes, which have become one of the green methodologies. Ionic liquids have attracted increasing attentions in the area of electrochemistry due to their significant properties including good chemical and thermal stability, wide liquid temperature range, considerable ionic conductivity, nonflammability, broad electrochemical potential window and tunable solvent properties. Up to now, abundant studies of ionic liquids have reported for their practical applications for electrochemical reactions. This review covers recent studies on the applications of ILs as green and universal replacements for the traditional reagents in electrochemical oxidation and reduction. The adaptabilities of ILs in these reactions are predicted as a solution to the problems of conventional electrochemical processes and to become a powerful method in electrochemical oxidation and reduction.

2020 ◽  
Vol 13 (5) ◽  
pp. 1408-1428 ◽  
Author(s):  
Qianqian Ji ◽  
Lei Bi ◽  
Jintao Zhang ◽  
Haijie Cao ◽  
X. S. Zhao

The oxygen reduction reaction (ORR) is one of the most important electrochemical reactions in energy conversion and storage technologies, such as fuel cells and metal–air batteries.


2017 ◽  
Vol 5 (38) ◽  
pp. 20170-20179 ◽  
Author(s):  
Bin Wang ◽  
Li Xu ◽  
Gaopeng Liu ◽  
Pengfei Zhang ◽  
Wenshuai Zhu ◽  
...  

Oxygen reduction (ORR), oxygen evolution (OER), and hydrogen evolution (HER) reactions are extremely important electrochemical reactions for electrochemical energy conversion and storage.


Nanomaterials ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 1137
Author(s):  
Tatiana Santos Andrade ◽  
Anastasios Keramidas ◽  
Panagiotis Lianos

Unmediated charging of a battery using solar radiation is a very attractive project of solar energy conversion and storage. In the present work, solar energy was converted into electricity using a photocatalytic fuel cell operating with a chalcogenide-semiconductor-sensitized nanoparticulate titania photoanode and an air-cathode functioning by oxygen reduction. This cell produced sufficient energy to directly charge a vanadium redox battery functioning with a VOSO4 electrolyte and carbon paper electrodes. The whole system is characterized by ease of construction and simplicity of conception; therefore, it satisfies conditions for practical applications.


2020 ◽  
Vol 4 (8) ◽  
pp. 4008-4017 ◽  
Author(s):  
Sourav Mallick ◽  
Arpan Samanta ◽  
C. Retna Raj

Bifunctional energy conversion and storage performance of cotton fabric derived mesoporous carbon supported MnWO4 nanorods towards asymmetric supercapacitors and Zn–air batteries is demonstrated.


2014 ◽  
Vol 64 (4) ◽  
pp. 407-423 ◽  
Author(s):  
J. Ma ◽  
L. Seidl ◽  
W. Ju ◽  
E. Mostafa ◽  
L. Asen ◽  
...  

Catalysts ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 475 ◽  
Author(s):  
Jian Zhang ◽  
Jia Wang ◽  
Zexing Wu ◽  
Shuai Wang ◽  
Yumin Wu ◽  
...  

Carbon nanomaterials are potential materials with their intrinsic structure and property in energy conversion and storage. As the electrocatalysts, graphene is more remarkable in electrochemical reactions. Additionally, heteroatoms doping with metal-free materials can obtain unique structure and demonstrate excellent electrocatalytic performance. In this work, we proposed a facile method to prepare bifunctional electrocatalyst which was constructed by nitrogen, sulfur doped graphene (NSG), which demonstrate superior properties with high activity and excellent durability compared with Pt/C and IrO2 for oxygen reduction (OR) and oxygen evolution (OE) reactions. Accordingly, these phenomena are closely related to the synergistic effect of doping with nitrogen and sulfur by rationally regulating the polarity of carbon in graphene. The current work expands the method towards carbon materials with heteroatom dopants for commercialization in energy-related reactions.


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