scholarly journals Kinetic Study of Esterification of Acetic Acid with n-butanol and isobutanol Catalyzed by Ion Exchange Resin

Author(s):  
Amrit Pal Toor ◽  
Mamta Sharma ◽  
Ghanshyam Kumar ◽  
Ravinder Kumar Wanchoo
ACS Omega ◽  
2019 ◽  
Vol 4 (21) ◽  
pp. 19462-19468 ◽  
Author(s):  
Ying Liu ◽  
Jia Liu ◽  
Hanzhao Yan ◽  
Zheng Zhou ◽  
Aidong Zhou

2012 ◽  
Vol 8 ◽  
pp. 227-233 ◽  
Author(s):  
Nan Wang ◽  
Ronghua Wang ◽  
Xia Shi ◽  
Gang Zou

A clean process has been developed for the synthesis of 2-adamantylphenol derivatives through adamantylation of substituted phenols with adamantanols catalyzed by commercially available and recyclable ion-exchange sulfonic acid resin in acetic acid. The sole byproduct of the adamantylation reaction, namely water, could be converted into the solvent acetic acid by addition of a slight excess of acetic anhydride during the work-up procedure, making the process waste-free except for regeneration of the ion-exchange resin, and facilitating the recycling of the resin catalyst. The ion-exchange sulfonic acid resin catalyst could be readily recycled by filtration and directly reused at least ten times without a significant loss of activity. The key intermediate of adapalene, 2-(1-adamantyl)-4-bromophenol, could be produced by means of this waste-free process.


2006 ◽  
Vol 61 (2) ◽  
pp. 753-765 ◽  
Author(s):  
Sergej Blagov ◽  
Sandra Parada ◽  
Oliver Bailer ◽  
Peter Moritz ◽  
David Lam ◽  
...  

2012 ◽  
Vol 188 ◽  
pp. 98-107 ◽  
Author(s):  
Alvaro Orjuela ◽  
Abraham J. Yanez ◽  
Arati Santhanakrishnan ◽  
Carl T. Lira ◽  
Dennis J. Miller

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