Abstract
The steam reforming of biomass pyrolysis oil is a well-established means of producing the more useful bio-hydrogen. Bio-oil has a comparatively low heating value, incomplete volatility and acidity, hence upgrading to a more useful product is required. Over the years, the experimental conditions of the process have been studied extensively in the domain of catalysis and process variable optimisation. Sorption enhancement is now being applied to the system to improve the purity of the hydrogen stream. Lifecycle analyses has revealed that bio-hydrogen offers considerable reductions in energy consumption compared to fossil fuel-derived hydrogen. Also, green-house-gas savings from the process can also be as high as 54.5 %. Unfortunately, techno-economic analyses have elucidated that bio-hydrogen production is still hampered by high production costs. Research endeavours in steam reforming of biomass bio-oil is done with an eye for developing added value products that can complement, substitute (and one day replace) fossil fuels whilst ameliorating the global warming menace.
A comparative study of two various empirical methodologies for deriving kinetics of methane/steam reforming reaction