In this paper, we study the Schrödinger equation with non-central modified Killingbeck potential plus a ring-shaped-like potential problem, which is not spherically symmetric. The factorization method is used to solve the hypergeometric equation types which lead to solutions with the associate Laguerre function for the radial part and Jacobi polynomial for the polar part. We introduce the raising and lowering operators to calculate the energies eigenvalues, which show that the lack of spherical symmetry removes the degeneracy of second quantum number m which is completely expected. These obtained energies are better to explain the superposition of the energy levels of the atoms in the crystalline structure of molecules.