The influence of non-stationarity and interphase curvature on the growth dynamics of spherical crystals in a metastable liquid

This manuscript is concerned with the theory of nucleation and evolution of a polydisperse ensemble of crystals in metastable liquids during the intermediate stage of a phase transformation process. A generalized growth rate of individual crystals is obtained with allowance for the effects of their non-stationary evolution in unsteady temperature (solute concentration) field and the phase transition temperature shift appearing due to the particle curvature (the Gibbs–Thomson effect) and atomic kinetics. A complete system of balance and kinetic equations determining the transient behaviour of the metastability degree and the particle-radius distribution function is analytically solved in a parametric form. The coefficient of mutual Brownian diffusion in the Fokker–Planck equation is considered in a generalized form defined by an Einstein relation. It is shown that the effects under consideration substantially change the desupercooling/desupersaturation dynamics and the transient behaviour of the particle-size distribution function. The asymptotic state of the distribution function (its ‘tail’), which determines the relaxation dynamics of the concluding (Ostwald ripening) stage of a phase transformation process, is derived. This article is part of the theme issue ‘Transport phenomena in complex systems (part 1)’.

Removal and recovery of Pb from wastewater through a reversible phase transformation process between nano-flower-like Mg(OH)2 and soluble Mg(HCO3)2

This study investigated the effectiveness of a new technique for recovering Pb as highly pure PbCO3 nanoparticles from wastewater by using a nano-Mg(OH)2 adsorbent.