[12]aneN3-Conjugated AIEgens with Two-Photon Imaging Property for Synergistic Gene/Photodynamic Therapy in Vitro and in Vivo

Six amphiphiles (TTC-L-M-1/2/3/4/5/6), each consisting of hydrophilic macrocyclic polyamine triazole-[12]aneN3 (M) and hydrophobic photosensitizer tetraphenylethenethiophene modified cyanoacrylate (TTC) moiety linked with alkyl chains (L), have been designed and synthesized for...

Macrocyclic polyamine [12]aneN3 modified triphenylamine-pyrazine derivatives as efficient non-viral gene vectors with AIE and two-photon imaging properties

[12]aneN3 modified triphenylamine-pyrazines as non-viral gene vectors with AIE and two-photon imaging properties.

Group 2 metal (Mg, Ca, Sr) silylamides supported by a cyclen-derived macrocyclic polyamine

[M{N(SiMe3)2}2] and [M{N(SiHMe2)2}2] (M = Mg, Ca, Sr) reacted with the macrocyclic NNNN-type polyamine (Me3TACD)H (LH) to give different types of products, especially with the β-SiH function, exhibiting the individuality of these alkaline earths within the identical ligand sets.

Unexpected alkane elimination from cationic group 13 dialkyls in a reaction with a macrocyclic polyamine

A macrocyclic polyamine 1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane, (Me3TACD)H formed thermally stable adducts with MR3 (M = Al, In) but released RH from reactions with [MR2]+.

Zinc hydridotriphenylborates supported by a neutral macrocyclic polyamine

A neutral macrocyclic polyamine 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane (Me4TACD) stabilizes cationic zinc hydridotriphenylborates that react with CO2(1 atm) under insertion into the B–H bonds.