Via vapor-phase chromatography 2-tiophentiol and the mixtures of individual xanthogenates, which are the stock of additive synthesis have been analyzed. Isomeric composition of high boiling aromatic hydrocarbons has been separated through vapor-phase chromatography. n,nꞌ-dyetoxiazoxybenzol and dygeptylphenyl ethers of phenyldicarbon acids, which are applied to the glass capillary columns have been used as a liquid stationary phase. The water vapor of moving carrier was used instead of the gas-carrier of nitrogen, which allowed to reduce the durability of the analysis and to improve the seperation efficiency. The main parameters of vapor-phase chromatography have been studied during the stock analysis as well. The retention time, the height of theoretic trays and rates of assimetry of analyzed compounds have been calculated.