outer coordination sphere
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scholarly journals Outer-Coordination Sphere in Multi-H+/Multi-e– Molecular Electrocatalysis

iScience ◽  
2021 ◽  
pp. 103628
Author(s):  
Soumalya Sinha ◽  
Caroline K. Williams ◽  
Jianbing "Jimmy" Jiang
Keyword(s):  
Coordination Sphere ◽  
Outer Coordination Sphere

scholarly journals Enhanced Hydrogenation of Carbon Dioxide to Methanol by a Ruthenium Complex with a Charged Outer-Coordination Sphere

ACS Catalysis ◽  
2020 ◽  
Vol 10 (13) ◽  
pp. 7419-7423
Author(s):  
Jeremy D. Erickson ◽  
Andrew Z. Preston ◽  
John C. Linehan ◽  
Eric S. Wiedner
Keyword(s):  
Carbon Dioxide ◽  
Coordination Sphere ◽  
Ruthenium Complex ◽  
Outer Coordination Sphere ◽  
Hydrogenation Of Carbon Dioxide

scholarly journals A Positive Charge in the Outer Coordination Sphere of an Artificial Enzyme Increases CO2 Hydrogenation

2020 ◽  
Vol 39 (9) ◽  
pp. 1532-1544 ◽  
Author(s):  
Joseph A. Laureanti ◽  
Bojana Ginovska ◽  
Garry W. Buchko ◽  
Gregory K. Schenter ◽  
Margaret Hebert ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Positive Charge ◽  
Co2 Hydrogenation ◽  
Artificial Enzyme ◽  
Outer Coordination Sphere

Phenol Reduces Nitrite to NO at Copper(II): Role of a Proton-Responsive Outer Coordination Sphere in Phenol Oxidation

2020 ◽  
Vol 142 (4) ◽  
pp. 1726-1730 ◽  
Author(s):  
Aditesh Mondal ◽  
Kiran P. Reddy ◽  
Jeffery A. Bertke ◽  
Subrata Kundu
Keyword(s):  
Coordination Sphere ◽  
Phenol Oxidation ◽  
Outer Coordination Sphere

scholarly journals Enhancing catalytic alkane hydroxylation by tuning the outer coordination sphere in a heme-containing metal–organic framework

2020 ◽  
Vol 11 (21) ◽  
pp. 5447-5452 ◽  
Author(s):  
David Z. Zee ◽  
T. David Harris
Keyword(s):  
Coordination Sphere ◽  
Metal Organic Framework ◽  
Alkane Hydroxylation ◽  
Metal Organic ◽  
Outer Coordination Sphere ◽  
Organic Framework

Removing labile protons via acetylation of the structural nodes in a metal–organic framework enhances catalysis at the heme linkers.

Outer Coordination Sphere Proton Relay Base and Proximity Effects on Hydrogen Oxidation with Iron Electrocatalysts

2019 ◽  
Vol 38 (6) ◽  
pp. 1391-1396 ◽  
Author(s):  
Neeraj Kumar ◽  
Jonathan M. Darmon ◽  
Charles J. Weiss ◽  
Monte L. Helm ◽  
Simone Raugei ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Hydrogen Oxidation ◽  
Proximity Effects ◽  
Proton Relay ◽  
Outer Coordination Sphere

Chicken fat for catalysis: a scaffold is as important for molecular complexes for energy transformations as it is for enzymes in catalytic function

2019 ◽  
Vol 3 (12) ◽  
pp. 3260-3278 ◽  
Author(s):  
Joseph A. Laureanti ◽  
Molly O'Hagan ◽  
Wendy J. Shaw
Keyword(s):  
Coordination Sphere ◽  
Molecular Complexes ◽  
Catalytic Performance ◽  
Chicken Fat ◽  
Catalytic Function ◽  
Outer Coordination Sphere

The outer coordination sphere, sometimes called chicken fat, is essential to achieving the best catalytic performance for energy transductions.

scholarly journals Evaluating the impacts of amino acids in the second and outer coordination spheres of Rh-bis(diphosphine) complexes for CO2 hydrogenation

2019 ◽  
Vol 215 ◽  
pp. 123-140 ◽  
Author(s):  
Aaron P. Walsh ◽  
Joseph A. Laureanti ◽  
Sriram Katipamula ◽  
Geoffrey M. Chambers ◽  
Nilusha Priyadarshani ◽  
...  
Keyword(s):  
Amino Acids ◽  
Coordination Sphere ◽  
Co2 Hydrogenation ◽  
Biologically Inspired ◽  
Hydrogenation Catalysts ◽  
Coordination Spheres ◽  
Outer Coordination Sphere

The influence of a biologically inspired second and outer coordination sphere on Rh-bis(diphosphine) CO2 hydrogenation catalysts was explored.

Macromolecular Engineering of the Outer Coordination Sphere of [2Fe-2S] Metallopolymers to Enhance Catalytic Activity for H2 Production

2018 ◽  
Vol 7 (11) ◽  
pp. 1383-1387 ◽  
Author(s):  
William P. Brezinski ◽  
Metin Karayilan ◽  
Kayla E. Clary ◽  
Keelee C. McCleary-Petersen ◽  
Liye Fu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Coordination Sphere ◽  
H2 Production ◽  
Outer Coordination Sphere
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