AbstractAccelerating loss of glacial mass caused by rising global temperatures has significant implications. The global cycle of the greenhouse gas CO2 is also associated with mineral weathering and glaciation. In glaciated areas, most estimates of atmospheric CO2 consumption are confined to chemical ionic mass balance or analog modeling methods. We applied the gradient method to the surface of Koxkar glacier, western Tien Shan, China, for a 5 month period during 2012. The overall net glacier-system CO2 exchange (NGE) rate was measured as -0.05 and -0.07mmol m–2 s–1 for regions of exposed ice and supraglacial moraine, respectively. This suggests that atmospheric CO2 drawdown may occur during ice melting because of consumption of H+ by CO2 hydrolysis that occurs in solutions. Using the degree-day model to calculate glacier ablation in bare-ice regions and considering characteristics of the NGE rate in the supraglacial debris region with the support of GIS, the daily NGE rate was estimated to be -1.23 ± 0.17μmmol m–2 d–1 between Julian days 125 and 268 of 2012. These findings present a new approach for modeling the dynamics of glacial CO2 sinks undergoing melting, and develop an understanding of the mechanism of atmospheric CO2 exchange.