Graptolite turnover and δ13Corg excursion in the upper Wenlock shales (Silurian) of the Holy Cross Mountains (Poland)

The mid–late Homerian Age of the Silurian Period was a time of intense changes in biota, oceanic chemistry, and sea level and is known as the lundgreni extinction (for the graptolite extinctions), the Mulde bioevent (for the conodont turnover event) or the Homerian carbon isotope excursion (CIE) probably related to glacially influenced climate perturbation. New information on this interval from the deep water sedimentary and graptolite succession of the Kielce Region (Holy Cross Mountains, Poland) of the northern margin of the Małopolska Block is presented here based on analysis of the Prągowiec Ravine section. The lundgreni–nilssoni graptolite biozones interval have been recognized there. This interval is composed by dark shales with very rare benthic fauna, which indicate the deep open-marine (pelagic) paleoenvironment. Ten samples were taken for the δ13Corg analysis from the lundgreni (2 samples), parvus (2 samples), praedeubeli (2 samples), praedeubeli–deubeli (1 sample), ludensis (2 samples) and nilssoni (1 sample) biozones. According to the δ13Corg results, the first positive δ13Corg excursion of the Mulde Bioevent is well recognized. The δ13Corg values rise from −30.7 – −30.1 ‰ in the lundgreni Biozone to −29.3 – −28.7 ‰ in the parvus Biozone and fall below −30 ‰ in the praedeubeli–deubeli interval. The second positive δ13Corg peak of the Mulde Event was not recognized in the Prągowiec Ravine. Based on the numerical comparisons using Raup-Crick metric of co-occurrences of graptolite species, the upper Homerian was characterized by significant between-biozone turnover of these taxa at the given locality.

The first occurrence of the earliest species of Acadoparadoxides outside West Gondwana (Cambrian; Holy Cross Mountains, Poland)

Two hundred and eighty specimens of paradoxidids from two localities in the Holy Cross Mountains (Poland) have been reanalysed using morphometric techniques. Revision of the dataset provided evidence for the presence of two endemic taxa: Acadoparadoxides kozlowskii (Orłowski, 1959) and Acadoparadoxides samsonowiczi (Orłowski, 1959), both belonging to the earliest group of Acadoparadoxides, initially considered to be present only in Gondwanan successions. Thus, this is the first description of the members of this group outside West Gondwana. The taxonomic revision, and the presence of representatives of the earliest acadoparadoxidines coupled with the absence of taxa typical of Scandinavia that were previously described from this locality have resulted in the modification of the biostratigraphic scheme hitherto used in the Holy Cross Mountains. The newly established A. samsonowiczi – A. kozlowskii Assemblage Zone is correlated with the Morocconus notabilis Zone of Morocco, and thus represents the Cambrian Series 2 and 3 boundary interval. Links with West Gondwana challenge the existing palaeogeographic interpretations for the southern part of the Holy Cross Mountains and point to an urgent need to revise the position of the Małopolska Block during the middle Cambrian.

EXPERIMENTAL TESTS OF H2S INTERACTIONS WITH AQUIFER ROCK

The experimental research in brine–rock–gas was performed in order to investigate the interactions of hydrogen sulphide with selected aquifer rocks from the Małopolska Block (Poland). Scanning microscopic analysis of reacted samples confirmed intense dissolution of the cement components (mainly hematite and carbonates). It was also found that the main process leading to hydrogen sulphide mineral trapping is its reaction with hematite, leading to the formation of iron (III) sulphide. Based on modeling of kinetic reactions we also assessed the amounts of sulphur blocked in the mineral form and in solution. On this basis, it was hypothesized that the analyzed rocks have significant potential for geological sequestration of H2S in the long term.

Petrology and geochemistry of granitoids and their mafic micogranular enclaves (MME) in marginal part of the Małopolska Block (S Poland)

Granitic plutons (the Dolina Będkowska valley and Pilica area) were found in a few boreholes in the Małopolska Block (MB). These granitic rocks may represent apical parts (apophyses) of a great magmatic bodies (batholiths) located in deeper level of the Ediacaran/Paleozoic basement. They are described as ‘stitching intrusions’, generated during/after collision in Carboniferous/Permian period (~300 Ma) between the Upper Silesian Block (USB) and the Małopolska Block (MB).These rocks are fresh, unaltered granodiorites that are pale grey in colour. They have holocrystalline, medium- to coarse-grained structure and massive texture. For the first time, several mafic microgranular enclaves (MME), varying in size and colour, were found in the granodioritic host (HG). The occurrence of MME in the host granodioritic rocks is evidence of a mingling process between mafic and felsic magmas.The MME are pale/dark grey in colour, fine-grained rocks with ‘porphyritic’ textures. They consist of large megacrysts/xenocrysts of plagioclase, quartz, alkali feldspars and the fine-grained groundmass of pseudo-doleritic textures (lath-shaped plagioclases, blade-shaped amphiboles/biotites). According to their modal/mineral composition, they represent Q-diorites and tonalites.The MME, similar to the host granodiorites (HG), are I-type rocks, exhibit high Na2O content >3.2 wt%; normative diopside or normative corundum occurs (mainly <1%). They are metaluminous to slightly peraluminous (ASI <1.1) and have calc-alkaline, medium-K to high-K character. They generally belong to magnesian series (#Mg=0.20-0.40) and have low agpaitic index (<0.87). They are low evolved magmatic rocks. The rocks studied are enriched in LREEs (La, Ce, Sm) compared to HREEs. The Eu* negative anomaly and high Sr contents point to varying degrees of plagioclase fractionation connected to the mixing process rather than simple fractional crystallization. Both rocks studied (HG and MME) are characterized by a high content of LILEs (K, Ba, Rb) in normalized patterns and a low HFS/LIL elements ratio (Ta, Nb)/(K, Rb, La). The projection points of the rocks studied plot in different fields of various petrochemical diagrams: mainly in the arc granites that are rare in the pre-collisional granites as well as the syn-subductional to post-collisional granites fields.For the first time, inner textures in rock-forming minerals related to mixing processes are described both in the granodioritic host (HG) and in the MME. Mantled boxy cellular plagioclase megacrysts with ‘old cores’ of labradorite composition, and amphibole aggregates with titanite and opaque minerals, represent peritectic rather than primary residual minerals. The plagioclase, quartz and alkali feldspar megacrysts/xenocrysts were mechanically transferred from the granodioritic host (HG) to MME. The presence of lath-shaped plagioclases, blade-shaped amphiboles/biotites and acicular-shaped apatites in the groundmass of the MME is evidence of undercooling of hot mafic blobs in a relatively cold granodioritic magma chamber. The MME were hybridized by leucocratic melt squeezed from the granodioritic magma in a later stage of the mixing process (quartz and alkali crystals in the interstices in the MME groundmass). In the granodiorites (HG), the spike and spongy cellular zones as well as biotite/amphibole zones in plagioclase megacrysts are connected to the mixing process.Both of the rocks studied are characterized by different amounts of major elements (SiO2, Na2O and K2O), trace elements (Ni, Cr, V, Ti and P), #Mg and modified alkali-lime index (MALI) that is related to their origins from different sources. On the other hand, they have similar chondrite-normalized patterns (for trace elements and REE), LILEs contents (Sr, Ba, Rb), aluminum saturation index (ASI) and isotopic signatures (high 86Sr/87Sr (0.079-0.713) and low 143Nd/144Nd (0.512) values but lower than in continental crust), which are evidence of the strong hybridisation of mafic enclaves by the granodioritic host magma. The parental rocks of both rocks studied have a similar mafic signature but were generated in different sources: the host granodiorites (HG) magma in lower continental crust rocks, and the MME magma in enriched upper mantle. The MME crystallized from strongly hybridized magma of intermediate compositions (Q-diorite, tonalite) rather than from primary mafic magma. The host granodiorites (HG) originated from completely homogenized crustal granodioritic magma which inherited its geochemical signature from ancient arc-rocks in a subduction-related setting

Xenotime-(Y) veins in a Neoproterozoic metamudstone (Małopolska Block, S Poland)

Xenotime-(Y) veins in a Neoproterozoic metamudstone (Małopolska Block, S Poland)First occurrence of xenotime-(Y) veins in the Neoproterozoic metamudstone, NW margin of the Małopolska Block, is reported here. The veins are <5 μm thick, inhomogeneous and of varied morphology. Their textural characteristics, exhibiting very low U and Th contents (<1 wt%) and relatively high heavy rare earth elements (REE) contents (12-24 REE2O3 wt%), suggest hydrothermal genesis, though diagenetic precursors of the veins are not excluded. The veins provide good evidence of the mobility of Y, REE, U and Th in low-temperature conditions (anchimetamorphic to greenschist facies). The observed differences in the chemical composition of the veins may indicate multiple stages of formation, possibly during several hydrothermal events that affected the area.

Principal characteristics of the Upper Silesian Block and Małopolska Block border zone (southern Poland)

The Upper Silesian and Małopolska blocks are situated near the southwestern boundary of the East European Platform within the Trans-European Suture Zone. The Lower Palaeozoic lithologies of the blocks reveal different stratigraphic and diastrophic development. In the Upper Silesian Block, unmetamorphosed and gently folded Lower Cambrian to Ordovician sedimentary rocks rest on a Cadomian basement. The Lower Cambrian is represented by an older (sub-Holmia) Borzęta Formation and a younger (Holmia) Goczałkowice Formation. The thickness of the Cambrian lithologies increases from the southwest towards the lateral part of the block. In the Małopolska Block Palaeozoic and Precambrian lithologies are represented by regionally metamorphosed and intensely folded Lower Cambrian–Vendian clastic rocks which are unconformably overlain by Ordovician–Lower Silurian carbonates and Upper Silurian clastic rocks. The crystalline basement of the Małopolska Block has yet to be recognized. The Lower Palaeozoic sediments of both blocks are overlain by Devonian and Carboniferous rocks. The blocks are in direct contact along a narrow tectonic zone, a part of the largely concealed Hamburg–Kraków fault zone, in which tectonic evolution has taken place spasmodically with strike-slip movements predominating.