scholarly journals Petrology and geochemistry of granitoids and their mafic micogranular enclaves (MME) in marginal part of the Małopolska Block (S Poland)

Mineralogia ◽  
2012 ◽  
Vol 43 (1-2) ◽  
pp. 3-127 ◽  
Author(s):  
Anna Wolska

AbstractGranitic plutons (the Dolina Będkowska valley and Pilica area) were found in a few boreholes in the Małopolska Block (MB). These granitic rocks may represent apical parts (apophyses) of a great magmatic bodies (batholiths) located in deeper level of the Ediacaran/Paleozoic basement. They are described as ‘stitching intrusions’, generated during/after collision in Carboniferous/Permian period (~300 Ma) between the Upper Silesian Block (USB) and the Małopolska Block (MB).These rocks are fresh, unaltered granodiorites that are pale grey in colour. They have holocrystalline, medium- to coarse-grained structure and massive texture. For the first time, several mafic microgranular enclaves (MME), varying in size and colour, were found in the granodioritic host (HG). The occurrence of MME in the host granodioritic rocks is evidence of a mingling process between mafic and felsic magmas.The MME are pale/dark grey in colour, fine-grained rocks with ‘porphyritic’ textures. They consist of large megacrysts/xenocrysts of plagioclase, quartz, alkali feldspars and the fine-grained groundmass of pseudo-doleritic textures (lath-shaped plagioclases, blade-shaped amphiboles/biotites). According to their modal/mineral composition, they represent Q-diorites and tonalites.The MME, similar to the host granodiorites (HG), are I-type rocks, exhibit high Na2O content >3.2 wt%; normative diopside or normative corundum occurs (mainly <1%). They are metaluminous to slightly peraluminous (ASI <1.1) and have calc-alkaline, medium-K to high-K character. They generally belong to magnesian series (#Mg=0.20-0.40) and have low agpaitic index (<0.87). They are low evolved magmatic rocks. The rocks studied are enriched in LREEs (La, Ce, Sm) compared to HREEs. The Eu* negative anomaly and high Sr contents point to varying degrees of plagioclase fractionation connected to the mixing process rather than simple fractional crystallization. Both rocks studied (HG and MME) are characterized by a high content of LILEs (K, Ba, Rb) in normalized patterns and a low HFS/LIL elements ratio (Ta, Nb)/(K, Rb, La). The projection points of the rocks studied plot in different fields of various petrochemical diagrams: mainly in the arc granites that are rare in the pre-collisional granites as well as the syn-subductional to post-collisional granites fields.For the first time, inner textures in rock-forming minerals related to mixing processes are described both in the granodioritic host (HG) and in the MME. Mantled boxy cellular plagioclase megacrysts with ‘old cores’ of labradorite composition, and amphibole aggregates with titanite and opaque minerals, represent peritectic rather than primary residual minerals. The plagioclase, quartz and alkali feldspar megacrysts/xenocrysts were mechanically transferred from the granodioritic host (HG) to MME. The presence of lath-shaped plagioclases, blade-shaped amphiboles/biotites and acicular-shaped apatites in the groundmass of the MME is evidence of undercooling of hot mafic blobs in a relatively cold granodioritic magma chamber. The MME were hybridized by leucocratic melt squeezed from the granodioritic magma in a later stage of the mixing process (quartz and alkali crystals in the interstices in the MME groundmass). In the granodiorites (HG), the spike and spongy cellular zones as well as biotite/amphibole zones in plagioclase megacrysts are connected to the mixing process.Both of the rocks studied are characterized by different amounts of major elements (SiO2, Na2O and K2O), trace elements (Ni, Cr, V, Ti and P), #Mg and modified alkali-lime index (MALI) that is related to their origins from different sources. On the other hand, they have similar chondrite-normalized patterns (for trace elements and REE), LILEs contents (Sr, Ba, Rb), aluminum saturation index (ASI) and isotopic signatures (high 86Sr/87Sr (0.079-0.713) and low 143Nd/144Nd (0.512) values but lower than in continental crust), which are evidence of the strong hybridisation of mafic enclaves by the granodioritic host magma. The parental rocks of both rocks studied have a similar mafic signature but were generated in different sources: the host granodiorites (HG) magma in lower continental crust rocks, and the MME magma in enriched upper mantle. The MME crystallized from strongly hybridized magma of intermediate compositions (Q-diorite, tonalite) rather than from primary mafic magma. The host granodiorites (HG) originated from completely homogenized crustal granodioritic magma which inherited its geochemical signature from ancient arc-rocks in a subduction-related setting

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Sylwester Czopek ◽  
Katarzyna Trybała-Zawiślak ◽  
Joanna Trąbska ◽  
Barbara Trybalska ◽  
Joanna Adamik-Proksa ◽  
...  

Abstract In 2017, an expedition of the Institute of Archeology of the University of Rzeszów (Poland) carried out excavations on a hillfort belonging to the Scythian cultural circle (its forest-steppe variant) in Chotyniec, in south-eastern Poland. The hillfort is the central and most important point of a large settlement cluster, which is the furthest north-western enclave of this cultural circle. In an excavated cult object – the so-called ‘zolnik’ – we made an interesting discovery. Here we show this unique finding for the first time: a Greek wine amphora, from the beginning of the sixth century BC. We were able to explore and reconstruct it almost entirely. Amphora is the only artefact of this type found in the present Polish borders. The amphora was subjected to archaeometric research with the use of PLM, SEM/EDS, TXRF and ToF SIMS. The massive fabric was made of high calcium clay enriched in quartz and volcanic lithoclasts. The lack of chromium and nickel among trace elements makes the vessel different from the amphoras from the Eastern Meditteranean analysed so far, suggesting a specific workshop. Red painting was executed with very fine grained iron compounds predominantly based on aluminosilicates, enriched in phosphorus. Obviously, since it is associated with the presence of Scythians in Eastern Europe, it simultaneously delimits (geography-wise) the borders of Greek influence.


2021 ◽  
Author(s):  
Abimbola Chris Ogunyele ◽  
Tommaso Giovanardi ◽  
Mattia Bonazzi ◽  
Maurizio Mazzucchelli ◽  
Alberto Zanetti

&lt;p&gt;The Ivrea-Verbano Zone (IVZ, westernmost sector of the Southern Alps) represents a unique opportunity to investigate the Paleozoic to Mesozoic geodynamic evolution of the Gondwana and Laurasia boundary from the perspective of the lower continental crust. Only recently, the petrochemical record of Triassic-Jurassic magmatism has been recognized. It mainly affected the northernmost tip, the Finero Complex, where the continental crust was tectonically thinned before opening of Alpine Tethys. However, the Mesozoic magmatism in the Finero Complex is still poorly-constrained. Firstly, its extent is largely unknown, because the mantle and crustal intrusives were already enriched by Paleozoic processes. Secondly, Mesozoic melts migration started when the Finero Complex was still placed at P-T conditions typical of a continental crust-mantle transition (1 GPa): this has promoted the reopening of the geochronological clocks in both Paleozoic and Mesozoic rocks, which usually provides wide time intervals. Lastly, the finding of Mesozoic magmatism as composite veins/pods and metasomatised layers has not allowed an exhaustive reconstruction of the primitive melts geochemistry. To place further constraints on such issue, a new dyke swarm cropping out in the Finero Phlogopite Peridotite mantle unit has been investigated. Dykes usually cut at high angle the mantle foliation and are up to 60 cm thick. They are composed by coarse-grained hornblendite to anorthosite, both phlogopite/biotite-bearing. Many dykes are composite, showing variable proportions of hornblendite and anorthosite. In places, the dyke swam was affected by volatiles overpressure as late magmatic stage, which produced plastic flow and development of a porphyroclastic structure by deformation of the early cumulates, with widespread segregation of a fine-grained mica matrix.&lt;/p&gt;&lt;p&gt;Dykes mainly consist of pargasite, phlogopite/biotite, albite (An 8-10), in association with apatite, monazite, ilmenite, zircon, Nb-rich oxides, carbonates. Enrichments in Fe (amphibole and biotite) and Na (plagioclase) suggest segregation from evolved melts, strongly enriched in H&lt;sub&gt;2&lt;/sub&gt;O, P, C. The large LILE and LREE contents in amphiboles, sometimes associated to high Nb, Ta, Zr and Hf concentrations, as well as the mineral assemblage, support an alkaline affinity of the melts. The strongly positive &amp;#949;Hf&lt;sub&gt;t &lt;/sub&gt;(+10) of zircons and the isotopic Sr composition of amphiboles (0.7042) point to a derivation of the melts from mildly enriched sources, possibly located at the crust-mantle interface.&lt;/p&gt;&lt;p&gt;Zircons from anorthosite layers are mostly anhedral fragments. They show homogenous internal structure or sector zoning. Concordant &lt;sup&gt;206&lt;/sup&gt;Pb/&lt;sup&gt;238&lt;/sup&gt;U zircon ages vary from 221 &amp;#177; 9 Ma to 192 &amp;#177; 8 Ma. The results of this study confirm that mantle input to the Southern Alps magmatism was of alkaline affinity from Norian to Sinemurian. A widespread fluids circulation induced by such magmatism at high P-T conditions was likely the main cause of the diffuse geochronological reset towards Mesozoic ages of the northern IVZ.&lt;/p&gt;


1995 ◽  
Vol 46 (1) ◽  
pp. 101 ◽  
Author(s):  
U Kern ◽  
B Westrich

For a lock-regulated reach of the River Neckar at Lauffen, Germany, results from sediment core analysis are presented. It is observed that sediment layers with a high concentration of heavy metals, especially cadmium, are covered by younger, less polluted sediment layers. A principal component analysis separated the parameters measured into three groups: heavy metals from human activities (Cd, Cr, Ni, Pb, Zn), metals from natural sources (Co, Fe, Mn), and inorganic carbon. Within the fine-grained sediment fraction containing particles smaller than 20 μm, a higher concentration of anthropogenic trace metals was found in fine-grained samples than in coarse-grained samples, whereas Co, Fe and Mn showed the opposite tendency. Obviously, this is due to two different sources of fine-grained material: sewage flocs and natural erosion particles. Acid-producing capacity (APC) and acid-neutralizing capacity (ANC) are calculated for both pore water and particulate matter of the sediment. At a depth of 20 cm, APC and ANC are controlled by the sediment matrix. ANC, which is due to calcium carbonate, is 20 times higher than APC, which is predominantly due to reduced sulfur components. Therefore, oxidation of sediment of the River Neckar does not lead to acidification.


2019 ◽  
Author(s):  
Aedan Y. Li ◽  
Keisuke Fukuda ◽  
Andy C. H. Lee ◽  
Morgan D. Barense

AbstractAlthough we can all agree that interference induces forgetting, there is surprisingly little consensus regarding what type of interference most likely disrupts memory. We previously proposed that the similarity of interference differentially impacts the representational detail of color memory. Here, we extend this work by applying the Validated Circular Shape Space (Li et al., 2020) for the first time to a continuous retrieval task, in which we quantified both the visual similarity of distracting information as well as the representational detail of shape memory. We found that the representational detail of memory was systematically and differentially altered by the similarity of distracting information. Dissimilar distractors disrupted both fine- and coarse-grained information about the target, akin to memory erasure. In contrast, similar distractors disrupted fine-grained target information but increased reliance on coarse-grained information about the target, akin to memory blurring. Notably, these effects were consistent across two mixture models that each implemented a different scaling metric (either angular distance or perceived target similarity), as well as a parameter-free analysis that did not fit the mixture model. These findings suggest that similar distractors will help memory in cases where coarse-grained information is sufficient to identify the target. In other cases where precise fine-grained information is needed to identify the target, similar distractors will impair memory. As these effects have now been observed across both stimulus domains of shape and color, and were robust across multiple scaling metrics and methods of analyses, we suggest that these results provide a general set of principles governing how the nature of interference impacts forgetting.


2015 ◽  
Vol 87 (4) ◽  
pp. 1959-1979 ◽  
Author(s):  
AKIHISA MOTOKI ◽  
SUSANNA E. SICHEL ◽  
THAIS VARGAS ◽  
DEAN P. MELO ◽  
KENJI F. MOTOKI

ABSTRACT This paper presents geochemical behaviour of trace elements of the felsic alkaline rocks of the state of Rio de Janeiro, Brazil, with special attention of fractional crystallization and continental crust assimilation. Fractionation of leucite and K-feldspar increases Rb/K and decreases K2O/(K2O+Na2O). Primitive nepheline syenite magmas have low Zr/TiO2, Sr, and Ba. On the Nb/Y vs. Zr/TiO2 diagram, these rocks are projected on the field of alkaline basalt, basanite, and nephelinite, instead of phonolite. Well-fractionated peralkaline nepheline syenite has high Zr/TiO2 but there are no zircon. The diagrams of silica saturation index (SSI) distinguish the trends originated form fractional crystallization and crustal assimilation. In the field of SSI<-200, Zr/TiO2 and Ba/Sr have negative correlations to SSI in consequence of fractional crystallization. In the field of SSI>-200, they show positive correlations due to continental crust assimilation. Total REEs (Rare Earth Elements) is nearly 10 times that of granitic rocks, but LaN/SmN and LaN/YbN are similar. REE trend is linear and Eu anomaly is irrelevant. The pegmatitic liquid generated by country rock partial melting is SiO2-oversaturated and peraluminous with high Ba, Sr, Ba/Sr, Zr/TiO2, and SSI, with high content of fluids. This model justifies the peraluminous and SiO2-oversaturated composition of the rocks with relevant effects of continental crust assimilation.


1988 ◽  
Vol 25 (11) ◽  
pp. 1777-1790 ◽  
Author(s):  
K. Schrijver ◽  
E. Marcoux ◽  
G. Beaudoin ◽  
J. Y. Calvez

Galena Pb-isotope ratios of epithermal vein and disseminated sulfide occurrences in the Taconian Orogen and Siluro-Devonian basin cluster around 17.90–18.05 for 206Pb/204Pb and 37.70–38.00 for 208Pb/204Pb. The major source of Pb in most, if not all, occurrences is a fairly common continental crust, a characteristic found in published analyses of Grenville feldspar Pb. A southwest to northeast increase in galena 206Pb/204Pb ratios is ascribed to the supply of several types of detritus from Grenville basement during the Cambro-Ordovician: coarse-grained, K-feldspar-bearing in the southwest, grading into fine-grained phyllitic, and relatively more highly radiogenic in the northeast.Emplacement (i) of Pb–Zn–barite veins and disseminations, commonly of homogeneous crustal Pb-isotopic signature, was late Taconian; (ii) of Pb–Zn–quartz veins, of less homogeneous signature, was post-Taconian; and (iii) of Pb–Zn–carbonate veins, relatively highly radiogenic and commonly homogeneous, was late or post-Acadian. Signatures of the first-mentioned group seem to be most useful in exploration.


2021 ◽  
pp. 1-18
Author(s):  
Jean-David Moreau ◽  
Jacques Sciau ◽  
Georges Gand ◽  
Emmanuel Fara

Abstract A recent excavation yielded 118 large tridactyl footprints in the Lower Jurassic Dolomitic Formation of the Causses Basin, at Mongisty in southern France. Most of the tracks are ascribed to Eubrontes giganteus Hitchcock, 1845. They are preserved on a surface of 53 m2 and form parallel rows with a preferential orientation towards the north. Such an abundance and density of E. giganteus is observed for the first time in the Early Jurassic from the Causses Basin. Sedimentological and ichnotaphonomical analyses show that the footprints were made at different time intervals, thus excluding the passage of a large group. In contrast to all other tracksites from the Dolomitic Formation, where tracks are preserved in fine-grained sediments corresponding to low-energy depositional palaeoenvironments, the tracks from Mongisty are preserved in coarse-grained sediment which is a matrix- to clast-supported breccia. Clasts consist of angular to sub-rounded, millimetric to centimetric-scale (up to 2 cm), poorly sorted, randomly oriented, homogeneous dolostone intraclasts floating in a dolomudstone matrix. Sedimentological analysis shows that the depositional environments of Mongisty varied from subtidal to intertidal/supratidal settings in a large and protected flat marsh. The lithology of the track-bearing surfaces indicates that the mudflat of the Causses Basin was sporadically affected by large mud flows that reworked and redeposited mudstone intraclasts coming from the erosion of upstream, dry and partially lithified mud beds. Throughout the world, this type of preservation of dinosaur tracks in tidal matrix- to clast-supported breccias remains rare.


Geosciences ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 196
Author(s):  
Stefania Corvò ◽  
Antonio Langone ◽  
José Alberto Padrón-Navarta ◽  
Andrea Tommasi ◽  
Alberto Zanetti

Petrographic and geochemical data for mylonites from a metric-scale shear zone in mantle peridotites from the Finero massif (Southern Alps) record large mineralogical and geochemical modifications compared to surrounding coarse-grained ultramafic rocks, which were pervasively deformed in presence of hydrous melts. The mylonites are composed by olivine and orthopyroxene and, less frequently, clinopyroxene, phlogopite, and pargasite porphyroclasts enclosed in a fine-grained matrix of phlogopite and olivine, with subordinate amounts of orthopyroxene, clinopyroxene, pargasite, and chromite. P-T estimates indicate that deformation occurred under granulite- to upper-amphibolite facies conditions. Field relationships and U-Pb dating indicate that the shear zone was active during Lower Jurassic and/or later, in an extensional setting at the western margin of the Adria plate, which led to the opening of the Alpine Tethys. The major and trace element composition of the porphyroclasts in the mylonites significantly differ from those in the hosting coarse-grained ultramafics. Porphyroclasts were chemically active during deformation acting as source (diffusion-out) or sink (diffusion-in) for some trace elements. The chemical modifications were promoted by the interaction with aqueous fluids and the composition varied from mantle- (enriched in Ni, Co, Li, Na, REE, Y, and Sr) to crustal-derived (enriched in Zn, K, Al, Ti, and Fe).


2021 ◽  
Vol 50 (11) ◽  
pp. 3205-3217
Author(s):  
Emad Ullah Khan ◽  
Abbas Ali Naseem ◽  
Maryam Saleem ◽  
Faisal Rehman ◽  
Syed Waseem Sajjad ◽  
...  

Replacement dolomite occurs in Jurassic Samanasuk Formation in Dara Adam khel area of Kohat ranges, North-Western Himalayas, Pakistan. This study, for the first time, document the process of dolomitization and evolution of strata bound dolomitic bodies. Field investigation, petrography and geochemistry helped in unraveling the formation of several dolomitic bodies. Petrographically dolomites comprises of: (1) medium grain crystalline planer subhedral dolomite (Dol-I); (2) fine grained crystalline anhedral non-planer dolomite rhombs (Dol-II); (3) medium to coarse grained crystalline subhedral-anhedral non-planer dolomite (Dol-III) and coarse to very coarse grained crystalline saddle dolomite cements (SD). The saddle dolomites (SD) postdate the replacement dolomites and precede telogenetic calcite (TC) cements. Stable O and C isotope analysis shows that these dolomites have δ18Ovpdb ranging from -4.09% to -10.4 whereas the δ13Cvpdb ranges from +0.8 to +2.51. Major and trace elements data show that Sr concentrations of 145.5 to 173 ppm; Fe contents of 2198 to 8215 ppm; and Mn contents of 93.5 to 411 ppm. Petrographically replacive dolomites, saddle dolomite, and δ18Ovpdb values depicts neomorphism of replacement dolomites that were formed earlier were exposed to late dolomitizing fluids. As a result of basin uplift during the Himalayan orogeny in Eocene time, dolomitization event was stopped through occurrence of meteoric water. The Main Boundary Thrust (MBT) and its splays were most likely essential conduits that channelized dolomitizing fluids from siliciclastic rocks that were buried deeply into the Jurassic carbonates rocks, leading to more extreme dolomitization.


2001 ◽  
Vol 34 (1) ◽  
pp. 129 ◽  
Author(s):  
Α. ΑΥΓΕΡΙΝΑΣ ◽  
Α. ΚΙΛΙΑΣ ◽  
Α. ΚΟΡΩΝΑΙΟΣ ◽  
Δ. ΜΟΥΝΤΡΑΚΗΣ ◽  
W. FRISCH ◽  
...  

The kinematic of the Cretaceous deformation and the relationship between deformation and metamorphism of the Pelagonian crystalline was studied in Voras Mt (northern Greece). The Pelagonian crystalline in this area has been subdivided into a lower, core part, consisting mainly of gneissic rocks and schists and an upper, cover part, consistine of schists and quartzites with marble intercalations. Intensely deformed granitic rocks of Upper Paleozoic age intrude the Pelagonian crystalline basement. An S j foliation is the oldest fabric recognized in the Pelagonian crystalline. Sj is mainly defined by syn-Sjgarnet(Gr1), biotite(Btj), white mica (Wnij), chloritoid, kyanite and plagioclase in the metapelitic rocks and green amphibole, epidote, plagioclase, and biotiteiBtj) in the amphibolite. Garnet grows also in some cases post-kinematically. Ilmenite and tourmaline are often found in the pelitic rocks as well. S is overprinted by an S2 foliation that developed as a crenulation cleavage. In most places, however, S2 has destroyed all earlier fabrics and a single S2 fabric is present related to, isoclinal or sheath folds intrafolial in places. S2 in the metapelitic rocks is characterized by the syn-S2 development of chlorite, white mica(Wm2) and plagioclase. In the amphibolite S2 is mainly defined by the syn-kinematic development of actinolite, plagioclase, biotite(Bt2), white mica(Wm2) and chlorite. During D2 garnet(Gr1) and biotiteiBtj) are partially replaced by chlorite, while green amphibole is replaced by actinolite and chlorite. Chloritoid remains generally stable along the S2-planes but in some places transforms to chlorite and sericite. Furthermore, D2 was locally followed by a static post-kinematic annealing indicated by polygonal quartz microfabrics with equilibrated grain boundaries and triple points. The overall orientation of S2 is dome shaped with a gentle SW-ward and NE-ward dip in the southwestern and northeastern flanks of the dome respectively. Syn-S2 minerals defined a very well exposed NW-SE trending stretching lineation. Kinematic indicators show a main top to the SE sense of movement. An S3 crenulation cleavage associated with asymmetric NW-SE trending folds is also present in most parts of the core and cover rocks, possibly, related to a constrictional type of deformation. A well developed, S4 shear band cleavage is mainly present in the upper parts of the metamorphic dome and formed under cooler conditions. S4 shear bands are associated with a NW-SE developed stretching lineation defined by elongated and dynamically recrystallized quartz grains and a preferred orientation of white mica and chlorite. Along the S4 shear bands a transformation of garnet, biotite, chloritoid and amphibole into chlorite is always observed. S4 shear bands indicate a main top to the SE sense of movement. The P-T metamorphic conditions were derived from textural equilibria and mineral assemblages, as well as from the spatial distribution of the metamorphic minerals. Syn-Dj metamorphism reached the conditions of the boundaries between greenschist and amphibolite facies. Syn-D2 retrogression took place under greenschist facie conditions. K/Ar radiometric datings on coarse-grained syn-St and younger fine-grained syn-S2 micas define an Early Cretaceous cooling age ('135Ma) for the older event and a Mid- to Late Cretaceous age ('90-80Ma) for the second event. A white mica age of ca. 65Ma correlates with S4 shear band clevage. Furthermore, the intrusion age of a granitic body into the Pelagonian crystalline is dated using the Pb/Pb single zircon evaporation method. The estimated intrusion age of 300±3Ma suggests that the Pelagonian crystalline was affected by a pre-kinematic magmatic activity relative to its Cretaceous deformation.


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