steric influence
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Biomolecular binding under confinement: statistical predictions of steric influence in the absence of long‐distance interactions

ChemPhysChem ◽  
2021 ◽  
Author(s):  
Guillaume Longatte ◽  
Fabio Lisi ◽  
Padmavathy Bakthavathsalam ◽  
Till Böcking ◽  
Katharina Gaus ◽  
...  
Keyword(s):  
Long Distance ◽  
Biomolecular Binding ◽  
Steric Influence

scholarly journals Steric Influence on Reactions of Benzyl Potassium Species with CO

2021 ◽  
Author(s):  
Tongtong Wang ◽  
Maotong Xu ◽  
Andrew Jupp ◽  
Zheng-Wang Qu ◽  
Stefan Grimme ◽  
...  
Keyword(s):  
Steric Influence

scholarly journals Iron-Catalyzed Cross-Coupling of Thioesters and Organomanganese Reagents

2021 ◽  
Author(s):  
Valentin Jacob Geiger ◽  
Ivana Fleischer
Keyword(s):  
Natural Products ◽  
Functional Groups ◽  
Cross Coupling ◽  
Pharmaceutical Compounds ◽  
Additional Step ◽  
Type Coupling ◽  
Pseudo Halides ◽  
Iron Manganese ◽  
Reaction Component ◽  
Steric Influence

We report a Fukuyama-type coupling of thioesters with aliphatic organomanganese reagents utilizing a cheap and easily available iron(III) catalyst. The reactions exhibit a wide tolerance of solvents and functional groups (e.g. ketones, esters, aryl(pseudo)halides) allowing for the conversion of thioesters derived from natural products and pharmaceutical compounds. Investigations showed a strong steric influence from each reaction component (carboxylic moiety, thiol substituent and manganese reagent), which enabled regioselective transformation of dithioesters. Tandem transformations combining the coupling with an additional step were observed. Our experiments provide insights into the potential of the employed aliphatic manganese reagents, such as the interaction between iron, manganese and oxygen, which allows for a smooth conversion.

scholarly journals Iron-Catalyzed Cross-Coupling of Thioesters and Organomanganese Reagents

2021 ◽  
Author(s):  
Valentin Jacob Geiger ◽  
Ivana Fleischer
Keyword(s):  
Natural Products ◽  
Functional Groups ◽  
Cross Coupling ◽  
Pharmaceutical Compounds ◽  
Additional Step ◽  
Type Coupling ◽  
Pseudo Halides ◽  
Iron Manganese ◽  
Reaction Component ◽  
Steric Influence

We report a Fukuyama-type coupling of thioesters with aliphatic organomanganese reagents utilizing a cheap and easily available iron(III) catalyst. The reactions exhibit a wide tolerance of solvents and functional groups (e.g. ketones, esters, aryl(pseudo)halides) allowing for the conversion of thioesters derived from natural products and pharmaceutical compounds. Investigations showed a strong steric influence from each reaction component (carboxylic moiety, thiol substituent and manganese reagent), which enabled regioselective transformation of dithioesters. Tandem transformations combining the coupling with an additional step were observed. Our experiments provide insights into the potential of the employed aliphatic manganese reagents, such as the interaction between iron, manganese and oxygen, which allows for a smooth conversion.

scholarly journals Steric influence at the 6,6’-positions in Mn-Bipy complexes and the resulting impact on electrochemical CO2 reduction

2020 ◽  
Author(s):  
Zane Thistleford ◽  
Christine Caputo ◽  
Rashi Gupta
Keyword(s):  
Co2 Reduction ◽  
Electrochemical Co2 Reduction ◽  
Steric Influence

scholarly journals Steric influence at the 6,6’-positions in Mn-Bipy complexes and the resulting impact on electrochemical CO2 reduction

2020 ◽  
Author(s):  
Zane Thistleford ◽  
Christine Caputo ◽  
Rashi Gupta
Keyword(s):  
Co2 Reduction ◽  
Electrochemical Co2 Reduction ◽  
Steric Influence

scholarly journals Steric influence at the 6,6’-positions in Mn-Bipy complexes and the resulting impact on electrochemical CO2 reduction

2020 ◽  
Author(s):  
Zane Thistleford ◽  
Christine Caputo ◽  
Rashi Gupta
Keyword(s):  
Co2 Reduction ◽  
Electrochemical Co2 Reduction ◽  
Steric Influence

scholarly journals Steric influence at the 6,6’-positions in Mn-Bipy complexes and the resulting impact on electrochemical CO2 reduction

2020 ◽  
Author(s):  
Zane Thistleford ◽  
Christine Caputo ◽  
Rashi Gupta
Keyword(s):  
Co2 Reduction ◽  
Electrochemical Co2 Reduction ◽  
Steric Influence

scholarly journals Steric influence at the 6,6’-positions in Mn-Bipy complexes and the resulting impact on electrochemical CO2 reduction

2020 ◽  
Author(s):  
Zane Thistleford ◽  
Christine Caputo ◽  
Rashi Gupta
Keyword(s):  
Co2 Reduction ◽  
Electrochemical Co2 Reduction ◽  
Steric Influence
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