A systematic study of halide-template effects in the assembly of lanthanide hydroxide cluster complexes with histidine

Controlled hydrolysis of lanthanide ions in the presence of histidine and halide templates of different sizes produced dodeca- and pentadecanuclear lanthanide hydroxide clusters.

Ce(OH)2Cl and lanthanide-substituted variants as precursors to redox-active CeO2 materials

Lanthanide hydroxide-chlorides Ce1−xLnx(OH)2Cl for Ln = La, Pr, Gd, Tb crystallise from poly(ethylene) glycol (Mn = 400) at 240 °C. Subsequent thermal decomposition yields oxides Ce1−xLnxO2−δ with redox properties suited for heterogeneous catalysis.

On the Linear Geometry of Lanthanide Hydroxide (Ln—OH, Ln=La-Lu)

Lanthanide hydroxides are key species in a variety of catalytic processes and in the preparation of corresponding oxides. This work explores the fundamental structure and bonding of the simplest lanthanide hydroxide, LnOH (Ln=La-Lu), using density functional theory calculations. Interestingly, the calculations predict that all structures of this series will be linear. Furthermore, these results indicate a valence electron configuration featuring an occupied sigma orbital and two occupied pi orbitals for all LnOH compounds, suggesting that the lanthanide-hydroxide bond is best characterized as a covalent triple bond.

On the Linear Geometry of Lanthanide Hydroxide (Ln—OH, Ln=La-Lu)

Lanthanide hydroxides are key species in a variety of catalytic processes and in the preparation of corresponding oxides. This work explores the fundamental structure and bonding of the simplest lanthanide hydroxide, LnOH (Ln=La-Lu), using density functional theory calculations. Interestingly, the calculations predict that all structures of this series will be linear. Furthermore, these results indicate a valence electron configuration featuring an occupied sigma orbital and two occupied pi orbitals for all LnOH compounds, suggesting that the lanthanide-hydroxide bond is best characterized as a covalent triple bond.

On the Linear Geometry of Lanthanide Hydroxide (Ln—OH, Ln=La-Lu)

Lanthanide hydroxides are key species in a variety of catalytic processes and in the preparation of corresponding oxides. This work explores the fundamental structure and bonding of the simplest lanthanide hydroxide, LnOH (Ln=La-Lu), using density functional theory calculations. Interestingly, the calculations predict that all structures of this series will be linear. Furthermore, these results indicate a valence electron configuration featuring an occupied sigma orbital and two occupied pi orbitals for all LnOH compounds, suggesting that the lanthanide-hydroxide bond is best characterized as a covalent triple bond.

On the Linear Geometry of Lanthanide Hydroxide (Ln—OH, Ln=La-Lu)

Lanthanide hydroxides are key species in a variety of catalytic processes and in the preparation of corresponding oxides. This work explores the fundamental structure and bonding of the simplest lanthanide hydroxide, LnOH (Ln=La-Lu), using density functional theory calculations. Interestingly, the calculations predict that all structures of this series will be linear. Furthermore, these results indicate a valence electron configuration featuring an occupied sigma orbital and two occupied pi orbitals for all LnOH compounds, suggesting that the lanthanide-hydroxide bond is best characterized as a covalent triple bond.

On the linear geometry of lanthanide hydroxide (Ln-OH, Ln = La–Lu)

Density functional theory predicts that lanthanide hydroxides are linear, with the lanthanide-hydroxide bond being characterized as a covalent triple bond.

A magnetic study of a layered lanthanide hydroxide family: Ln8(OH)20Cl4·nH2O (Ln = Tb, Ho, Er)

Experimental and semi-empirical calculations allowed the correlation of Ln electronic configurations and the diversity of different magnetic behaviors of these LLHs.