The transient pool boiling heat transfer of zircaloy and stainless steel rodlets was investigated using a quenching method. The influences of quenchant temperature, test specimen size, and material property were examined. The groove-structured surface was also prepared and tested, which could be a valuable attempt to study the effect of a machined surface structure of a vertical rodlet on the rapid cooling heat transfer performance. A test specimen with a small volume-to-heat transfer surface area and small heat capacity showed a shorter quenching time. In the low quenchant temperature condition, a stable film boiling regime was likely to be hardly observed. The grooved surface appeared to have a shorter quenching duration, which could be due to its small volume-to-area ratio. In addition, the groove-structured portion seemed to help the liquid make contact with the heated wall earlier than the plain portion. Based on this work, it was found that the quenching duration and the position of vapor film rupture can be controlled by the surface structure.