Supplemental Material: A fragile record of fleeting water on Mars

Detailed descriptions of the methods and datasets used in this study.<br>

Supplemental Material: A fragile record of fleeting water on Mars

Detailed descriptions of the methods and datasets used in this study.<br>

Water heavily fractionated as it ascends on Mars as revealed by ExoMars/NOMAD

Isotopic ratios and, in particular, the water D/H ratio are powerful tracers of the evolution and transport of water on Mars. From measurements performed with ExoMars/NOMAD, we observe marked and rapid variability of the D/H along altitude on Mars and across the whole planet. The observations (from April 2018 to April 2019) sample a broad range of events on Mars, including a global dust storm, the evolution of water released from the southern polar cap during southern summer, the equinox phases, and a short but intense regional dust storm. In three instances, we observe water at very high altitudes (>80 km), the prime region where water is photodissociated and starts its escape to space. Rayleigh distillation appears the be the driving force affecting the D/H in many cases, yet in some instances, the exchange of water reservoirs with distinctive D/H could be responsible.

Atmospheric Loss to Space and the History of Water on Mars

Mars is the nearest planet that potentially harbors life and that can be explored by humans, so its history of water is of considerable importance. Water was abundant on early Mars but disappeared as Mars became the cold, dry planet we see today. Loss of water to space played a major role in the history of this water. Variability of components of the atmosphere that can drive escape has taken place on all timescales, from interannual to the 105-, 106-, and >107-year timescales of obliquity variations to the 4 billion-year timescale of large-scale climate evolution. These variations have had a major impact on the behavior of the atmosphere, climate, and water. They also make it difficult to evaluate quantitatively where the water has gone. Despite this uncertainty, the observed enrichment in the ratio of deuterium/hydrogen requires that loss to space has been substantial. ▪ Mars is the nearest planet that potentially harbors life and that can be explored by humans, so its history of water is important. ▪ The Mars atmosphere has varied on all timescales, from year to year to its 4 billion-year history, driving the evolution of water. ▪ Loss of water from the Martian atmosphere to space has been a major process in Mars’ atmospheric evolution. Expected final online publication date for the Annual Review of Earth and Planetary Sciences, Volume 49 is May 28, 2021. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.