Specific Interactions Induced Controlled Dispersion of Multiwall Carbon Nanotubes in Co-Continuous Polymer Blends

2010 ◽  
pp. 373-389
2008 ◽  
Vol 19 (33) ◽  
pp. 335704 ◽  
Author(s):  
Suryasarathi Bose ◽  
Arup R Bhattacharyya ◽  
Rupesh A Khare ◽  
Ajit R Kulkarni ◽  
T Umasankar Patro ◽  
...  

2008 ◽  
Author(s):  
Ajit R. Kulkarni ◽  
Suryasarathi Bose ◽  
Arup R. Bhattacharyya ◽  
Shyamalendu M. Bose ◽  
S. N. Behera ◽  
...  

2008 ◽  
Vol 263 (1) ◽  
pp. 11-20 ◽  
Author(s):  
Suryasarathi Bose ◽  
Arup R. Bhattacharyya ◽  
Rupesh A. Khare ◽  
Ajit R. Kulkarni ◽  
Petra Pötschke

2008 ◽  
Vol 8 (4) ◽  
pp. 1721-1727 ◽  
Author(s):  
Suryasarathi Bose ◽  
Arup R. Bhattacharyya ◽  
Manish Chawley ◽  
Pravin V. Kodgire ◽  
Ajit R. Kulkarni ◽  
...  

Multiwall carbon nanotubes (MWNT) were melt-mixed with poly(ethylene-co-methacrylic acid) ionomers (Surlyn) using twin screw microcompounder. The specific interactions existing between the Na+ moieties in Surlyn and the π electron clouds of MWNT were supported by FTIR and Raman spectroscopic analysis. SAXS scattering patterns were found to be progressively broadened in presence of MWNT in Surlyn/MWNT composites. Morphological investigations revealed selective clustering of MWNT in the vicinity of the ionic domains in Surlyn. Further, the domain size of the ionic clusters was found to increase with increasing MWNT content disrupting the ionic pairs apart in the ionic domain. The melt rheological response of Surlyn was significantly affected in presence of MWNT and was profoundly dependent on the ionic clusters. The state of dispersion of MWNT was assessed by AC electrical conductivity measurements. The associated percolation threshold was observed between 1.5–2 wt% of MWNT.


2018 ◽  
Author(s):  
Gen Hayase

By exploiting the dispersibility and rigidity of boehmite nanofibers (BNFs) with a high aspect ratio of 4 nm in diameter and several micrometers in length, multiwall-carbon nanotubes (MWCNTs) were successfully dispersed in aqueous solutions. In these sols, the MWCNTs were dispersed at a ratio of about 5–8% relative to BNFs. Self-standing BNF–nanotube films were also obtained by filtering these dispersions and showing their functionality. These films can be expected to be applied to sensing materials.


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