Living Radical Polymerisation in Emulsion and Miniemulsion

2007 ◽  
pp. 111-139 ◽  
Author(s):  
Michael J. Monteiro ◽  
Bernadette Charleux
Keyword(s):  
Radical Polymerisation

scholarly journals Plug-and-play aqueous electrochemical atom transfer radical polymerization

2021 ◽  
Vol 57 (32) ◽  
pp. 3897-3900
Author(s):  
Boyu Zhao ◽  
Mahir Mohammed ◽  
Bryn A. Jones ◽  
Paul Wilson
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Good Control ◽  
Atom Transfer ◽  
Plug And Play ◽  
Radical Polymerisation ◽  
Galvanostatic Conditions

‘Plug-and-play’ simplified electrochemical atom transfer radical polymerisation of PEGA480 under potentiostatic and galvanostatic conditions proceeds with very good control to conversions up to 83%.

Facile synthesis of gemini surface-active ATRP initiator and its use in soap-free AGET ATRP mini-emulsion polymerisation

2013 ◽  
Vol 67 (3) ◽  
Author(s):  
Chuan Cheng ◽  
Quan Fu ◽  
Xiong Bai ◽  
Shao Liu ◽  
Liang Shen ◽  
...  
Keyword(s):  
Gemini Surfactant ◽  
Reaction Kinetic ◽  
Total Yield ◽  
Kinetic Studies ◽  
Facile Synthesis ◽  
Aget Atrp ◽  
Cationic Gemini Surfactant ◽  
Emulsion Polymerisation ◽  
Radical Polymerisation ◽  
Surface Active

AbstractA novel cationic gemini surfactant has been readily synthesised in 70 % total yield. The functional gemini surfactant can act both as an emulsifier and an atom transfer radical polymerisation (ATRP) initiator in mini-emulsion polymerisation of methyl methacrylate (MMA), in which no other emulsifier was required. 1-(Dimethylamino)dodecane (N,N-dimethyldodecylamine, DMDA) was found to be a good ligand in the activator generated by electron transfer (AGET) ATRP reaction. Kinetic studies indicated that the polymerisation featured controlled/living radical polymerisation.

Synthesis and properties of semifluorinated block copolymers containing poly(ethylene oxide) and poly(fluorooctyl methacrylates) via atom transfer radical polymerisation

Polymer ◽  
2002 ◽  
Vol 43 (25) ◽  
pp. 7043-7049 ◽  
Author(s):  
Kwon Taek Lim ◽  
Min Young Lee ◽  
Myung Jun Moon ◽  
Gun Dae Lee ◽  
Seong-Soo Hong ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Ethylene Oxide ◽  
Atom Transfer ◽  
Radical Polymerisation ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene

Heterophase Radical Polymerisation

1973 ◽  
Vol 42 (2) ◽  
pp. 120-135 ◽  
Author(s):  
V A Popov ◽  
G P Gladyshev
Keyword(s):  
Radical Polymerisation
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