Dimanganese decacarbonyl

2010 ◽  
pp. 000-000
Author(s):  
Tse-Lok Ho ◽  
Mary Fieser ◽  
Louis Fieser
Keyword(s):  
Dimanganese Decacarbonyl

ChemInform Abstract: Thermodynamics for the Hydrogenation of Dimanganese Decacarbonyl.

ChemInform ◽  
2010 ◽  
Vol 23 (25) ◽  
pp. no-no
Author(s):  
R. J. KLINGLER ◽  
J. W. RATHKE
Keyword(s):  
Dimanganese Decacarbonyl

ChemInform Abstract: LASER PHOTOLYSIS STUDY OF THE PHOTOSUBSTITUTION IN DIMANGANESE DECACARBONYL

1984 ◽  
Vol 15 (1) ◽  
Author(s):  
H. YESAKA ◽  
T. KOBAYASHI ◽  
K. YASUFUKU ◽  
S. NAGAKURA
Keyword(s):  
Laser Photolysis ◽  
Dimanganese Decacarbonyl

Efficient Radical Coupling of Organobromides Using Dimanganese Decacarbonyl

1999 ◽  
Vol 29 (15) ◽  
pp. 2711-2718 ◽  
Author(s):  
Bruce C. Gilbert ◽  
Chris I. Lindsay ◽  
P. Terry McGrail ◽  
Andrew F. Parsons ◽  
David T. E. Whittaker
Keyword(s):  
Radical Coupling ◽  
Dimanganese Decacarbonyl

Dimanganese decacarbonyl

2009 ◽  
pp. 000-000
Author(s):  
Tse-Lok Ho ◽  
Mary Fieser ◽  
Louis Fieser
Keyword(s):  
Dimanganese Decacarbonyl

scholarly journals Ketyl radical reactivity via atom transfer catalysis

Science ◽  
2018 ◽  
Vol 362 (6411) ◽  
pp. 225-229 ◽  
Author(s):  
Lu Wang ◽  
Jeremy M. Lear ◽  
Sean M. Rafferty ◽  
Stacy C. Fosu ◽  
David A. Nagib
Keyword(s):  
Functional Group ◽  
Atom Transfer ◽  
Ketyl Radical ◽  
Radical Reactivity ◽  
Atom Transfer Radical Addition ◽  
Synthetic Utility ◽  
Vinyl Iodide ◽  
Dimanganese Decacarbonyl ◽  
Electron Reduction

Single-electron reduction of a carbonyl to a ketyl enables access to a polarity-reversed platform of reactivity for this cornerstone functional group. However, the synthetic utility of the ketyl radical is hindered by the strong reductants necessary for its generation, which also limit its reactivity to net reductive mechanisms. We report a strategy for net redox-neutral generation and reaction of ketyl radicals. The in situ conversion of aldehydes to α-acetoxy iodides lowers their reduction potential by more than 1 volt, allowing for milder access to the corresponding ketyl radicals and an oxidative termination event. Upon subjecting these iodides to a dimanganese decacarbonyl precatalyst and visible light irradiation, an atom transfer radical addition (ATRA) mechanism affords a broad scope of vinyl iodide products with highZ-selectivity.

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