ChemInform Abstract: ISONITRILE DERIVATIVES OF DIMANGANESE DECACARBONYL PART 1, EVIDENCE FOR METAL-METAL LIGAND EXCHANGE

1975 ◽  
Vol 6 (27) ◽  
pp. no-no
Author(s):  
R. D. ADAMS ◽  
D. F. CHODOSH
Keyword(s):  
Ligand Exchange ◽  
Metal Metal ◽  
Dimanganese Decacarbonyl ◽  
Derivatives Of ◽  
Metal Ligand

scholarly journals The nature of frontier orbitals under systematic ligand exchange in (pseudo-)octahedral Fe(ii) complexes

2018 ◽  
Vol 20 (44) ◽  
pp. 27745-27751 ◽  
Author(s):  
Raphael M. Jay ◽  
Sebastian Eckert ◽  
Mattis Fondell ◽  
Piter S. Miedema ◽  
Jesper Norell ◽  
...  
Keyword(s):  
Excited State ◽  
Ligand Exchange ◽  
Ligand Substitution ◽  
Frontier Orbitals ◽  
X Ray ◽  
X Ray Scattering ◽  
The Impact ◽  
Metal Ligand ◽  
Ray Scattering

The impact of ligand substitution on metal-ligand covalency and the valence excited state landscape is investigated using resonant inelastic soft X-ray scattering.

Novel routes to heteronuclear metal clusters containing rhodium

1982 ◽  
Vol 308 (1501) ◽  
pp. 87-93 ◽  
Keyword(s):  
Similar Pattern ◽  
Metal Clusters ◽  
Frontier Orbitals ◽  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds ◽  
Metal Ligand

Logical methods for preparing small metal clusters with heteronuclear metal-metal bonds can be devised by appreciating the isolobal relationships that exist between certain metal ligand combinations and organic fragments. Thus the group W(CO) 2 (r|-C 5 H 5 ) has frontier orbitals of similar pattern to those of CH, while those of Rh(CO) (r|-C 5 Me 5 ) and CH 2 are also similar. This paper shows how such ideas have been employed to generate compounds with bonds between rhodium and other metals.

Non-linearity with metal-metal ligand complex reactions in flow injection systems. Metal-thiocyanate reactions

1997 ◽  
Vol 350 (1-2) ◽  
pp. 37-50 ◽  
Author(s):  
J.F. van Staden ◽  
C. Saling ◽  
D. Malan ◽  
R.E. Taljaard
Keyword(s):  
Flow Injection ◽  
Ligand Complex ◽  
Metal Metal ◽  
Metal Ligand

Structural bonding trends in rhenium carbonylcluster chemistry : metal–metal metal–ligand bondlengths calculated strengths

Polyhedron ◽  
1998 ◽  
Vol 17 (17) ◽  
pp. 2803-2815 ◽  
Author(s):  
Katherine M Hillary ◽  
Andrew K Hughes ◽  
Karen L Peat ◽  
Ken Wade
Keyword(s):  
Structural Bonding ◽  
Metal Metal ◽  
Metal Ligand

Experimental charge density in the transition metal complex Mn2(CO)10: a comparative study

2003 ◽  
Vol 59 (2) ◽  
pp. 234-247 ◽  
Author(s):  
Louis J. Farrugia ◽  
Paul R. Mallinson ◽  
Brian Stewart
Keyword(s):  
Charge Density ◽  
Transition Metal Complex ◽  
Topological Analysis ◽  
Atoms In Molecules ◽  
Topological Properties ◽  
B3lyp Level ◽  
Metal Metal ◽  
Density Study ◽  
Experimental Charge Density ◽  
Metal Ligand

An accurate experimental charge density study at 100 K of Mn2(CO)10 [bis(pentacarbonylmanganese)(Mn—Mn)] has been undertaken. A comparison with previously reported structural determinations reveals no evidence for significant Mn—Mn bond lengthening between 100 and 296 K. The nature of the metal–metal and metal–ligand atom interactions has been studied by topological analysis using the Atoms in Molecules (AIM) approach of Bader [(1990), Atoms in Molecules: a Quantum Theory.Oxford: Clarendon Press]. An analysis of the density ρ(r), the Laplacian of the density ∇2ρ(r b ) and the total energy densities H(r b ) at the bond critical points is used to classify all the chemical bonds as covalent in nature. The results are compared qualitatively and quantitatively with previous charge density studies on this molecule and DFT calculations at the 6-311+G* B3LYP level. The topological properties of the theoretical and experimental densities are in close agreement.

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