In Situ Spectroscopy for Mechanistic Studies in Semiconductor Photocatalysis

2021 ◽  
pp. 51-75
Author(s):  
Jan P. Hofmann
Author(s):  
Hanna Lyle ◽  
Suryansh Singh ◽  
Michael Paolino ◽  
Ilya Vinogradov ◽  
Tanja Cuk

The conversion of diffusive forms of energy (electrical and light) into short, compact chemical bonds by catalytic reactions regularly involves moving a carrier from an environment that favors delocalization to one that favors localization.


2021 ◽  
pp. 174751982098753
Author(s):  
Xiaofang Wu ◽  
Lei Zhou ◽  
Fangshao Li ◽  
Jing Xiao

A PCl3-mediated conversion of tert-butyl esters into esters and amides in one-pot under air is developed. This novel protocol is highlighted by the synthesis of skeletons of bioactive molecules and gram-scale reactions. Mechanistic studies revealed that this transformation involves the formation of an acid chloride in situ, which is followed by reactions with alcohols or amines to afford the desired products.


Author(s):  
S. Ted Oyama ◽  
Gwang-Nam Yun ◽  
So-Jin Ahn ◽  
Kyoko K. Bando ◽  
Atsushi Takagaki ◽  
...  

2007 ◽  
Vol 46 (28) ◽  
pp. 5412-5416 ◽  
Author(s):  
Simona M. Bennici ◽  
Bas M. Vogelaar ◽  
T. Alexander Nijhuis ◽  
Bert M. Weckhuysen

2015 ◽  
Vol 6 (3) ◽  
pp. 464-469 ◽  
Author(s):  
Oliver Supplie ◽  
Matthias M. May ◽  
Gabi Steinbach ◽  
Oleksandr Romanyuk ◽  
Frank Grosse ◽  
...  

2014 ◽  
Vol 2 (42) ◽  
pp. 17875-17882 ◽  
Author(s):  
Sou Taminato ◽  
Masaaki Hirayama ◽  
Kota Suzuki ◽  
KyungSu Kim ◽  
Yueming Zheng ◽  
...  

2018 ◽  
Vol 90 (11) ◽  
pp. 1855-1863 ◽  
Author(s):  
Sebastian Ponce ◽  
Hauke Christians ◽  
Alfons Drochner ◽  
Bastian J. M. Etzold

Author(s):  
B. Rasaiah ◽  
C. Bellman ◽  
R.D. Hewson ◽  
S. D. Jones ◽  
T. J. Malthus

Field spectroscopic metadata is a central component in the quality assurance, reliability, and discoverability of hyperspectral data and the products derived from it. Cataloguing, mining, and interoperability of these datasets rely upon the robustness of metadata protocols for field spectroscopy, and on the software architecture to support the exchange of these datasets. Currently no standard for in situ spectroscopy data or metadata protocols exist. This inhibits the effective sharing of growing volumes of in situ spectroscopy datasets, to exploit the benefits of integrating with the evolving range of data sharing platforms. A core metadataset for field spectroscopy was introduced by Rasaiah et al., (2011-2015) with extended support for specific applications. This paper presents a prototype model for an OGC and ISO compliant platform-independent metadata discovery service aligned to the specific requirements of field spectroscopy. In this study, a proof-of-concept metadata catalogue has been described and deployed in a cloud-based architecture as a demonstration of an operationalized field spectroscopy metadata standard and web-based discovery service.


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