Metal-Organic Frameworks: From Bimetallic Metal-Organic Framework to Porous Carbon: High Surface Area and Multicomponent Active Dopants for Excellent Electrocatalysis (Adv. Mater. 34/2015)

Metal-organic framework (MOF) materials show extraordinary performances in several frontier applications of energy research due to their well-defined crystalline porous architecture, high surface area and periodicity of the functional groups...

Download Full-text

Nano palladium supported on high-surface-area metal-organic framework MIL-101: an efficient catalyst for Sonogashira coupling of aryl and heteroaryl bromides with alkynes

Applied Organometallic Chemistry ◽

10.1002/aoc.3277 ◽

2015 ◽

Vol 29 (4) ◽

pp. 234-239 ◽

Cited By ~ 23

Author(s):

Manne Annapurna ◽

T. Parsharamulu ◽

P. Vishnuvardhan Reddy ◽

M. Suresh ◽

Pravin R. Likhar ◽

...

Keyword(s):

Surface Area ◽

Metal Organic Framework ◽

High Surface ◽

High Surface Area ◽

Sonogashira Coupling ◽

Efficient Catalyst ◽

Metal Organic ◽

Organic Framework

Download Full-text

High surface area mesoporous alumina nanosheets and nanorolls from an aluminum based metal organic framework

Ceramics International ◽

10.1016/j.ceramint.2016.08.101 ◽

2016 ◽

Vol 42 (15) ◽

pp. 17742-17748 ◽

Cited By ~ 12

Author(s):

Maryam Derakhshani ◽

Alireza Hashamzadeh ◽

Mostafa M. Amini

Keyword(s):

Surface Area ◽

Metal Organic Framework ◽

High Surface ◽

High Surface Area ◽

Mesoporous Alumina ◽

Metal Organic ◽

Organic Framework

Download Full-text

Enhanced Fungicidal Efficacy by Co-Delivery of Azoxystrobin and Diniconazole with Cauliflower-Like Metal–Organic Frameworks NH2-Al-MIL-101

International Journal of Molecular Sciences ◽

10.3390/ijms221910412 ◽

2021 ◽

Vol 22 (19) ◽

pp. 10412

Author(s):

Huiping Chen ◽

Yongpan Shan ◽

Lidong Cao ◽

Pengyue Zhao ◽

Chong Cao ◽

...

Keyword(s):

Surface Area ◽

Plant Protection ◽

Metal Organic Framework ◽

High Surface ◽

Metal Organic Frameworks ◽

High Surface Area ◽

Release Time ◽

Natural Ecosystems ◽

Resistance Risk ◽

Metal Organic

Long-term use of a single fungicide increases the resistance risk and causes adverse effects on natural ecosystems. Controlled release formulations of dual fungicides with different modes of action can afford a new dimension for addressing the current issues. Based on adjustable aperture and superhigh surface area, metal–organic frameworks (MOFs) are ideal candidates as pesticide release carriers. This study used Al3+ as the metal node and 2-aminoterephthalic acid as the organic chain to prepare aluminum-based metal–organic framework material (NH2-Al-MIL-101) with “cauliflower-like” structure and high surface area of 2359.0 m2/g. Fungicides of azoxystrobin (AZOX) and diniconazole (Dini) were simultaneously encapsulated into NH2-Al-MIL-101 with the loading content of 6.71% and 29.72%, respectively. Dual fungicide delivery system of AZOX@Dini@NH2-Al-MIL-101 demonstrated sustained and pH responsive release profiles. When the maximum cumulative release rate of AZOX and Dini both reached about 90%, the release time was 46 and 136 h, respectively. Furthermore, EC50 values as well as the percentage of inhibition revealed that AZOX@Dini@NH2-Al-MIL-101 had enhanced germicidal efficacy against rice sheath blight (Rhizoctonia solani), evidenced by the synergistic ratio of 1.83. The present study demonstrates a potential application prospect in sustainable plant protection through co-delivery fungicides with MOFs as a platform.

Download Full-text