Studies and production of anodic exfoliated graphene have been blossoming exponentially to meet the high demand for next generation optoelectronics devices. In this study, the effect of sulfate concentration on the graphene film is presented. The electrochemical exfoliation was conducted using a simple two-electrode system to study on the morphological and optical properties of graphene films using Atomic Force Microscope (AFM), Raman Spectroscopy and Ultraviolet–Visible (UV-Vis) spectrophotometer. Preliminary results show the presence of few layers graphene with nanometer-scale lateral dimension. The study suggests an alternative solution for the large-scale manufacturing capabilities of graphene is feasible