A Method to Apply Zavitsas’ Aqueous Electrolyte Model to Multicomponent Solutions and its Equivalence to Zdanovskii’s Rule

AIChE Journal ◽  
2021 ◽  
Author(s):  
Jacob G. Reynolds
Keyword(s):  
Aqueous Electrolyte ◽  
Zdanovskii’S Rule ◽  
Multicomponent Solutions ◽  
Zdanovskii's Rule

Thermodynamics of Mixed Electrolyte Solutions

1975 ◽  
Vol 53 (10) ◽  
pp. 1410-1413 ◽  
Author(s):  
James Sangster ◽  
Fabio Lenzi
Keyword(s):  
Electrolyte Solutions ◽  
Mixed Electrolyte ◽  
Mixed Electrolyte Solutions ◽  
Harned's Rule ◽  
Zdanovskii’S Rule ◽  
Zdanovskii's Rule

A general thermodynamic expression has been derived for the deviation Δ from Zdanovskii's rule. Conditions have been deduced under which Δ vanishes, and examples given. For nonzero values of Δ it has been shown by means of an example that Δ may be evaluated in some cases by the introduction of empirical assumptions, such as Harned's rule. The use of Zdanovskii's rule in facilitating the integration of the McKay–Perring equation has been discussed briefly.

Calculation of the activity of uranyl nitrate and nitric acid in the H2O–HNO3–UO2(NO3)2–TBP–diluent system using Zdanovskii’s rule

2016 ◽  
Vol 58 (3) ◽  
pp. 280-286 ◽  
Author(s):  
A. V. Ochkin ◽  
A. O. Merkushkin ◽  
S. Yu. Nekhaevskii ◽  
E. A. Tyupina
Keyword(s):  
Nitric Acid ◽  
Uranyl Nitrate ◽  
Zdanovskii’S Rule ◽  
Zdanovskii's Rule

Zdanovskii’s Rule and Isopiestic Measurements Applied to Synthetic Bayer Liquors

2007 ◽  
Vol 36 (11-12) ◽  
pp. 1619-1634 ◽  
Author(s):  
Erich Königsberger ◽  
Lan-Chi Königsberger ◽  
Glenn Hefter ◽  
Peter M. May
Keyword(s):  
Isopiestic Measurements ◽  
Zdanovskii’S Rule ◽  
Bayer Liquors ◽  
Zdanovskii's Rule

Promoting Nitrogen Electroreduction to Ammonia with Bismuth Nanocrystals and Potassium Cations in Water

2020 ◽  
Author(s):  
Jaecheol Choi ◽  
Hoang-Long Du ◽  
Manjunath Chatti ◽  
Bryan H. R. Suryanto ◽  
Alexandr Simonov ◽  
...  
Keyword(s):  
Electrocatalytic Activity ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Reduction Reaction ◽  
Nitrogen Reduction ◽  
Aqueous Electrolyte Solutions

We demonstrate that bismuth exhibits no measurable electrocatalytic activity for the nitrogen reduction reaction to ammonia in aqueous electrolyte solutions, contrary to several recent reports on the highly impressive rates of Bi-catalysed electrosynthesis of NH<sub>3</sub> from N<sub>2</sub>.

scholarly journals Correction to: Tetra chlorobenzoxazolamine nickel (II) phthalocyanine supercapacitor with aqueous electrolyte and MWCNTs

2021 ◽  
Author(s):  
N. Y. Praveen Kumar ◽  
Mounesh Mounesh ◽  
T. M. Sharanakumar ◽  
K. R. Venugopala Reddy
Keyword(s):  
Aqueous Electrolyte
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