Efficient Synthesis of Sulfenamides through Mitsunobu‐type Coupling Reaction of Thiols with Amines using Dibenzyl Azodicarboxylate

2020 ◽  
Vol 9 (6) ◽  
pp. 933-938
Author(s):  
Se Hwan Ryu ◽  
Jongmin Ra ◽  
Haye Min Ko
2010 ◽  
Vol 51 (15) ◽  
pp. 2023-2028 ◽  
Author(s):  
Yan-Yan Han ◽  
Zhi-Jun Wu ◽  
Xiao-Mei Zhang ◽  
Wei-Cheng Yuan

2019 ◽  
Vol 17 (45) ◽  
pp. 9799-9807 ◽  
Author(s):  
Suo Chen ◽  
Hui Wang ◽  
Wei Jiang ◽  
Pei-Xin Rui ◽  
Xiang-Guo Hu

A practical and efficient synthesis of fluoroalkylanilines has been achieved via the Ullmann type coupling of (hetero)aromatic bromides with tri(di)fluoroethylamine.


2011 ◽  
Vol 7 ◽  
pp. 1334-1341 ◽  
Author(s):  
Sanny Verma ◽  
Suman L Jain ◽  
Bir Sain

PEG-embedded potassium tribromide ([K+PEG]Br3 −) was found to be an efficient and recyclable catalyst for the synthesis of functionalized piperidines in high yields in a one step, three component coupling between aldehyde, amine and β-keto ester. At the end of the reaction the [K+PEG]Br3 − was readily regenerated from the reaction mixture by treating the residue containing [K+PEG]Br− with molecular bromine.


Author(s):  
Yong Wang ◽  
Yu-Jiao Wang ◽  
Xian-Cheng Liang ◽  
Mei-Hua Shen ◽  
Hua-Dong Xu ◽  
...  

The addition reaction of thiol to vinyl azide has been extensively studied. Variously substituted aryl thiols are all viable for this coupling process. The scope of the other partner is...


Heterocycles ◽  
1992 ◽  
Vol 33 (2) ◽  
pp. 831 ◽  
Author(s):  
Seiichi Takano ◽  
Masashi Akiyama ◽  
Takumichi Sugihara ◽  
Kunio Ogasawara

e-Polymers ◽  
2001 ◽  
Vol 1 (1) ◽  
Author(s):  
Michael Ishaque ◽  
Ralf Wombacher ◽  
Joachim H. Wendorff ◽  
Andreas Greiner

AbstractTwo step synthesis of educts for the synthesis of poly(p-xylylene)s was accomplished by Grignard-type coupling reaction of 4-bromotoluene and different aldehydes or p-tolylaldehyde and different aryl bromides followed by conversion of alcohols into corresponding chlorides. Derivatives of poly(p-xylylene) (PPX) were obtained by vapor phase pyrolysis/chemical vapor deposition (CVD) or Gilch-type polymerization of these chlorides. Functional groups along the PPX main chain were introduced by substituted phenyl rings in a-position. The resulting PPXs are soluble under ambient conditions and are amorphous in the solid state. The glass transition temperatures varied only slightly with substituents on the phenyl ring in a-position. Significant enhancement by substituents was found for the thermal stability under nitrogen and a considerable decrease of the surface energies by fluorinated substituents.


2014 ◽  
Vol 50 (28) ◽  
pp. 3692-3694 ◽  
Author(s):  
Jiangang Mao ◽  
Shuo-Qing Zhang ◽  
Bing-Feng Shi ◽  
Weiliang Bao

A novel Pd(0)-catalyzed domino cyclopropanation reaction was established. The process involves a Heck-type coupling reaction and a C(sp3)–H activation.


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