A Mixed Molecular Building Block Strategy for the Design of Nested Polyhedron Metal-Organic Frameworks

2013 ◽  
Vol 126 (3) ◽  
pp. 856-860 ◽  
Author(s):  
Dan Tian ◽  
Qiang Chen ◽  
Yue Li ◽  
Ying-Hui Zhang ◽  
Ze Chang ◽  
...  
Keyword(s):  
Building Block ◽  
Metal Organic Frameworks ◽  
Molecular Building Block ◽  
Metal Organic

Recent progress in the design and synthesis of zeolite-like metal–organic frameworks (ZMOFs)

2021 ◽  
Author(s):  
Xinyao Liu ◽  
Yunling Liu
Keyword(s):  
Building Block ◽  
High Stability ◽  
Recent Progress ◽  
Metal Organic Frameworks ◽  
Excellent Performance ◽  
Design And Synthesis ◽  
Molecular Building Block ◽  
Secondary Building Units ◽  
Metal Organic

ZMOFs are a subset of MOFs that exhibit zeolite-like topologies. Using molecular building block strategy, many ZMOFs with high stability and excellent performance can be rationally designed and synthesized using different secondary building units.

Incorporation of an intact dimeric Zr12 oxo cluster from a molecular precursor in a new zirconium metal–organic framework

2018 ◽  
Vol 54 (22) ◽  
pp. 2735-2738 ◽  
Author(s):  
Andrey A. Bezrukov ◽  
Karl W. Törnroos ◽  
Erwan Le Roux ◽  
Pascal D. C. Dietzel
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Molecular Building Block ◽  
Molecular Precursor ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

A dimeric Zr12 oxo cluster was used as new molecular building block in construction of metal–organic frameworks utilizing the precursor approach.

A Mixed Molecular Building Block Strategy for the Design of Nested Polyhedron Metal-Organic Frameworks

2013 ◽  
Vol 53 (3) ◽  
pp. 837-841 ◽  
Author(s):  
Dan Tian ◽  
Qiang Chen ◽  
Yue Li ◽  
Ying-Hui Zhang ◽  
Ze Chang ◽  
...  
Keyword(s):  
Building Block ◽  
Metal Organic Frameworks ◽  
Molecular Building Block ◽  
Metal Organic

A supermolecular building block approach for construction of chiral metal–organic frameworks

2019 ◽  
Vol 55 (59) ◽  
pp. 8639-8642 ◽  
Author(s):  
Hong Jiang ◽  
Kai-Jie Chen ◽  
Fan-Fan Zheng ◽  
Xu Chen ◽  
Yan Liu ◽  
...  
Keyword(s):  
Building Block ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Metal Organic ◽  
Block Approach

Three isoreticular chiral porous metal–organic frameworks (MOFs) with different pore environments are synthesized through a supermolecular building block approach.

Planar-chiral building blocks for metal–organic frameworks

2015 ◽  
Vol 51 (23) ◽  
pp. 4796-4798 ◽  
Author(s):  
Murat Cakici ◽  
Zhi-Gang Gu ◽  
Martin Nieger ◽  
Jochen Bürck ◽  
Lars Heinke ◽  
...  
Keyword(s):  
Building Block ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Chiral Building Block ◽  
Metal Organic

The first example of a planar-chiral building block being used for chiral metal–organic frameworks (MOFs) is presented.

Control over Catenation in Metal−Organic Frameworks via Rational Design of the Organic Building Block

2010 ◽  
Vol 132 (3) ◽  
pp. 950-952 ◽  
Author(s):  
Omar K. Farha ◽  
Christos D. Malliakas ◽  
Mercouri G. Kanatzidis ◽  
Joseph T. Hupp
Keyword(s):  
Building Block ◽  
Rational Design ◽  
Metal Organic Frameworks ◽  
Metal Organic

A new two-dimensional cadmium metal–organic framework: poly[bis(4,7-diphenyl-1,10-phenanthroline)(μ3-5-nitroisophthalato)cadmium(II)]

2012 ◽  
Vol 68 (11) ◽  
pp. m306-m308
Author(s):  
Jun-Wei Ye ◽  
Li-Mei Zhao ◽  
Wei Li ◽  
Gui-Ling Ning
Keyword(s):  
Building Block ◽  
General Position ◽  
Metal Organic Framework ◽  
Building Blocks ◽  
Two Dimensional ◽  
Aromatic Rings ◽  
Molecular Building Block ◽  
Cadmium Metal ◽  
Metal Organic ◽  
Organic Framework

In the title cadmium metal–organic framework complex, [Cd(C8H3NO6)(C24H16N2)]nor [Cd(NIPH)(dpphen)] (NIPH is nitroisophthalate and dpphen is 4,7-diphenyl-1,10-phenanthroline), the unique CdIIcation in a general position is coordinated by four carboxy O atoms from three symmetry-related NIPH anions and two N atoms from a dpphen ligand. The CdIIcations are bridged by pairs of NIPH anions to generate a dinuclear molecular building block, [Cd2N4(CO2R)4], with a Cd...Cd separation of 4.0936 (10) Å. Each such building block is connected to four adjacent dinuclear building blocks by NIPH anions, resulting in a two-dimensional layer framework in thebcplane. The dpphen ligands occupy the space between these layers and are linked by π–π interactions, with a separation of 3.4541 (6) Å between the central aromatic rings of inversion-related dpphen ligands. The thermogravimetric and photoluminescent properties of the complex have also been investigated.

scholarly journals Sulfur polyconjugated organic ligands as building block in photoactive metal–organic frameworks

2018 ◽  
Vol 74 (a2) ◽  
pp. e372-e373
Author(s):  
Alba García Sánchez ◽  
Marta Liras ◽  
Fernando Fresno ◽  
Mariam Barawi ◽  
Enrique Gutiérrez-Puebla ◽  
...  
Keyword(s):  
Building Block ◽  
Metal Organic Frameworks ◽  
Organic Ligands ◽  
Metal Organic
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