Suppressing fire hazard of poly(vinyl alcohol) based on ( NH 4 ) 2 [ VO ( HPO 4 )] 2 ( C 2 O 4 )· 5H 2 O with layered structure

2021 ◽  
pp. 51345
Author(s):  
Haojie Zhu ◽  
Yongming Chen ◽  
Shuai Huang ◽  
Yuan Wang ◽  
Ru Yang ◽  
...  
Langmuir ◽  
2019 ◽  
Vol 35 (34) ◽  
pp. 11099-11107 ◽  
Author(s):  
Tsukasa Miyazaki ◽  
Noboru Miyata ◽  
Mitsunori Asada ◽  
Yoshihiro Tsumura ◽  
Naoya Torikai ◽  
...  

Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1078
Author(s):  
Cheng-Yuan Xing ◽  
Shi-Lin Zeng ◽  
Shi-Kai Qi ◽  
Meng-Jin Jiang ◽  
Long Xu ◽  
...  

Fibers with good flame retardant (FR) and smoke suppression performances are highly desirable for the purpose of eliminating fire hazard. This study developed a novel FR fiber by wet-spinning poly (vinyl alcohol)/β-cyclodextrin (PVA/βCD) composite fiber and crosslinking it with hexamethylene diisocyanate (HDI). βCDs showed good compatibility with PVA matrix, and the resulting PVA/CD/HDI fibers showed mechanical strength at the same level as natural cotton fiber. The PVA/CD/HDI fibers also showed excellent flame retardance (the LOI value of PVA/CD/HDI could reach 41.7%, and their peak of heat release (PHRR) could be reduced by up to 77.7% by neat PVA), and super-smoke suppression (the value of total smoke production (TSP) was only 28.6% compared to PVA). These dramatic reductions of fire hazard were ascribed to the char formation of βCD and crosslinking structure of PVA/CD/HDI, which formed a compact char layer during combustion, thus preventing heat transmission and smoke release.


Langmuir ◽  
2021 ◽  
Author(s):  
Tsukasa Miyazaki ◽  
Noboru Miyata ◽  
Hiroshi Arima-Osonoi ◽  
Hiroshi Kira ◽  
Keiichi Ohuchi ◽  
...  

Carbon ◽  
2009 ◽  
Vol 47 (15) ◽  
pp. 3538-3543 ◽  
Author(s):  
Yuxi Xu ◽  
Wenjing Hong ◽  
Hua Bai ◽  
Chun Li ◽  
Gaoquan Shi

1986 ◽  
Vol 1 (6) ◽  
pp. 861-869 ◽  
Author(s):  
Paul D. Garrett ◽  
David T. Grubb

2019 ◽  
Vol 18 (1) ◽  
pp. 125-136 ◽  
Author(s):  
Luiza Jecu ◽  
Iuliana Raut ◽  
Elena Grosu ◽  
Mariana Calin ◽  
Violeta Purcar ◽  
...  

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