Lignin-Based Green Catalyst for the Chemical Fixation of Carbon Dioxide with Epoxides To Form Cyclic Carbonates under Solvent-Free Conditions

ChemCatChem ◽  
2013 ◽  
Vol 5 (6) ◽  
pp. 1328-1333 ◽  
Author(s):  
Zhilian Wu ◽  
Haibo Xie ◽  
Xue Yu ◽  
Enhui Liu
Keyword(s):  
Carbon Dioxide ◽  
Solvent Free ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Green Catalyst ◽  
Solvent Free Conditions ◽  
Fixation Of Carbon Dioxide

Nicotine-derived ammonium salts as highly efficient catalysts for chemical fixation of carbon dioxide into cyclic carbonates under solvent-free conditions

RSC Advances ◽  
2015 ◽  
Vol 5 (75) ◽  
pp. 61179-61183 ◽  
Author(s):  
Abdol R. Hajipour ◽  
Yasaman Heidari ◽  
Gholamreza Kozehgary
Keyword(s):  
Carbon Dioxide ◽  
Organic Solvent ◽  
Solvent Free ◽  
Ammonium Salts ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Highly Efficient ◽  
Solvent Free Conditions ◽  
Recyclable Catalysts ◽  
Fixation Of Carbon Dioxide

Ammonium salts based on nicotine proved to be highly efficient and recyclable catalysts for the synthesis of cyclic carbonates from epoxides and CO2 without the utilization of any organic solvent and any additives.

Niobate salts of organic base catalyzed chemical fixation of carbon dioxide with epoxides to form cyclic carbonates

2015 ◽  
Vol 17 (3) ◽  
pp. 1842-1852 ◽  
Author(s):  
Angjun Chen ◽  
Chen Chen ◽  
Yuhe Xiu ◽  
Xuerui Liu ◽  
Jizhong Chen ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Solvent Free ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Organic Base ◽  
Halogen Free ◽  
Fixation Of Carbon Dioxide

Peroxoniobate salts of amidine and guanidine have been utilized as halogen-free catalysts for the synthesis of cyclic carbonates from epoxides and CO2 under solvent-free and halide-free conditions.

Bifunctional Aluminum Catalysts for the Chemical Fixation of Carbon Dioxide into Cyclic Carbonates

2018 ◽  
Vol 6 (4) ◽  
pp. 5322-5332 ◽  
Author(s):  
Felipe de la Cruz-Martínez ◽  
Javier Martínez ◽  
Miguel A. Gaona ◽  
Juan Fernández-Baeza ◽  
Luis F. Sánchez-Barba ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Fixation Of Carbon Dioxide

scholarly journals Recent Advances in the Chemical Fixation of Carbon Dioxide: A Green Route to Carbonylated Heterocycle Synthesis

Catalysts ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 511 ◽  
Author(s):  
Renato Dalpozzo ◽  
Nicola Della Ca’ ◽  
Bartolo Gabriele ◽  
Raffaella Mancuso
Keyword(s):  
Carbon Dioxide ◽  
Value Added ◽  
The Other ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Heterocycle Synthesis ◽  
Green Industry ◽  
Green Route ◽  
Earth’S Climate ◽  
Fixation Of Carbon Dioxide

Carbon dioxide produced by human activities is one of the main contributions responsible for the greenhouse effect, which is modifying the Earth’s climate. Therefore, post-combustion CO2 capture and its conversion into high value-added chemicals are integral parts of today’s green industry. On the other hand, carbon dioxide is a ubiquitous, cheap, abundant, non-toxic, non-flammable and renewable C1 source. Among CO2 usages, this review aims to summarize and discuss the advances in the reaction of CO2, in the synthesis of cyclic carbonates, carbamates, and ureas appeared in the literature since 2017.

DBU/benzyl bromide: an efficient catalytic system for the chemical fixation of CO2 into cyclic carbonates under metal- and solvent-free conditions

2016 ◽  
Vol 6 (11) ◽  
pp. 3872-3877 ◽  
Author(s):  
Lin Wang ◽  
Koichi Kodama ◽  
Takuji Hirose
Keyword(s):  
Catalytic System ◽  
Benzyl Bromide ◽  
Solvent Free ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Metal Free ◽  
Solvent Free Conditions ◽  
Wide Range

A simple, mild and inexpensive catalytic system, DBU and benzyl bromide, was developed for the cycloaddition of epoxides to ambient CO2 under metal-free and solvent-free conditions and a wide range of epoxides was converted to the corresponding cyclic carbonates with good to excellent yields (81–95%).

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