Niobate salts of organic base catalyzed chemical fixation of carbon dioxide with epoxides to form cyclic carbonates

2015 ◽  
Vol 17 (3) ◽  
pp. 1842-1852 ◽  
Author(s):  
Angjun Chen ◽  
Chen Chen ◽  
Yuhe Xiu ◽  
Xuerui Liu ◽  
Jizhong Chen ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Solvent Free ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Organic Base ◽  
Halogen Free ◽  
Fixation Of Carbon Dioxide

Peroxoniobate salts of amidine and guanidine have been utilized as halogen-free catalysts for the synthesis of cyclic carbonates from epoxides and CO2 under solvent-free and halide-free conditions.

Nicotine-derived ammonium salts as highly efficient catalysts for chemical fixation of carbon dioxide into cyclic carbonates under solvent-free conditions

RSC Advances ◽  
2015 ◽  
Vol 5 (75) ◽  
pp. 61179-61183 ◽  
Author(s):  
Abdol R. Hajipour ◽  
Yasaman Heidari ◽  
Gholamreza Kozehgary
Keyword(s):  
Carbon Dioxide ◽  
Organic Solvent ◽  
Solvent Free ◽  
Ammonium Salts ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Highly Efficient ◽  
Solvent Free Conditions ◽  
Recyclable Catalysts ◽  
Fixation Of Carbon Dioxide

Ammonium salts based on nicotine proved to be highly efficient and recyclable catalysts for the synthesis of cyclic carbonates from epoxides and CO2 without the utilization of any organic solvent and any additives.

Bifunctional Aluminum Catalysts for the Chemical Fixation of Carbon Dioxide into Cyclic Carbonates

2018 ◽  
Vol 6 (4) ◽  
pp. 5322-5332 ◽  
Author(s):  
Felipe de la Cruz-Martínez ◽  
Javier Martínez ◽  
Miguel A. Gaona ◽  
Juan Fernández-Baeza ◽  
Luis F. Sánchez-Barba ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Fixation Of Carbon Dioxide

scholarly journals Recent Advances in the Chemical Fixation of Carbon Dioxide: A Green Route to Carbonylated Heterocycle Synthesis

Catalysts ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 511 ◽  
Author(s):  
Renato Dalpozzo ◽  
Nicola Della Ca’ ◽  
Bartolo Gabriele ◽  
Raffaella Mancuso
Keyword(s):  
Carbon Dioxide ◽  
Value Added ◽  
The Other ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Heterocycle Synthesis ◽  
Green Industry ◽  
Green Route ◽  
Earth’S Climate ◽  
Fixation Of Carbon Dioxide

Carbon dioxide produced by human activities is one of the main contributions responsible for the greenhouse effect, which is modifying the Earth’s climate. Therefore, post-combustion CO2 capture and its conversion into high value-added chemicals are integral parts of today’s green industry. On the other hand, carbon dioxide is a ubiquitous, cheap, abundant, non-toxic, non-flammable and renewable C1 source. Among CO2 usages, this review aims to summarize and discuss the advances in the reaction of CO2, in the synthesis of cyclic carbonates, carbamates, and ureas appeared in the literature since 2017.

Quaternary ammonium hydroxide as a metal-free and halogen-free catalyst for the synthesis of cyclic carbonates from epoxides and carbon dioxide

2015 ◽  
Vol 5 (4) ◽  
pp. 2314-2321 ◽  
Author(s):  
Tadashi Ema ◽  
Kazuki Fukuhara ◽  
Takashi Sakai ◽  
Masaki Ohbo ◽  
Fu-Quan Bai ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Quaternary Ammonium ◽  
Ammonium Hydroxide ◽  
Solvent Free ◽  
Cyclic Carbonates ◽  
Tetrabutylammonium Hydroxide ◽  
Metal Free ◽  
Good Catalyst ◽  
Solvent Free Conditions ◽  
Halogen Free

Tetrabutylammonium hydroxide (TBAH) acted as a good catalyst for the formation of cyclic carbonates from epoxides and CO2 under solvent-free conditions.

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