scholarly journals Discovery of a Fischer-Tropsch Hybrid Reaction: Hydrogenation of Methylformate to Long-Chain Hydrocarbons with Anderson-Schulz-Flory Chain Length Distribution

ChemCatChem ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 1200-1204 ◽  
Author(s):  
Viacheslav Iablokov ◽  
Norbert Kruse
Keyword(s):  
Chain Length ◽  
Length Distribution ◽  
Fischer Tropsch ◽  
Chain Length Distribution ◽  
Long Chain

Nanoreactors: An Efficient Tool To Control the Chain-Length Distribution in Fischer–Tropsch Synthesis

ACS Catalysis ◽  
2016 ◽  
Vol 6 (3) ◽  
pp. 1785-1792 ◽  
Author(s):  
Vijayanand Subramanian ◽  
Kang Cheng ◽  
Christine Lancelot ◽  
Svetlana Heyte ◽  
Sébastien Paul ◽  
...  
Keyword(s):  
Chain Length ◽  
Length Distribution ◽  
Tropsch Synthesis ◽  
Fischer Tropsch ◽  
Efficient Tool ◽  
Chain Length Distribution ◽  
Fischer Tropsch Synthesis

The composition of Eucalyptus and some other leaf waxes

1964 ◽  
Vol 17 (4) ◽  
pp. 464 ◽  
Author(s):  
DHS Horn ◽  
ZH Kranz ◽  
JA Lamberton
Keyword(s):  
Gas Chromatography ◽  
Chain Length ◽  
Eucalyptus Globulus ◽  
Copper Complexes ◽  
Carbon Number ◽  
Length Distribution ◽  
Eucalyptus Species ◽  
Chain Length Distribution ◽  
Medium Chain Length ◽  
Long Chain

Many Eucalyptus waxes contain as major components long-chain β-diketones, which may be readily separated from the rest of the wax as insoluble copper complexes. The most commonly occurring β-diketone is n-tritriacontan-16,18-dione, but in two species, Eucalyptus risdoni and E. coccifera, β-diketones of shorter chain length predominate. From the waxes of several Eucalyptus species a new flavone, 5-hydroxy- 4',7-dimethoxy-6,8-dimethylflavone, and a new triterpene, 11,l2-dehydroursolic lactone acetate, have been isolated. Gas chromatography has been used to determine the chain length distribution of β-diketones, hydrocarbons, and esters from several waxes. The esterified alcohols of Eucalyptus globulus and E. risdoni belong to two series-long-chain n-alkan-1-ols of predominantly even carbon number, and n-alkan-2-ols of medium chain length and predominantly uneven carbon number (n-C9, n-C11, n-C13, and n-C15).

Direct Observation of Chain Lengths and Conformations in Oligofluorene Distributions from Controlled Polymerization by Double Electron-Electron Resonance

2019 ◽  
Author(s):  
Dennis Bücker ◽  
Annika Sickinger ◽  
Julian D. Ruiz Perez ◽  
Manuel Oestringer ◽  
Stefan Mecking ◽  
...  
Keyword(s):  
Chain Length ◽  
Length Distribution ◽  
Catalyst System ◽  
Chain Conformation ◽  
Controlled Polymerization ◽  
Chain Length Distribution ◽  
Electron Resonance ◽  
Double Electron ◽  
The Individual ◽  
Double Electron Electron Resonance

Synthetic polymers are mixtures of different length chains, and their chain length and chain conformation is often experimentally characterized by ensemble averages. We demonstrate that Double-Electron-Electron-Resonance (DEER) spectroscopy can reveal the chain length distribution, and chain conformation and flexibility of the individual n-mers in oligo-(9,9-dioctylfluorene) from controlled Suzuki-Miyaura Coupling Polymerization (cSMCP). The required spin-labeled chain ends were introduced efficiently via a TEMPO-substituted initiator and chain terminating agent, respectively, with an in situ catalyst system. Individual precise chain length oligomers as reference materials were obtained by a stepwise approach. Chain length distribution, chain conformation and flexibility can also be accessed within poly(fluorene) nanoparticles.

scholarly journals Miniaturized Analysis of Amylopectin Chain Length Distribution by Fluorescence-Assisted Capillary Electrophoresis (FACE) down to Single Starch Granules

2021 ◽  
Author(s):  
amandine pruvost ◽  
stanislas helle ◽  
nicolas szydlowski ◽  
Christian ROLANDO
Keyword(s):  
Capillary Electrophoresis ◽  
Chain Length ◽  
Solid Phase ◽  
Potato Starch ◽  
Relative Proportion ◽  
Length Distribution ◽  
Fluorescence Analysis ◽  
Starch Granules ◽  
Chain Length Distribution ◽  
Single Granule

In the present work, we developed a miniaturized method for determining amylopectin chain length distribution (CLD) by fluorescence-assisted capillary electrophoresis (FACE). The method relies on single granule entrapping into capillaries followed by direct starch gelatinization and amylopectin debranching on carbograph-based solid phase extraction (SPE) cartridges. Sample desalting on HypersepTM tips following APTS-labelling and the use of nanovials allowed for the fluorescence analysis of weakly diluted samples. Consequently, method sensitivity was improved by 500-fold which is compatible with the analysis of single potato starch granules. The method was implemented to determine CLD profiles of single starch granules ranging from 50 to 100 µm in diameter. In these experiments, the relative proportion of starch glucans of up to 30 degrees of polymerization (DP) could be quantified.

Chain Length Distribution of Amylopectins of Double- and Triple-Mutants Containing the Waxy Gene in the Inbred Oh43 Maize Background

1987 ◽  
Vol 39 (9) ◽  
pp. 295-298 ◽  
Author(s):  
H. Fuwa ◽  
D. V. Glover ◽  
K. Miyaura ◽  
N. Inouchi ◽  
Y. Konishi ◽  
...  
Keyword(s):  
Chain Length ◽  
Length Distribution ◽  
Waxy Gene ◽  
Chain Length Distribution
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