Abstract
The present study investigated the relationship between the activated carbon surface area, as measured by the BET nitrogen adsorption method, and its adsorptive capacity. Aqueous solutions of phenol at pH 7 were used. The activated carbons were produced in the laboratory from raw and demineralized lignite. Adsorption experiments took place under equilibrium or kinetic conditions and the results were simulated by mathematical modelling. Freundlich and Langmuir models were used to describe equilibrium, while the Peel-Benedek non-equilibrium model was applied for the kinetic study. The results showed that for activated carbons produced from different starting materials, the adsorptive capacities could not be solely explained by their BET surface area. While laboratory-made activated carbons with a surface area of 300 m2/g demonstrated similar capacities under equilibrium, their kinetic behaviour was different. Activated carbon produced from raw lignite showed faster kinetics, due to wider porosity, which was facilitated by the mineral matter during activation. These results were in agreement with the mass transfer coefficients in macropores and micropores estimated by the Peel-Benedek model. Comparison of a laboratory-made activated carbon, with a surface area of 500m2/g, with a commercial activated carbon having twice the surface area showed that the maximum adsorptive capacity under equilibrium of the commercial carbon was only 35% higher than that of the lab-made carbon. Yet, the mass transfer coefficients of the commercial carbon were one to two orders of magnitude higher than those of the laboratory-produced carbon. Finally, the use of the qualitative D-R plots has been suggested to elucidate the porous structure of the activated carbons.
Entrance region(Lévêquelike) mass transfer coefficients in packed bed reactors
